Issue

Vol. 25 No. 7 (2013): Vol 25 Issue 7

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Spectrophotometric Determination of Magnesium(II) with m-Acetylchlorophosphonazo

https://doi.org/10.14233/ajchem.2013.14475
Qing-Zhou Zhai
Research Center for Nanotechnology, South Campus, Changchun University of Science and Technology, 7186 Weixing Road, Changchun 130022, P.R. China
Jing-Mei Li
Research Center for Nanotechnology, South Campus, Changchun University of Science and Technology, 7186 Weixing Road, Changchun 130022, P.R. China
Wei-Qiang Sun
Research Center for Nanotechnology, South Campus, Changchun University of Science and Technology, 7186 Weixing Road, Changchun 130022, P.R. China

Corresponding Author(s) : Qing-Zhou Zhai

zhaiqingzhou@163.com

Asian Journal of Chemistry, Vol. 25 No. 7 (2013): Vol 25 Issue 7

Abstract

The optimum conditions of spectrophotometric determination of Mg(II) with m-acetylchlorophosphonazo (CPAmA) were studied. In a medium of pH 10.5 NH3-NH4Cl, the maximum absorption peak of Mg (II)-CPAmA complex is located at 610 nm. At this wavelength, Beer's law is obeyed over the range of 0-1.5 μg/mL of Mg(II) and the apparent molar absorptivity of the complex is 2.99 × 104 L mol-1 cm-1. Detection limit of the method is 7.71 ng/mL. When the proposed method was used to determine magnesium in serums, the determined results were in good agreement with those obtained by atomic absorption spectrometry. The recovery of the standard addition for the determination of serum sample by the present method was 97.59-99.71 % and the relative standard deviation for eleven replicate determinations was 1.36-3.47 %. The analytical results were satisfactory.

Keywords

m-Acetylchlorophosphonazo Magnesium Spectrophotometry Serum
Zhai, Q.-Z., Li, J.-M., & Sun, W.-Q. (2013). Spectrophotometric Determination of Magnesium(II) with m-Acetylchlorophosphonazo. Asian Journal of Chemistry, 25(7), 4080–4082. https://doi.org/10.14233/ajchem.2013.14475
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. T. Xu and C.B. He, Stud. Trace Elements Health, 21, 60 (2004).
  2. T. Xu and C.B. He, Guangdong Trace Elements Sci., 10, 11 (2003).
  3. Y.Z. He, J. Hengshui Univ., 4, 55 (2008).
  4. N. Peerzada and E. Kozlik, Anal. Lett., 23, 1087 (1990).
  5. S.R. Liu and X.L. Xu, Chin. J. Anal. Chem., 24, 94 (1996).
  6. Y. Yuang, Chin. J. Anal. Chem., 12, 1052 (1989).
  7. J.Y. Zhuang, Z.D. Su, J.S. Li and Q.H. Pan, Chin. J. Anal. Chem., 12, 701 (1989).
  8. J.H. Yu, PPTCA (Part B: Chem. Anal.), 34, 387 (1998).
  9. C.M. Zhang, K. Gu, B.X. Wang, Z. Li and G.Y. Yang, Chin. J. Spectr. Lab., 21, 181 (2004).
  10. B. Yang, F. Liu, J. Pu, X.F. Li and J.Y. Yin, Chin. J. Spectr. Lab., 21, 191 (2004).
  11. J.M. Li, Q.Z. Zhai and G.Q. Zhang, Asian J. Chem., 22, 4855 (2010).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0