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Synthesis, Characterization and Antimicrobial Screening of Co(II), Ni(II), Cu(II), Mn(II) and Zn(II) Complexes with Schiff Base Derived from 2-Sulphanilamidopyridine and 2-Hydroxy-3-methoxybenzaldehyde
Corresponding Author(s) : G. Valarmathy
Asian Journal of Chemistry,
Vol. 25 No. 4 (2013): Vol 25 Issue 4
Abstract
The Schiff base derived from 2-sulphanilamidopyridine and 2-hydroxy-3-methoxy benzaldehyde and its metal complexes have been synthesized and characterised by IR, 1H NMR, UV, elemental analysis, molar conductance and magnetic susceptibility. The Schiff base ligand and the metal complexes were screened for antimicrobial activity by disc diffusion technique. From the analytical and spectral data, the stoichiometry has been found to be 1:2 for all the metal complexes. An octahedral structure has been proposed. All these metal complexes were found to be active against bacteria and fungi.
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- S.A. WestCott, Transition Met. Chem., 30, 411 (2005).
- Z.H. Chohah, M. Praveen and M. Ghaffar, Met. Based Drugs, 4, 267 (1997).
- De Clereq and F. Verpoort, Macromolecules, 35, 8943 (2002).
- N.N. Gulerman, S. Rollas and H. Erdeniz, J. Pharm. Sci., 26, 1 (2001).
- P. Tarasconi, R. Albertini, A. Bonati, P.P. Dall Aglio, P. Lunghi and S. Pinelli, Bioinorg. Med. Chem., 8, 154 (2000).
- M. Wang, L.F. Wang, Y.Z. Li, Q.X. Li, Z.D. Xu and D.Q. Qu, Transition Met. Chem., 26, 307 (2001).
- M. Ramesh, K.B. Chandrasekar and K.H. Reddy, Indian J. Chem., 9A, 1337 (2000).
- J. Mannad and J.C. Crabbe, Bacterial and Antibacterial agents, Spectrum Academic Publishers, Oxford (1996).
- R. Raveendran and S. Pal, J. Organomet. Chem., 692, 824 (2007).
- P.P. Dholakiya and M.N. Patel, Synth. React. Inorg.-Met. Org. Chem., 34, 553 (2004).
- C.R. Choudhury, S.K. Day, N. Mondal, S. Mitra, S.O.G. Mahalliand and K.M.A. Malik, J. Chem. Crystallogr., 31, 57 (2002).
- W.J. Geary, Coord. Chem. Rev., 7, 81 (1971).
- R.K. Upadhyay, J. Indian Chem. Soc., 74, 535 (1977).
- L.N. Sharda and M.C. Ganokar, Indian J. Chem., 27A, 617 (1988).
- V. Chinuusamy and K. Natarjan, Synth. React. Inorg.-Met. Org. Nanomet. Chem., 23, 889 (1993).
- V.L. Chavan and B.H. Mehta, Asian J. Chem., 22, 5976 (2010).
- J.H. Deshmukh and M.N. Deshpande, Asian J. Chem., 22, 5961 (2010).
- K. Nakamota, Infra Red and Raman spectra of Inorganic Co-Ordination compounds, New York, Wiley & Sons, p. 229 (1998).
- B.P. Ghargava, R. Bembi and M. Tyagu, J. Indian Chem. Soc., 60, 214 (1983).
- R.C. Maurya and P. Patel, Spectrosc. Lett., 32, 213 (1999).
- R.C. Maurya, D.D. Mishra, S. Mukherjee and J. Dubey, Polyhedron, 14, 1351 (1995).
- J.D. Lee, Concise Inorganic Chemistry, Blackwell Science Publishers, Reprint, edn. 5, p. 967 (1999).
- H.R. Singh and B.V. Agarwala, J. Indian Chem. Soc., 65, 591 (1988).
- B.V. Agarwala, S. Hingorani, V. Puri, C.L. Khetrapal and G.A. Nagangowda, Transition Met. Chem., 19, 25 (1994).
- A. Rahman, M.I. Choudhary and W.J. Thomsen, Bioassay Techniques for Drug Development, Harwood Academic Publishers, Netherlands (2001).
References
S.A. WestCott, Transition Met. Chem., 30, 411 (2005).
Z.H. Chohah, M. Praveen and M. Ghaffar, Met. Based Drugs, 4, 267 (1997).
De Clereq and F. Verpoort, Macromolecules, 35, 8943 (2002).
N.N. Gulerman, S. Rollas and H. Erdeniz, J. Pharm. Sci., 26, 1 (2001).
P. Tarasconi, R. Albertini, A. Bonati, P.P. Dall Aglio, P. Lunghi and S. Pinelli, Bioinorg. Med. Chem., 8, 154 (2000).
M. Wang, L.F. Wang, Y.Z. Li, Q.X. Li, Z.D. Xu and D.Q. Qu, Transition Met. Chem., 26, 307 (2001).
M. Ramesh, K.B. Chandrasekar and K.H. Reddy, Indian J. Chem., 9A, 1337 (2000).
J. Mannad and J.C. Crabbe, Bacterial and Antibacterial agents, Spectrum Academic Publishers, Oxford (1996).
R. Raveendran and S. Pal, J. Organomet. Chem., 692, 824 (2007).
P.P. Dholakiya and M.N. Patel, Synth. React. Inorg.-Met. Org. Chem., 34, 553 (2004).
C.R. Choudhury, S.K. Day, N. Mondal, S. Mitra, S.O.G. Mahalliand and K.M.A. Malik, J. Chem. Crystallogr., 31, 57 (2002).
W.J. Geary, Coord. Chem. Rev., 7, 81 (1971).
R.K. Upadhyay, J. Indian Chem. Soc., 74, 535 (1977).
L.N. Sharda and M.C. Ganokar, Indian J. Chem., 27A, 617 (1988).
V. Chinuusamy and K. Natarjan, Synth. React. Inorg.-Met. Org. Nanomet. Chem., 23, 889 (1993).
V.L. Chavan and B.H. Mehta, Asian J. Chem., 22, 5976 (2010).
J.H. Deshmukh and M.N. Deshpande, Asian J. Chem., 22, 5961 (2010).
K. Nakamota, Infra Red and Raman spectra of Inorganic Co-Ordination compounds, New York, Wiley & Sons, p. 229 (1998).
B.P. Ghargava, R. Bembi and M. Tyagu, J. Indian Chem. Soc., 60, 214 (1983).
R.C. Maurya and P. Patel, Spectrosc. Lett., 32, 213 (1999).
R.C. Maurya, D.D. Mishra, S. Mukherjee and J. Dubey, Polyhedron, 14, 1351 (1995).
J.D. Lee, Concise Inorganic Chemistry, Blackwell Science Publishers, Reprint, edn. 5, p. 967 (1999).
H.R. Singh and B.V. Agarwala, J. Indian Chem. Soc., 65, 591 (1988).
B.V. Agarwala, S. Hingorani, V. Puri, C.L. Khetrapal and G.A. Nagangowda, Transition Met. Chem., 19, 25 (1994).
A. Rahman, M.I. Choudhary and W.J. Thomsen, Bioassay Techniques for Drug Development, Harwood Academic Publishers, Netherlands (2001).