Synthesis, Characterization and Thermal Behaviour of Amino Functional Polymers from 4-Chloromethyl Styrene Polymers

M.H. Nasirtabrizi; Z. Ghashangi; A. Parchehbaf Jadid; M. Nouri Molalar

doi:10.14233/ajchem.2013.13591

Issue

Vol. 25 No. 5 (2013): Vol 25 Issue 5

Issue Published : November 26, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Characterization and Thermal Behaviour of Amino Functional Polymers from 4-Chloromethyl Styrene Polymers

https://doi.org/10.14233/ajchem.2013.13591

M.H. Nasirtabrizi

Department of Applied Chemistry, Ardabil Branch, Islamic Azad University, Ardabil, Iran

Z. Ghashangi

Young Researcher Club, Islamic Azad University Ardabil Branch, Ardabil, Iran

A. Parchehbaf Jadid

Department of Applied Chemistry, Ardabil Branch, Islamic Azad University, Ardabil, Iran

M. Nouri Molalar

Young Researcher Club, Islamic Azad University Ardabil Branch, Ardabil, Iran

Corresponding Author(s) : M.H. Nasirtabrizi

nasirtabrizi@gmail.com

Asian Journal of Chemistry, Vol. 25 No. 5 (2013): Vol 25 Issue 5
Article Published : December 11, 2012

Abstract

The 4-chloromethyl styrene was copolymerized with different styrenes monomers such as styrene, methyl styrene and 4-methoxy styrene by free radical polymerization at 70 ± 1 ºC using a,a'-azobis(isobutyronitrile) (AIBN) as an initiator and the copolymers I, II and III collected, respectively. The copolymer compositions were characterized by ¹H NMR spectra and the polydispersity of the copolymers were determined using gel permeation chromatography. The phthalimide substituents were attached to the obtained copolymers with replacement of all the chlorine atoms in 4-chloromethyl styrene units. The hydrolysis of those polymers gave poly(4-aminomethyl styrene). The polymers, obtained in quantitative yields, were characterized by FTIR, ¹H NMR spectroscopy and dynamic mechanical thermal analysis. All the polymers containing phthalimide groups and amino groups showed a high glass transition temperature (in the range 140-150 ºC) and (in the range 120-130 ºC), respectively in comparison with copolymers I-III (in the range 75-95 ºC).

Keywords

Amino function polymers 4-Chloromethyl styrene Dynamic mechanical thermal analysis Phthalimide

Nasirtabrizi, M., Ghashangi, Z., Parchehbaf Jadid, A., & Nouri Molalar, M. (2012). Synthesis, Characterization and Thermal Behaviour of Amino Functional Polymers from 4-Chloromethyl Styrene Polymers. Asian Journal of Chemistry, 25(5), 2651–2656. https://doi.org/10.14233/ajchem.2013.13591

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K.D. Safa, H.A. Eram and M.H. Nasirtabrizi, Iran. Polym. J., 15, 249 (2006).

J.Y. Dong, E. Manias and T.C. Chung, Macromol., 35, 3439 (2002).

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L.A. Worl, WE. Jones, G.F. Strouse, J.N. Younathan, E. Danielson and K.A. Maxwell, Inorg. Chem., 38, 2705 (1999).

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A. Kanazawa, T. Ikeda and T. Endo, J. Polym. Sci. A: Polym. Chem., 31, 2873 (1993).

M. Babazadeh, J. Appl. Polym. Sci., 102, 633 (2006).

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C.M. Cheng, M.I. Egbe, J.M. Grasshoff, D.J. Guarrera, R.P. Pai and J.C. Warner, J. Polym. Sci. A: Polym. Chem., 33, 2515 (1995).

C. Noel, K.C. Ching, M. Large, D. Reyx and F. Kajzar, Macromol. Chem. Phys., 198, 1665 (1997).

K. Kihara, H. Toda, M. Mori, M. Hashimoto and S. Mizogami, Eur. J. Med. Chem., 23, 411 (1988).

M.H. Tabrizi, S. Davaran and A. Entezami, Iran. Polym. J., 5, 243 (1996).

R. Jayakumar, R. Balaji and S. Nanjundan, Eur. Polym. J., 36, 1659 (2000).

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M. Ismail, V. Veena and K.R. Animesh, J. Appl. Polym. Sci., 62, 217 (1998).

K. Ohno, Y. Izu, Y. Tsujii, T. Fukuda and H. Kitano, Eur. Polym. J., 40, 81 (2004).

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M. Guntupallia, C.W. Wilkins and P.E. Cassidya, Int. J. Polym. Mater., 57, 442 (2008).

A. Parthiban, A. Le Guen, Y. Yansheng, U. Hoffmann, M. Klapper and K. Müllen, Macromol., 30, 2238 (1997).

Issue

Vol. 25 No. 5 (2013): Vol 25 Issue 5

Synthesis, Characterization and Thermal Behaviour of Amino Functional Polymers from 4-Chloromethyl Styrene Polymers

Corresponding Author(s) : M.H. Nasirtabrizi

Abstract

Keywords

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