Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Utilization of Extensively Available Environmental Waste Mentha spicata for Uptake of Pb(II) from Aqueous Solutions
Corresponding Author(s) : Tariq Mahmood Ansari
Asian Journal of Chemistry,
Vol. 25 No. 8 (2013): Vol 25 Issue 8
Abstract
The present study was focused on extensively available Mentha spicata distillation waste biomass for Pb(II) uptake from aqueous solutions. The biomass was entrapped in alginate bead after adopting a specially carried out process. The effect of various experimental parameters on adsorption of Pb(II) was investigated under laboratory conditions. The results clearly indicated the importance of various experimental parameters such as pH, biosorbent dose, biosorbent particle size, initial metal concentration and contact time for removal of Pb(II) from aqueous solutions. The uptake of Pb(II) by immobilized Mentha spicata distillation waste biomass increased with increase in pH reaching a maximum at 5. The equilibrium sorption data agrees well with Freundlich sorption isotherm with high correlation coefficients. The kinetics of the sorption process was found to follow pseudo-second order kinetic model in batch mode and pseudo-first order in continuous mode of adsorption. High Pb(II) uptake capacity of immobilized Mentha spicata distillation waste biomass suggested that it could be used as a potential biomaterial to remove Pb(II) ions from aqueous solutions.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- I.C. Kong, C.W. Lee and Y.T. Kwon, Bull. Environ. Contam. Toxicol., 61, 505 (1998).
- M. Malakootian, J. Nouri and H. Hossaini, Int. J. Environ. Sci. Technol., 6, 183 (2009).
- B.W. Atkinson, F. Bux and H.C.C. Kasan, Water SA, 24, 129 (1998).
- S.M. Lee and A.P. Davis, Water Res., 35, 534 (2001).
- N. Ahalya, T.V. Ramachandra and R.D. Kanamadi, Res. J. Chem. Environ., 7, 71 (2003).
- M. Martinez, N. Miralles, S. Hidalgo, N. Fiol, I. Villaescusa and J. Poch, J. Hazard. Mater., 133, 203 (2006).
- H.S. Kim, M.H. Park, E.Y. Song, H. Park, S.Y. Kwon, S.K. Han and Y.S. Shim, Hum. Immunol., 66, 1074 (2005).
- B. Volesky and Z.R. Holan, Biotechnol. Prog., 11, 235 (1995).
- M.A. Hanif, R. Nadeem, H.N. Bhatti, N.R. Ahmed and T.M. Ansari, J. Hazard. Mater., 139, 345 (2007).
- E. Fourest and B. Volesky, Environ. Sci. Technol., 30, 277 (1996).
- J.T. Matheickal, Q. Yu and G.M. Woodburn, Water Res., 33, 335 (1998).
- M.H. Nasir, R. Nadeem, M.A. Hanif and K.A.M., J. Hazard. Mater., 147, 1006 (2007).
- Y. Sag, D. Ozer and T. Kutsal, Proc. Biochem., 30, 169 (1995).
- J.S. Chang, V. Law and C. Chang, Water Res., 31, 1651 (1997).
- G.M. Gadd, Accumulation of Metals by Micro-organisms and Algae. In Biotechnology, Special Microbial processes. VCH Ver/agsgellschaft, Weinheim, pp. 401-403 (1998).
- R. Nadeem, T.M. Ansari and A.M. Khalid, J. Hazard. Mater., 156, 64 (2008).
- R. Han, J. Zhang, W. Zou, H. Xiao, J. Shi and H. Liu, J. Hazard. Mater., 133, 262 (2006).
- S.Y. Quek, D.A.J. Wasal and C.F. Forster, Water Strategic Areas, 24, 251 (1998).
- G. Mckay, M.S. Otterburn and Sweeney, Water Res., 14, 15 (1980).
- A. Zubair, H.N. Bhatti, M.A. Hanif and F. Shafqat, Water Air Soil Pollut., 191, 305 (2008).
- J.A. Brierley, C.L. Brierley, R.F. Deeker and G.M. Goyack, European Patent Application No. 85112810, Publication No. 0181 497(1985).
- Muraleedharan, Venkobachar, T.R. Muraleedharan and C. Venkobachar, Biotechnol. Bioeng., 35, 320 (1990).
- K.G. Bhattacharyya and A. Sharma, J. Hazard. Mater., 113, 97 (2004).
- W.J.J.R. Weber, in ed.: Slejko, Adsorption Theory, Concepts and Models, Adsorption Technology: A step-by-step Approach to Process Evalution and Application. Marcel Dekker, New York, pp. 1-35 (1985).
- S. Lagergren, Handlingar, 24, 1 (1898).
- Y.S. Ho and A.E. Ofomaja, J. Hazard. Mater., 129, 137 (2006).
- M.H. Cheng, J.W. Patterson and R.E. Minear, J. Water Pollut. Cont. Federat., 47, 362 (1975).
- B. Benguella and H. Benaissa, Water Res., 36, 2463 (2002).
References
I.C. Kong, C.W. Lee and Y.T. Kwon, Bull. Environ. Contam. Toxicol., 61, 505 (1998).
M. Malakootian, J. Nouri and H. Hossaini, Int. J. Environ. Sci. Technol., 6, 183 (2009).
B.W. Atkinson, F. Bux and H.C.C. Kasan, Water SA, 24, 129 (1998).
S.M. Lee and A.P. Davis, Water Res., 35, 534 (2001).
N. Ahalya, T.V. Ramachandra and R.D. Kanamadi, Res. J. Chem. Environ., 7, 71 (2003).
M. Martinez, N. Miralles, S. Hidalgo, N. Fiol, I. Villaescusa and J. Poch, J. Hazard. Mater., 133, 203 (2006).
H.S. Kim, M.H. Park, E.Y. Song, H. Park, S.Y. Kwon, S.K. Han and Y.S. Shim, Hum. Immunol., 66, 1074 (2005).
B. Volesky and Z.R. Holan, Biotechnol. Prog., 11, 235 (1995).
M.A. Hanif, R. Nadeem, H.N. Bhatti, N.R. Ahmed and T.M. Ansari, J. Hazard. Mater., 139, 345 (2007).
E. Fourest and B. Volesky, Environ. Sci. Technol., 30, 277 (1996).
J.T. Matheickal, Q. Yu and G.M. Woodburn, Water Res., 33, 335 (1998).
M.H. Nasir, R. Nadeem, M.A. Hanif and K.A.M., J. Hazard. Mater., 147, 1006 (2007).
Y. Sag, D. Ozer and T. Kutsal, Proc. Biochem., 30, 169 (1995).
J.S. Chang, V. Law and C. Chang, Water Res., 31, 1651 (1997).
G.M. Gadd, Accumulation of Metals by Micro-organisms and Algae. In Biotechnology, Special Microbial processes. VCH Ver/agsgellschaft, Weinheim, pp. 401-403 (1998).
R. Nadeem, T.M. Ansari and A.M. Khalid, J. Hazard. Mater., 156, 64 (2008).
R. Han, J. Zhang, W. Zou, H. Xiao, J. Shi and H. Liu, J. Hazard. Mater., 133, 262 (2006).
S.Y. Quek, D.A.J. Wasal and C.F. Forster, Water Strategic Areas, 24, 251 (1998).
G. Mckay, M.S. Otterburn and Sweeney, Water Res., 14, 15 (1980).
A. Zubair, H.N. Bhatti, M.A. Hanif and F. Shafqat, Water Air Soil Pollut., 191, 305 (2008).
J.A. Brierley, C.L. Brierley, R.F. Deeker and G.M. Goyack, European Patent Application No. 85112810, Publication No. 0181 497(1985).
Muraleedharan, Venkobachar, T.R. Muraleedharan and C. Venkobachar, Biotechnol. Bioeng., 35, 320 (1990).
K.G. Bhattacharyya and A. Sharma, J. Hazard. Mater., 113, 97 (2004).
W.J.J.R. Weber, in ed.: Slejko, Adsorption Theory, Concepts and Models, Adsorption Technology: A step-by-step Approach to Process Evalution and Application. Marcel Dekker, New York, pp. 1-35 (1985).
S. Lagergren, Handlingar, 24, 1 (1898).
Y.S. Ho and A.E. Ofomaja, J. Hazard. Mater., 129, 137 (2006).
M.H. Cheng, J.W. Patterson and R.E. Minear, J. Water Pollut. Cont. Federat., 47, 362 (1975).
B. Benguella and H. Benaissa, Water Res., 36, 2463 (2002).