A Novel Sensor Based on Polyoxometalates Modified Electrode

Pengcheng Li; Shuhong Ye; Shouhui Chen; Jianping Xiong; Li Wang; Yonghai Song

doi:10.14233/ajchem.2013.13048

Issue

Vol. 25 No. 3 (2013): Vol 25 Issue 3

Issue Published : October 8, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Novel Sensor Based on Polyoxometalates Modified Electrode

https://doi.org/10.14233/ajchem.2013.13048

Pengcheng Li

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China

Shuhong Ye

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China

Shouhui Chen

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China

Jianping Xiong

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China

Li Wang

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China

Yonghai Song

College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P.R. China

Corresponding Author(s) : Yonghai Song

yhsong@jnxu.edu.cn

Asian Journal of Chemistry, Vol. 25 No. 3 (2013): Vol 25 Issue 3
Article Published : October 9, 2012

Abstract

A novel [SiNi(H₂O)W₁₁O₃₉]^6-/poly(ferrocenylsilane) (PFS)/phthalocyanatocobalt(II) (Co(II)TAPc) modified gold (Au) electrode was fabricated by stepwise self-assembly of Co(II)TAPc, PFS and Keggin-type [SiNi(H₂O)W₁₁O₃₉]^6- on gold electrode. The properties and electrochemical behaviours of the modified electrode had been investigated by atomic force microscopy and electrochemical methods. Atomic force microscopy results showed that the Au electrode surface had been successfully covered by the three materials which formed three-dimensional (3D) porous film. The electrochemical results showed that the 3D porous film modified gold electrode combined the properties of [SiNi(H₂O)W₁₁O₃₉]^6-, PFS and Co(II)TAPc and exhibited good electrocatalytic ability to a series of chemicals, including O₂, H₂O₂, Fe³⁺, SO₃^2-, uric acid and ascorbic acid. The resulted [SiNi(H₂O)W₁₁O₃₉]^6-/PFS/Co(II)TAPc/Au electrode could be used in a large range of pH (0-8) and exhibited extremely fast amperometric response, low detection limit, high selectivity and wide linear range to these analyses.

Keywords

Electrochemistry Phthalocyanatocobalt Polyoxometalates Sensor

Li, P., Ye, S., Chen, S., Xiong, J., Wang, L., & Song, Y. (2012). A Novel Sensor Based on Polyoxometalates Modified Electrode. Asian Journal of Chemistry, 25(3), 1420–1424. https://doi.org/10.14233/ajchem.2013.13048

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Z.M. Zhang, Y.F. Qi, C. Qin, Y.G. Li, E.B. Wang, X.L. Wang, Z.M. Su and L. Xu, Inorg. Chem., 46, 8162 (2007).

X.L. Wang, Y.F. Bi, B.K. Chen, H.Y. Lin and G.C. Liu, Inorg. Chem., 47, 2442 (2008).

L.H. Bi, K.V. Foster, T. Mccormac and E. Dempsey, J. Electroanal. Chem., 605, 24 (2007).

S.Y. Zhai, J.Y. Liu, J.G. Jiang and S.J. Dong, Electroanalysis, 15, 1165 (2003).

P. Wang, X.P. Wang and G.Y. Zhu, New J. Chem., 24, 481 (2000).

M.A. Rahman, M.S. Won, P.H. Wei and Y.B. Shim, Electroanalysis, 18, 993 (2006).

C.X. Li, Y. Zhang, K.P.O' Halloran, J.W. Zhang and H.Y. Ma, J. Appl. Electrochem., 39, 421 (2009).

H. Hamidi, E. Shams, B. Yadollahi and F.K. Esfahani, Talanta, 74, 909 (2008).

M. Jiang, X.D. Zhai and M.H. Liu, J. Mater. Chem., 17, 193 (2007).

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J. Molina, A.I. del Río, J. Bonastre and F. Cases, Eur. Polym. J., 44, 2087 (2008).

B. Keita, R. Contant, P. Mialane, F. Sécheresse, P. Oliveira and L. Nadjo, Electrochem. Commun., 8, 767 (2006).

C.Y. Chen, Y.H. Song and L. Wang, Electrochim. Acta, 54, 1607 (2009).

C.Y. Chen, Y.H. Song and L. Wang, Electroanal., 20, 2543 (2008).

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U. Mazur, M. Leonetti, W.A. English and K.W. Hipps, J. Phys. Chem. B, 108, 17003 (2004).

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C.D. Zhang, C.Y. Sun, S.X. Liu, H.M. Ji and Z.M. Su, Inorg. Chim. Acta, 363, 718 (2010).

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J. Xu, F. Shang, J.H.T. Luong, K.M. Razeeb and J.D. Glennon, Biosens. Bioelectron., 25, 1313 (2010).

Issue

Vol. 25 No. 3 (2013): Vol 25 Issue 3

A Novel Sensor Based on Polyoxometalates Modified Electrode

Corresponding Author(s) : Yonghai Song

Abstract

Keywords

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