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Assembly of 1D Cadmium(II) Coordination Polymer with Bis(2-benzimidazole) and 1,3-Benzenedicarboxylic Acid Mixed Ligands
Corresponding Author(s) : Guo-Dong Feng
Asian Journal of Chemistry,
Vol. 25 No. 6 (2013): Vol 25 Issue 6
Abstract
A novel one-dimensional cadmium(II) compound: {[CdL(H2C2EIm)(H2O)](H2O)2}n (1) with 1,3-benzene dicarboxylic acid (H2L) and 2,2'-(1,2-ethanediyl)bis(1H-benzimidazole) (H2C2EIm) has been synthesized by means of hydrothermal method and characterized by X-ray single-crystal diffraction. The crystal belongs to the triclinic system triclinic, space group P-1 with a = 1.0189(5) nm, b = 1.1204(5) nm, c = 1.2319(5) nm, a = 115.824(5)º, b = 98.363(5)º, g = 102.654(5)º, V = 1.1878(9) nm3, Dc = 1.649 g cm-3, Z = 2, F(000) = 594, Goof= 0.997, R1 = 0.0358, wR2 = 0.0881. The compound 1 shows a novel one-dimensional (1D) chain structure along the c axis and further extended into a 1D double chain structure through p-p packing interactions. The intermolecular hydrogen bonds contribute to the formation of the three-dimensional supramolecular architecture and stabilize the crystal structure.
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- O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae and M. Eddaoudi, J. Kim. Nat., 423, 705 (2003).
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- Z.Q. Jiang, Asian J. Chem., 25, 2353 (2013).
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- L. Jiang, Z.X. Li and Z.M. Su, Inorg. Chem. Commun., 14, 1077 (2011).
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References
O.M. Yaghi, M. O'Keeffe, N.W. Ockwig, H.K. Chae and M. Eddaoudi, J. Kim. Nat., 423, 705 (2003).
A.J. Blake, N.R. Champness, P. Hubberstey, W.S. Li, M.A. Withersby and M. Schröder, Coord. Chem. Rev., 183, 117 (1999).
Y.-P. Hu, C.-P. Tan, S.-F. Wang and X.-B. Meng, Asian J. Chem., 25, 1137 (2013).
Z.Q. Jiang, Asian J. Chem., 25, 2353 (2013).
R. Wang, L. Han, F. Jiang, Y. Zhou, D. Yuan and M. Hong, Cryst. Growth Des., 5, 129 (2005).
(a) J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim (1995); (b) J.W. Steed and J.L. Atwood, Supramolecular Chemistry, Wiley, New York (2000).
(a) J.C. MacDonald, P.C. Dorrestein, M.M. Pilley, M.M. Foote, J.L. Lundburg, R.W. Henning, A.J. Shultz and J.L. Manson, J. Am. Chem. Soc., 122, 11692 (2000); (b) J.C. Noveron, M.S. Lak, R.E. Del Sesto, A.M. Miller and P.J. Stang, J. Am. Chem. Soc., 124, 6613 (2002).
J.Y. Lu and V. Schauss, Inorg. Chem. Commun., 6, 1332 (2003).
Y.-B. Wang, X.-J. Zheng, W.-J. Zhuang and L. Jin, Eur. J. Inorg. Chem., 1355 (2003).
V. Arora, M. Gupta and P. Mathur, Indian J. Chem., 38, 1219 (1999).
G.A. van Albada, M.T. Lakin, N. Veldman, A.L. Spek and J. Reedijk, Inorg. Chem., 34, 4910 (1995).
G.A. van Albada, N. Veldman, A.L. Spek and J. Reedijk, J. Chem. Crystallogr., 30, 69 (2000).
L. Jiang, Z.X. Li and Z.M. Su, Inorg. Chem. Commun., 14, 1077 (2011).
V.A. Blatov, L. Carlucci, G. Ciani and D.M. Proserpio, Cryst. Eng. Comm., 6, 378 (2004).
M. Du, X.J. Jiang and X.J. Zhao, Inorg. Chem., 45, 3998 (2006).
L.Y.W. Lilian and M.J. Madeleine, J. Am. Chem. Soc., 79, 5706 (1957).
T. Higashi, Program for Absorption Correction, Rigaku Corporation, Tokyo, Japan, (1995).
SHELXTL, Version 5.1, Siemens Industrial Automation, Inc. (1997).
G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).
I.P. Santos and L.M.L. Marzan, Langmuir, 15, 948 (1999)