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New Nine Coordinated Hydrated Heavier Lanthanide Ethylenediaminetetraacetates Containing Hydrazinium Cation: Molecular Structure of N2H5[Tb(EDTA)(H2O)3]·5H2O and N2H5[Gd(EDTA)(H2O)3]·5H2O
Corresponding Author(s) : B.N. Sivasankar
Asian Journal of Chemistry,
Vol. 25 No. 3 (2013): Vol 25 Issue 3
Abstract
Two complexes of lanthanide with the composition N2H5[Tb(III)(EDTA)(H2O)3]·5H2O (I) and N2H5[Gd(III)(EDTA)(H2O)3]·5H2O (II) (EDTA = ethylenediaminetetraacetic acid) were prepared and characterized by X-ray single crystal diffraction technique. For I and II the Tb(III) and Gd(III) ions are nine coordinated by an EDTA ligand and three coordination water molecules, yielding a monocapped square-antiprisamatic (MCSAP) conformation. Complexes I and II are crystallizes in the orthorhombic system with Fd22 space group. The crystal data are as follows: a = 19.5030(9), b = 35.3459(17), c = 12.2825(5), a = b = g = 90, V = 8467(7) Å3, Z = 16, r = 1.704 Mg/m3, μ = 3.405 mm-1, F(000) = 4208, R1 = 0.0390 and wR2 = 0.1101 for 22995 observed reflections with I ³ 2s(I). The crystal data of the complex II are as follows: a = 19.5336(7) Å, b = 35.3788(14) Å, c = 12.2792(5) Å, a = b = g = 90º, V = 8485.9(6), Z = 16, r = 1.745 Mg/m3, μ = 3.196 mm-1, F(000) = 4320, R1 = 0.0226 and wR2 = 0.0666 for 8558 observed reflections with I = 2s(I). According to thermal analyses, the collapsing temperatures of crystal structure are 260 ºC for I and 240 ºC for II, which indicate that the crystal structure of I is more stable.
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References
J. Zhou, L.F. Wang and J.Y. Wang, J. Inorg. Biochem., 83, 41 (2001).
M. Shibasaki and N. Yoshikawa, Chem. Rev., 102, 2187 (2002).
M. Xiao and P.R. Selvin, J. Am. Chem. Soc., 123, 7067 (2001).
C. Lin, J.H. Yang and X. Wu, Anal. Chim. Acta, 403, 219 (2000).
G. Mathis, Clin. Chem., 41, 1391 (1995).
D. Parker, Coord. Chem. Rev., 205, 109 (2000).
J. Wang, X.D. Zhang and Y. Wang, Chin. J. Struct. Chem., 23, 890 (2004).
J.G. Kang, J.P. Hong and S.K. Yoon, J. Alloys Comp., 339, 248 (2002).
J. Wang, Y. Wang and Z.H. Zhang, J. Coord. Chem., 59, 295 (2006).
S.J. Franklin, Curr. Opin. Chem. Biol., 5, 201 (2001).
H. Kobayashi, S. Kawamoto, T. Saga, N. Sato, T. Ishimori, J. Konishi, K. Ono, K. Togashi and M.W. Brechbiel, Bioconjugate Chem., 12, 587 (2001).
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I.A. Vogel,A Text Book of Quantitative Inorganic Analysis; Longmans Green, London (2005).
G.M. Sheldrik, SHELX-97 Programs for Crystal Structure Determination; University of Cambridge, UK (1977).
A. Braibanti, F. Dallavalle, M.A. Pellinghelli and E. Laporati, Inorg. Chem., 7, 1430 (1968).
L. Vikram and B.N. Sivasankar, Indian J. Chem., 47A, 25 (2008)