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A Highly Selective Aldol Condensation of Cyclopentanone with Valeraldehyde Over Hydrotalcite-type Catalysts
Corresponding Author(s) : X. Peng
Asian Journal of Chemistry,
Vol. 25 No. 7 (2013): Vol 25 Issue 7
Abstract
The aldol condensation using cyclopentanone with valeraldehyde was conducted at hydrotalcites catalysis. The catalyst was obtained by calcining the hydrotalcite precursor (Mg/Al = 3:1) at 773 K. Its reaction performance was evaluated on the various molar ratios of cyclopentanone to n-valeraldehyde. A good catalytic selectivity of 90 % and a high conversion of 93 % were achieved under mild conditions.
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- U. Ravid and R. Ikan, J. Org. Chem., 39, 2637 (1974).
- H. Hagiwara, J. Hamaya, T. Hoshi and C. Yokoyama, Tetrahedron Lett., 46, 393 (2005).
- M. Hasnia, G. Prado, J. Rouchaud, P. Grange, M. Devillers and S. Delsarte, J. Mol. Catal. A, 247, 116 (2006).
- R.A. Wilson and B. Mookherjee, U.S. Patent 4260830 (1981).
- K.K. Rao, M. Gravelle and J.S. Valente, J. Catal., 173, 115 (1998).
- E. Dumitriu, V. Hulea and C. Chelaru, Appl. Catal. A, 178, 145 (1999).
- D. Tichit, D. Lutic and B. Coq, J. Catal., 219, 167 (2003).
- J.C.A.A. Roelofs, A.J.V. Dillen and K.P.D. Jong, Catal. Today, 60, 297 (2000).
- V.V. Brei, O.V. Melezhyk, G.M. Starukh, E.I. Oranskaya and P.A. Mutovkin, Micropor. Mesopor. Mater., 113, 411 (2008).
- C. Yonggui, T. Steven, E.B. Scroggins and M.J.F. Jean, J. Am. Chem. Soc., 130, 17287 (2008).
- J.J. Shrikhande, M.B. Gawande and R.V. Jayaran, Catal. Commun., 9, 1010 (2008).
- S. Bhagat, R. Sharma and A.K. Chakraborti, J. Mol. Catal. A, 260, 235 (2006).
- N. Iranpoor and F. Kazemi, Tetrahedron, 54, 9475 (1998).
- P. Kustrowski, D. Sulkowska, L. Chmielarz and R. Dziembaj, Appl. Catal. A, 302, 317 (2006).
- M.J. Climent, A.C.V. Fornes and R. Guil-Lopez, Adv. Synth. Catal., 344, 1090 (2002).
- C.N. Perez, C.A. Henriques, O.A.C. Antunes and J.L.F. Monteiro, J. Mol. Catal. A, 233, 83 (2005).
References
U. Ravid and R. Ikan, J. Org. Chem., 39, 2637 (1974).
H. Hagiwara, J. Hamaya, T. Hoshi and C. Yokoyama, Tetrahedron Lett., 46, 393 (2005).
M. Hasnia, G. Prado, J. Rouchaud, P. Grange, M. Devillers and S. Delsarte, J. Mol. Catal. A, 247, 116 (2006).
R.A. Wilson and B. Mookherjee, U.S. Patent 4260830 (1981).
K.K. Rao, M. Gravelle and J.S. Valente, J. Catal., 173, 115 (1998).
E. Dumitriu, V. Hulea and C. Chelaru, Appl. Catal. A, 178, 145 (1999).
D. Tichit, D. Lutic and B. Coq, J. Catal., 219, 167 (2003).
J.C.A.A. Roelofs, A.J.V. Dillen and K.P.D. Jong, Catal. Today, 60, 297 (2000).
V.V. Brei, O.V. Melezhyk, G.M. Starukh, E.I. Oranskaya and P.A. Mutovkin, Micropor. Mesopor. Mater., 113, 411 (2008).
C. Yonggui, T. Steven, E.B. Scroggins and M.J.F. Jean, J. Am. Chem. Soc., 130, 17287 (2008).
J.J. Shrikhande, M.B. Gawande and R.V. Jayaran, Catal. Commun., 9, 1010 (2008).
S. Bhagat, R. Sharma and A.K. Chakraborti, J. Mol. Catal. A, 260, 235 (2006).
N. Iranpoor and F. Kazemi, Tetrahedron, 54, 9475 (1998).
P. Kustrowski, D. Sulkowska, L. Chmielarz and R. Dziembaj, Appl. Catal. A, 302, 317 (2006).
M.J. Climent, A.C.V. Fornes and R. Guil-Lopez, Adv. Synth. Catal., 344, 1090 (2002).
C.N. Perez, C.A. Henriques, O.A.C. Antunes and J.L.F. Monteiro, J. Mol. Catal. A, 233, 83 (2005).