Synthesis and Crystal Structure of [Y(C6H4NO2)2(H2O)4]n&middot;nCl

Wen-Tong Chen; Zhi-Gang Luo

doi:10.14233/ajchem.2013.14124

Issue

Vol. 25 No. 7 (2013): Vol 25 Issue 7

Issue Published : January 18, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of [Y(C6H4NO2)2(H2O)4]n·nCl

https://doi.org/10.14233/ajchem.2013.14124

Wen-Tong Chen

Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China

Zhi-Gang Luo

Corresponding Author(s) : Wen-Tong Chen

wtchen_2000@yahoo.cn

Asian Journal of Chemistry, Vol. 25 No. 7 (2013): Vol 25 Issue 7
Article Published : February 5, 2013

Abstract

A novel yttirium complex with the general formula [Y(C₆H₄NO₂)₂(H₂O)₄]_n·nCl (1) has been prepared via a hydrothermal synthesis method and structurally characterized by X-ray diffractions. Complex 1 crystallizes in the space group Pbcn of the orthorhombic system with four formula units in a cell: a = 8.9401(14), b = 19.576(3), c = 10.0063(13) Å, V = 1751.2(4) Å³, C₁₂H₁₆N₂O₈ClY, M_r = 440.63, D_c = 1.671 g/cm³, T = 293.15 K, F(000) = 888 and R1/wR² = 0.0421/0.0991 for 1256 observed reflections [I > 2s(I)] and 1539 unique reflections. Complex 1 features a novel one-dimensional (1-D) chain-like structure.

Keywords

Crystal Hydrothermal Yttirium Isonicotinic Supramolecule

Chen, W.-T., & Luo, Z.-G. (2013). Synthesis and Crystal Structure of [Y(C6H4NO2)2(H2O)4]n·nCl. Asian Journal of Chemistry, 25(7), 4077–4079. https://doi.org/10.14233/ajchem.2013.14124

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