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Aggregates Morphologies of Poly(g-benzyl L-glutamate)-graft-poly(ethylene glycol) and Poly(g-benzyl L-glutamate) Mixtures in Dilute Solution
Corresponding Author(s) : Fa-Gang Wang
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
Poly(g-benzyl L-glutamate) (PBLG) homopolymer and poly(g-benzyl L-glutamate)-graft-poly( ethylene glycol) (PBLG-graft-PEG) copolymer were synthesized by a standard N-carboxyl- g-benzyl-L-glutamate anhydride method and by ester exchange reaction, respectively. The aggregates morphologies of PBLG-graft-PEG and PBLG mixtures in dilute solution were studied by scanning electron microscopy. The effects of the weight (wt) ratio of PBLG-graft-PEG to PBLG, various solvent system and the addition of denaturant acid on the aggregates morphologies of the PBLG-graft-PEG and PBLG mixtures in the dilute solution were investigated.
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- D.M. Tang, J.P. Lin, S.L. Lin, S.N. Zhang, T. Chen and X.H. Tian, Macromol. Rapid Commun., 25, 1241 (2004).
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- C.S. Cho, J.W. Nah, Y.I. Jeong, J.B. Cheon, S. Asayama, H. Ise and T. Akaike, Polymer, 40, 6769 (1999).
- G.Q. Zhu, Chem. Pap., 63, 683 (2009); 64, 34 (2010).
- G.Q. Zhu, Fiber. Polym., 10, 425 (2009).
- M. Moffitt and A. Eisenberg, Macromolecules, 30, 4363 (1997).
- K. Jokei, M. Oka, T. Hayashi and Y. Miyachi, Eur. Polym. J., 35, 945 (1999).
- Y. Miyachi, K. Jokei, M. Oka and T. Hayashi, Eur. Polym. J., 35, 767 (1999).
- J. Sun, X.S. Chen, J.S. Guo, Q. Shi, Z.G. Xie and X.B. Jing, Polymer, 50, 455 (2009).
- F. Rybnikar and P.H. Geil, Biopolymers, 11, 271 (1972).
- J.J.B.P. Blais and P.H. Geil, J. Ultrastruct. Res., 22, 303 (1968).
- A. Abe and T. Yamazaki, Macromolecules, 22, 2138 (1989).
- Y. Tajima, J.M. Anderson and P.H. Geil, Int. J. Biol. Macromol., 2, 186 (1980).
References
D.M. Tang, J.P. Lin, S.L. Lin, S.N. Zhang, T. Chen and X.H. Tian, Macromol. Rapid Commun., 25, 1241 (2004).
C.S. Cho, J.B. Cheon, Y.I. Jeong, I.S. Kim, S.H. Kim and T. Akaike, Macromol. Rapid Commun., 18, 361 (1997).
C.S. Cho, J.W. Nah, Y.I. Jeong, J.B. Cheon, S. Asayama, H. Ise and T. Akaike, Polymer, 40, 6769 (1999).
G.Q. Zhu, Chem. Pap., 63, 683 (2009); 64, 34 (2010).
G.Q. Zhu, Fiber. Polym., 10, 425 (2009).
M. Moffitt and A. Eisenberg, Macromolecules, 30, 4363 (1997).
K. Jokei, M. Oka, T. Hayashi and Y. Miyachi, Eur. Polym. J., 35, 945 (1999).
Y. Miyachi, K. Jokei, M. Oka and T. Hayashi, Eur. Polym. J., 35, 767 (1999).
J. Sun, X.S. Chen, J.S. Guo, Q. Shi, Z.G. Xie and X.B. Jing, Polymer, 50, 455 (2009).
F. Rybnikar and P.H. Geil, Biopolymers, 11, 271 (1972).
J.J.B.P. Blais and P.H. Geil, J. Ultrastruct. Res., 22, 303 (1968).
A. Abe and T. Yamazaki, Macromolecules, 22, 2138 (1989).
Y. Tajima, J.M. Anderson and P.H. Geil, Int. J. Biol. Macromol., 2, 186 (1980).