Issue

Vol. 25 No. 5 (2013): Vol 25 Issue 5

Copyright (c) 2013 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Cationic Polymerization of 1,3-Pentadiene in Presence of AlCl3/SbCl3

https://doi.org/10.14233/ajchem.2013.13667
G.Q. Wang
College of Automotive Engineering, Dalian Science and Technology University, Dalian 116024, P.R. China
W.X. Zhang
College of Automotive Engineering, Dalian Science and Technology University, Dalian 116024, P.R. China
J.C. Liang
College of Automotive Engineering, Dalian Science and Technology University, Dalian 116024, P.R. China
G.Y. Chen
College of Automotive Engineering, Dalian Science and Technology University, Dalian 116024, P.R. China
Z.Y. Wei
College of Automotive Engineering, Dalian Science and Technology University, Dalian 116024, P.R. China
Long Zhang
School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P.R. China

Corresponding Author(s) : Long Zhang

zhanglongzhl@163.com

Asian Journal of Chemistry, Vol. 25 No. 5 (2013): Vol 25 Issue 5

Abstract

The cationic polymerization of 1,3-pentadiene using AlCl3/SbCl3 binary catalyst mainly carried out at various SbCl3 concentrations. With an increase in the SbCl3 concentration, the molecular weight decreased and molecular mass distribution of the polymer widened, that is consistent with b-pinene. It is shown that the degree of unsaturation of poly(1,3-pentadiene) are almost independent of the SbCl3 concentrations.

Keywords

Cationic polymerization 1,3-Pentadiene
Wang, G., Zhang, W., Liang, J., Chen, G., Wei, Z., & Zhang, L. (2012). Cationic Polymerization of 1,3-Pentadiene in Presence of AlCl3/SbCl3. Asian Journal of Chemistry, 25(5), 2690–2692. https://doi.org/10.14233/ajchem.2013.13667
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. F. Duchemin, V.B. Celton, H. Cheradame, C. Merienne and A. Macedo, Macromolecules, 31, 7627 (1998).
  2. J. Santarella, E. Rousset, S. Randriamahefa,A. Macedo and H. Cheradame, Eur. Polym. J., 36, 2715 (2000).
  3. T. Higashimura, J. Lu, M. Kamigaito, M. Sawamoto and Y.X. Deng, Makromol. Chem., 193, 2311 (1992).
  4. T. Higashimura, J. Lu, M. Kamigaito, M. Sawamoto and Y.X. Deng, Makromol. Chem., 194, 3441 (1993).
  5. T. Higashimura, J. Lu, M. Kamigaito, M. Sawamoto and Y.X. Deng, Makromol. Chem., 194, 3455 (1993).
  6. J. Lu, M. Kamigaito, M. Sawamoto, T. Higashimura and Y.X. Deng, J. Appl. Polym. Sci., 61, 1011 (1996).
  7. Y.X. Peng, J.L. Liu, L.R. Cun and H.S. Dai, Polym. Bull., 35, 393 (1995).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0