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Optimization of Molecularly Imprinted Poly (MAA-co-AM) Composite Membranes for Evaluation of Chlorimuron-Ethyl Herbicide
Corresponding Author(s) : Zheng-Hao Liu
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
Several experimental conditions, such as reaction solvent, extraction solvent, extraction time and crosslinker were evaluated and optimized in the preparation molecularly imprinted composite membranes using chlorimuron-ethyl herbicide as the template. The structures and the thermal stability of molecularly imprinted composite membranes were characterized by infrared spectroscopy and thermogravimetric analysis. The static equilibrium binding properties of the membranes to chlorimuron-ethyl and the swelling property of the membrane in different solvents were tested. The Scatchard plot revealed that one class of binding sites was mainly produced in the imprinted composite membrane in the studied concentration range of chlorimuron-ethyl herbicide.
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References
M.J. Whitcombe, M.E. Rodriguez, P. Villar and E.N. Vulfson, J. Am. Chem. Soc., 117, 7105 (1995).
T. Takeuchi, T. Mukawa, J. Matsui, M. Higashi and K.D. Shimizu, Anal. Chem., 73, 3869 (2001).
E.P.C. Lai, Z.D. Maleki and S. Wu, J. Appl. Polym. Sci., 116, 1499 (2010).
R. Arshady and K. Mosbach, Makromol. Chem., 182, 687 (1981).
D.S. Wang, Q. Wei, Y. Zhang and C. Zhao, J. Appl. Polym. Sci., 114, 4036 (2009).
K. Tanabe, T. Takeuchi, J. Matsui, K. Ikebukuro, K. Yano and I. Karube, J. Chem. Soc. Chem. Commun., 2303 (1995).
R. Kielczynski and M. Bryjak, Sep. Purif. Tech., 41, 231 (2005).
X. Wu, K. Goswami and Ken D. Shimizu, J. Mol. Recognit., 21, 410 (2008).
S.A. Piletsky, I.Y. Dubey, D.M. Fedoryak and V.P. Kukhar, Biopolym. Kletka, 6, 55 (1990) (In Russian).
J.M. Hong, P.E. Anderson, J. Qian and C.R. Martin, Chem. Mater., 10, 1029 (1998).
P. Wang, W. Hu and W. Su, Anal. Chim. Acta, 615, 54 (2008).
S.A. Piletsky, H. Matuschewski, U. Schedler and A. Wilpert, Macromolecules, 33, 3092 (2000).
K.J. Mathew and K.J. Shea, J. Am. Chem. Soc., 118, 8154 (1996).
M. Yoshikawa, T. Fujisawa, J. Izumi and T. Kitao, Anal. Chim. Acta, 365, 59 (1998).
W. Zhang, J.J. Wang and Z.M. Zhang, Sci. Agric. Sinica, 40, 1730 (2007).
X.M. Shi and X.W. Xu, Pollut. Control Technol., 22, 89 (2009).
C. Wu, L. Gao, G. Wang, B. Chen and Q. Zhang, Pest Sci. Adv., 25, 6 (2006).
F. Trotta, C. Baggiani, M.P. Luda, E. Drioli and T. Massari, J. Membr. Sci., 254, 13 (2005).
G. Scatchard, Ann. N.Y. Acad. Sci., 51, 660 (1949).
Z.H. Zhang, Y.F. Hu, H.B. Zhang, H. Li and S.Z. Yao, Acta Chimica Sinica, 67, 2121 (2009).
C. Yu and K. Mosbach, J. Org. Chem., 62, 4057 (1997).
J. Zhou, X.W. He and Y.J. Li, Anal. Chim. Acta, 394, 353 (1999).