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Effect of Tertiary Amines on the Hydrolysis Kinetics of Benzoyl Chloride in Water-Dioxane Solutions
Corresponding Author(s) : Mohammad A. Batiha
Asian Journal of Chemistry,
Vol. 25 No. 7 (2013): Vol 25 Issue 7
Abstract
The main object of this study was to study the effect of pyridine, 2-methyl pyridine, 3-methyl pyridine, 2,6-dimethyl pyridine, quinoline and tribenzylamine on the hydrolysis kinetics of benzoyl chloride in water-dioxane solutions. The investigation has been made by means of gas-liquid chromatography measurements. Almost equal rate constants have been determined for the hydrolysis reaction of benzoyl chloride in dioxane solutions. The catalytic effect of the studied range of tertiary amines on the hydrolysis reaction of benzoyl chloride was determined.
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References
G. Berger and S.C.J. Olivier, Rec. Trav. Chim. Pays-Bas, 46, 516 (1927).
S.G. Éntelis, R.P. Tiger, E. Ya. Nevel'skii and I.V. Épel'baum, Russ. Chem. Bull., 12, 223 (1962).
R.F. Hudson and J.E. Wardill, J. Chem. Soc., 1729 (1950).
B.L. Archer and R.F. Hudson, J. Chem. Soc., 3259 (1950).
D.A. Brown and R.F. Hudson, J. Chem. Soc., 883 (1953).
D.A. Brown and R.F. Hudson, J. Chem. Soc., 3352 (1953).
B.L. Archer, R.F. Hudson and J.E. Wardill, J. Chem. Soc., 888 (1953).
M. Wang, C. Ou and J. Jwo, Mol. Catal. A: Chem., 99, 153 (1995).
E.M. Cherkasova, S.V. Bogatkov and Z.P. Golovina, Russ. Chem. Rev., 46, 246 (1977).
L. Kuritsyn, Problems of Kinetics and Catal., 1, 25 (1973).
H.K. Vorobuv, O.K. Shebanova and N.E. Zabolotskaya, Chem. Chem. Technol., 17, 814 (1974).
O.K. Shebanova and H.C. Ivanova, Chem. Chem. Technol., 25, 699 (1982).
O.K. Shebanova and E.V. Kulibaba, Diponirovan, 709, 85 (1985).