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Synthesis and Crystal Structure of a New Oxime-Type Zinc(II) Complex
Corresponding Author(s) : Li Zhao
Asian Journal of Chemistry,
Vol. 25 No. 8 (2013): Vol 25 Issue 8
Abstract
The Zn(II) complex of an oxime has been synthesized by the reaction of 1-(4-{[(E)-3-ethoxy-2-hydroxybenzylidene]amino}phenyl)ethanone oxime and zinc(II) acetate dihydrate in the mixture of ethanol and acetonitrile. The molecule crystallizes in the triclinic system, space group P-1. Each zine(II) atom coordinates with two mono-oxime ligands in tetrahedral coordination. In the crystal structure, each molecule connects with two other molecules through two strong intermolecular N4-H4···O1 hydrogen bonds and two N2-H2···O4 intermolecular hydrogen bonds. Moreover, a 1D supramolecular structure formed with another adjacent molecule by the two pairs of intermolecular N1-H1···O1 and N2-H2···O4 hydrogen bonds.
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- W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009).
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- W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009).
- W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009).
- L. Zhao and S.W. Ng, Acta Cryst., E66, o2473 (2010).
- L. Zhao and S.W. Ng, Acta Cryst., E66, o2474 (2010).
- W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch., 67b, 197 (2012).
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- W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010).
References
W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009).
S.S. Sun, C.L. Stern and S.T. Nguyen, J. Am. Chem. Soc., 126, 6314 (2004).
S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002).
D.A. Atwood and M.J. Harvey, Chem. Rev., 101, 37 (2001).
W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transition Met. Chem., 37, 271 (2012).
W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009).
W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009).
L. Zhao and S.W. Ng, Acta Cryst., E66, o2473 (2010).
L. Zhao and S.W. Ng, Acta Cryst., E66, o2474 (2010).
W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch., 67b, 197 (2012).
H.L. Wu, K.T. Wang, F. Kou, F. Jia, B. Liu, J.K. Yuan and Y. Bai, J. Coord. Chem., 64, 2676 (2010).
W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010).