Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation and Surface Modification of ZnO/Al2O3 Nanocomposites
Corresponding Author(s) : Shiyu Ma
Asian Journal of Chemistry,
Vol. 25 No. 3 (2013): Vol 25 Issue 3
Abstract
In this work, the ZnO/Al2O3 nanocomposites are prepared by situ-modified method and the ZnO/Al2O3 nanocomposites are modified by silane coupling agent. By using the particle size analysis, it is confirmed that the mean particle size of modified ZnO/Al2O3 nanocomposites is 68 nm and its distribution is uniform. The dispersion of modified ZnO/Al2O3 nanocomposites is analyzed by the absolute value of ZnO/Al2O3 nanocomposites zeta potential. Through scanning electron microscope studies, it is found that the silane coupling agent improve the dispersibility of ZnO/Al2O3 nanocomposites. The hydroxyl groups on the surface of ZnO/Al2O3 nanocomposites can interact with hydroxyl groups of silane coupling agent and an organic coating layer is formed. The formed covalent bands are testified by Fourier transform infrared spectra (FT-IR). The dispersion stabilization of modified ZnO/Al2O3 nanocomposites is significantly improved due to the introduction of grafted polymers on the surface of nanoparticles. In addition, their surfaces become organic phase from inorganic phase.
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- Y. Zhang and J. Zhang, J. Colloid Interf. Sci., 283, 352 (2005).
- Y.L. Tai, J.S. Qian, Y.C. Zhang and J.D. Huang, Chem. Eng. J., 141, 354 (2008).
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- J. Ah-Young and M.Y. Li, Curr. Appl. Phys., 9, 144 (2009).
- W. Li, S.H. Zheng, S.Y. MA, H.Y. Ding, D. Jiao and B.Q. Cao, Asian J. Chem., 23, 705 (2011).
- M. Zhang, X.B. Wang, X.S. Fu and Y.Q. Xia, Tribol. Int., 42, 1029 (2009).
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- D. Jiao, S.H. Zheng, Y.Z. Wang, R.F. Guan and B.Q. Cao, Appl. Surf. Sci., 257, 5720 (2011).
- A.D. Pomogailo, Polym. Sci. Series C, 48, 85 (2006).
- N.B. Faouzi, A. Naceur and C. Yves, Prog. Org. Coat., 55, 303 (2006)
References
Y. Zhang and J. Zhang, J. Colloid Interf. Sci., 283, 352 (2005).
Y.L. Tai, J.S. Qian, Y.C. Zhang and J.D. Huang, Chem. Eng. J., 141, 354 (2008).
X.B. Ji, Y.X. Chen, G.Q. Zhao, X.B. Wang and W.M. Liu, Tribol. Lett., 41, 113 (2011)
Q.B. Guo, M.Z. Rong, G.L. Jia, T.L. Kin and M.Q. Zhang, Wear, 266, 658 (2009).
J. Ah-Young and M.Y. Li, Curr. Appl. Phys., 9, 144 (2009).
W. Li, S.H. Zheng, S.Y. MA, H.Y. Ding, D. Jiao and B.Q. Cao, Asian J. Chem., 23, 705 (2011).
M. Zhang, X.B. Wang, X.S. Fu and Y.Q. Xia, Tribol. Int., 42, 1029 (2009).
G. Sui, W.H. Zhong, X. Ren, X.Q. Wang and X.P. Yang, Mater. Chem. Phys., 115, 404 (2009).
W. Li, S.H. Zheng, B.Q. Cao and S.Y. Ma, J. Nanopart. Res., 13, 2129 (2011).
D. Jiao, S.H. Zheng, Y.Z. Wang, R.F. Guan and B.Q. Cao, Appl. Surf. Sci., 257, 5720 (2011).
A.D. Pomogailo, Polym. Sci. Series C, 48, 85 (2006).
N.B. Faouzi, A. Naceur and C. Yves, Prog. Org. Coat., 55, 303 (2006)