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Synthesis and Crystal Structure of 3,3'-Dimethyloxy-1,1'-[butane-1,4-diyldioxybis(nitrilomethylidyne)]dibenzene
Corresponding Author(s) : Li Wang
Asian Journal of Chemistry,
Vol. 25 No. 7 (2013): Vol 25 Issue 7
Abstract
The compound 3,3'-dimethyloxy-1,1'-[butane-1,4-diyldioxybis(nitrilomethylidyne)]dibenzene with the m.f. C20H24N2O4, was synthesized by the reaction of 3-methoxybenzaldehyde with 1,4-bis(aminooxy)butane in ethanol. The molecule, which lies about an inversion centre, adopts a linear structure, in which the oxime groups and benzene ring systems assume an anti conformation. The intramolecular interplanar distance between parallel benzene rings is 0.901(3) Å. Weak intermolecular C10-H10B···O2 hydrogen bonds link two other molecules into infinite zig-zag supramolecular structure.
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- S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002).
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References
S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002).
W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transition Met. Chem., 37, 271 (2012).
H. Miyasaka, N. Matsumoto, H. Okawa, N. Re, E. Gallo and C. Floriani, J. Am. Chem. Soc., 118, 981 (1996).
P.G. Lacroix, Eur. J. Inorg. Chem., 339 (2001).
T.K. Ronson, H. Adams and M.D. Ward, Inorg. Chim. Acta, 358, 1943 (2005).
A.K. Sharma, F. Lloret and R. Mukherjee, Inorg. Chem., 46, 5128 (2007).
C. Policar, F. Lambert, M. Cesario and I. Morgenstern-Badarau, Eur. J. Inorg. Chem., 12, 2201 (1999).
D.A. Atwood and M.J. Harvey, Chem. Rev., 101, 37 (2001).
W.K. Dong, X.N. He, C.M. Dong, L. Wang, J.K. Zhong, X. Chen and T.Z. Yu, Z. Kristallogr. New Cryst. Struct., 222, 289 (2007).
W.K. Dong, X.N. He, Y.X. Sun, L. Xu and Y.H. Guan, Acta Cryst., E64, o1917 (2008).
W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009).
H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z. Naturforsch., 66b, 1049 (2011).
W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009).
W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009)