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Synthesis of 3-(4-Methyl-phenyl)-2-phenyl-3,4-dihydro-2H-benzo[e][1,3,2]oxazaphosphinine and Its Chalcogenides
Corresponding Author(s) : Arif Ali Khan
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
A simple method for the synthesis of 3-(4-methyl-phenyl)-2-phenyl-3,4-dihydro-2H-benzo[ e][1,3,2]oxazaphosphinine (2) is described. P-Chalcogenides of (2) can be prepared by reacting with S, Se powder in toluene at 110 ºC. Whereas the tungsten pentacarbonyl complex (6) can be prepared by reacting (2) with W(CO)5CH3CN in THF at 20-25 ºC.
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- A.A. Prishchenko and M.V. Livantsov, Abstracts of XIVTH International Conference on Phosphorus Chemistry, Cincinnati, Ohio, p. 213 (1998).
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- B.S. Kumar, A.U.R. Sankar, G.C.S. Reddy, M.V.N. Reddy, C.D. Reddy and C.S. Reddy, ARKIVOC, 109 (2008).
- K.R.K.K. Reddy, C.B. Reddy, K.S. Kumar, C.N. Raju and C.S. Reddy, Org. Commun., 2, 28 (2009).
- K.R.K.K. Reddy, G.S. Prasad, M.A. Kumar, C.S. Reddy and C.N. Raju, E-J. Chem., 5, 1025 (2008).
- S.J. Joglekar and S.D. Samant, J. Indian Chem. Soc., 65, 110 (1988).
- A.A. Khan, C. Wismach, P.G. Jones and R. Streubel, J. Chem. Soc., Dalton Trans., 2483 (2003).
- A.A. Khan, C. Neumann, C. Wismach, P.G. Jones and R. Streubel, J. Organomet. Chem., 682, 212 (2003).
References
D.L. Quin, The Heterocyclic Chemistry of Phosphorus (Wiley, New York, p. 21 (1981).
A.A. Prishchenko and M.V. Livantsov, Abstracts of XIVTH International Conference on Phosphorus Chemistry, Cincinnati, Ohio, p. 213 (1998).
S.M. Ludeman, V.L. Boyd, J.B. Regan, L.N. Gallo, G. Zon and K. Ishii, J. Med. Chem., 29, 716 (1986).
B.F. Schmidt, W.C. Tang and G. Eisenbrand, Synthesis, 701 (1962).
H. Kivela, Z. Zalam, P. Tahtinen, R. Sillanpaa, F. Fulop and K. Pihalaja, Eur. J. Org. Chem., 6, 1189 (2005).
B.S. Kumar, A.U.R. Sankar, G.C.S. Reddy, M.V.N. Reddy, C.D. Reddy and C.S. Reddy, ARKIVOC, 109 (2008).
K.R.K.K. Reddy, C.B. Reddy, K.S. Kumar, C.N. Raju and C.S. Reddy, Org. Commun., 2, 28 (2009).
K.R.K.K. Reddy, G.S. Prasad, M.A. Kumar, C.S. Reddy and C.N. Raju, E-J. Chem., 5, 1025 (2008).
S.J. Joglekar and S.D. Samant, J. Indian Chem. Soc., 65, 110 (1988).
A.A. Khan, C. Wismach, P.G. Jones and R. Streubel, J. Chem. Soc., Dalton Trans., 2483 (2003).
A.A. Khan, C. Neumann, C. Wismach, P.G. Jones and R. Streubel, J. Organomet. Chem., 682, 212 (2003).