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Removal of Orthophosphate from Municipal Wastewater Using Chemical Precipitation Process in Ahvaz Wastewater Treatment Plant, Iran
Corresponding Author(s) : Afshin Takdastan
Asian Journal of Chemistry,
Vol. 25 No. 5 (2013): Vol 25 Issue 5
Abstract
Phosphate removal such as orthophosphate, from municipal wastewater has become an environmental necessity, since the excessive phosphate ion content in municipal wastewater causes water eutrophication. According to environmental protection organization of Iran, maximum permissible concentration of residual phosphorus in treated municipal wastewater is 1 mg/L P. Almost all the phosphorus in natural water and wastewater is available in the form of phosphate. Phosphorus compounds in wastewater, after hydrolysis and biodegradation, change to solution orthophosphates. In this research, poly aluminium chloride and bentonite clay as nature coagulant were added and with low chemical cost, bentonite effect in improving poly aluminium chloride in municipal wastewater treatment, has been investigated. The research is a bench scale experimental type. Samples were collected from influent wastewater to primary and effluent of secondary clarifier and then effect of pH and dose of coagulant investigated on orthophosphate removal efficiency. The result show optimal conditions of compound of polyaluminium chloride and bentonite for removal of orthophosphate, COD, BOD and TSS in pH = 7 and optimal dose 15.55 mg/L polyaluminium chloride and 5.55 mg/L bentonite in influent wastewater to primary clarifier has been obtained 71.83, 46.1, 48.9 and 63.5 %, respectively. Under optimal condition, orthophosphate concentration was reached to 1 mg/L. So this compound coagulant, in lowest dose and consequently chemical cost decrease, was selected as suitable coagulant in removal of orthophosphate of effluent of treatment plant.
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- Enviromental Protection Organization of Iran, Executive Bylaws for Paragraph(C) of Article 104 and Article 134 of the Third-5 year plan of the Islamic Republic of Iran (2001).
- D.J. Conley, H.W. Paerl, R.W. Howarth, D.F. Boesch, S.P. Seitzinger, K.E. Havens, C. Lancelot and G.E. Likens, Science, 323, 1014 (2009).
- R.K. Linsley, J.B. Franzini, D.L. Freyberg and G. Tchobanoglous, Water Resources Engineering, McGraw-Hill, Singapore, edn 4, pp. 154-166 (1992).
- O. Mahmut and S. Ayhan, Turk. J. Eng. Environ. Sci., 27, 227 (2003).
- J.Q. Jiang and N.J. Graham, Water SA, 24, 237 (1998).
- J-.S. Nam and C.Y. Kim, J. Non-Crystalline Solids, 354, 5009 (2008).
- M. Koiv, M. Liira, U. Mander, R. Motleb, C. Vohla and K. Kirsimae, Water Res., 44, 5232 (2010).
- L. Lupa, P. Negrea, A. Negrea, A. Iovi, L. Cocheci and G. Mosoarca, J. Chem. Eng., 25, 9 (2008).
- D.D. Heas, M. Wentzel and Ekama, Water SA, 26, 439 (2000).
- E. Paul, M.L. Laval and M. Sperandio, Environ. Tech., 22, 1363 (2001).
- K. Howe, J.C. Crittenden, D.W. Hand, R.R. Trussell and G. Tchobanoglous, Water Treatment:Principles and Design, edn. 3, pp. 340-380 (2011).
- S. Shanawaz, Y. Yoon, G. Amy and J. Yoon, Chmosphere, 57, 1115 (2004).
- K. Mccurdy, K. Carlson and D. Gregory, Water Res., 38, 486 (2004).
- H. Sool Lee, S. Park and T. Yoon, Proc. Biochem., 38, 81 (2002).
- I. Bamidele, O. Owolabi and L. Emmanuel, J. Hazard. Mater., 184, 731 (2010).
- A.I. Zouboulis and N.D. Tzoupanos, Desalination, 250, 339 (2010).
- J.E. Wolfe and O.T. Lind, Hydrobiologia, 610, 211 (2008).
- M. James, P.L. Ebeling Sibrell, S.R. Ogden and S.T. Steven, Aquacult. Eng., 29, 23 (2003).
- AWWA, WEF, APHA, Standard Methods for the Examination of Water and WasteWater, Washington D.C, USA, edn. 21 (2005).
- A.I. Zouboulis and N.D. Tzoupanos, J. Hazard. Mater., 162, 1379 (2009).
- V. Cucurella and G. Renman, J. Environ. Qual., 38, 381 (2009).
- O.S. Amuda and I.A. Amoo, J. Hazard. Mater., 141, 778 (2007).
- H. Roques, Fondements Theoretiques du Traitement chimique des eaux, Vol. II, Ed. Technique et documentation-lavoisier, II rue Lavoisier-F 75384 Paris, Cedex 08, 40 (1990)
References
Enviromental Protection Organization of Iran, Executive Bylaws for Paragraph(C) of Article 104 and Article 134 of the Third-5 year plan of the Islamic Republic of Iran (2001).
D.J. Conley, H.W. Paerl, R.W. Howarth, D.F. Boesch, S.P. Seitzinger, K.E. Havens, C. Lancelot and G.E. Likens, Science, 323, 1014 (2009).
R.K. Linsley, J.B. Franzini, D.L. Freyberg and G. Tchobanoglous, Water Resources Engineering, McGraw-Hill, Singapore, edn 4, pp. 154-166 (1992).
O. Mahmut and S. Ayhan, Turk. J. Eng. Environ. Sci., 27, 227 (2003).
J.Q. Jiang and N.J. Graham, Water SA, 24, 237 (1998).
J-.S. Nam and C.Y. Kim, J. Non-Crystalline Solids, 354, 5009 (2008).
M. Koiv, M. Liira, U. Mander, R. Motleb, C. Vohla and K. Kirsimae, Water Res., 44, 5232 (2010).
L. Lupa, P. Negrea, A. Negrea, A. Iovi, L. Cocheci and G. Mosoarca, J. Chem. Eng., 25, 9 (2008).
D.D. Heas, M. Wentzel and Ekama, Water SA, 26, 439 (2000).
E. Paul, M.L. Laval and M. Sperandio, Environ. Tech., 22, 1363 (2001).
K. Howe, J.C. Crittenden, D.W. Hand, R.R. Trussell and G. Tchobanoglous, Water Treatment:Principles and Design, edn. 3, pp. 340-380 (2011).
S. Shanawaz, Y. Yoon, G. Amy and J. Yoon, Chmosphere, 57, 1115 (2004).
K. Mccurdy, K. Carlson and D. Gregory, Water Res., 38, 486 (2004).
H. Sool Lee, S. Park and T. Yoon, Proc. Biochem., 38, 81 (2002).
I. Bamidele, O. Owolabi and L. Emmanuel, J. Hazard. Mater., 184, 731 (2010).
A.I. Zouboulis and N.D. Tzoupanos, Desalination, 250, 339 (2010).
J.E. Wolfe and O.T. Lind, Hydrobiologia, 610, 211 (2008).
M. James, P.L. Ebeling Sibrell, S.R. Ogden and S.T. Steven, Aquacult. Eng., 29, 23 (2003).
AWWA, WEF, APHA, Standard Methods for the Examination of Water and WasteWater, Washington D.C, USA, edn. 21 (2005).
A.I. Zouboulis and N.D. Tzoupanos, J. Hazard. Mater., 162, 1379 (2009).
V. Cucurella and G. Renman, J. Environ. Qual., 38, 381 (2009).
O.S. Amuda and I.A. Amoo, J. Hazard. Mater., 141, 778 (2007).
H. Roques, Fondements Theoretiques du Traitement chimique des eaux, Vol. II, Ed. Technique et documentation-lavoisier, II rue Lavoisier-F 75384 Paris, Cedex 08, 40 (1990)