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Orthophosphoric Acid Activated Ananas comosus Leaves Carbon as an Adsorbent for the Removal of Basic Yellow 2
Corresponding Author(s) : R. Parimalam
Asian Journal of Chemistry,
Vol. 25 No. 3 (2013): Vol 25 Issue 3
Abstract
Removal of basic yellow 2 from aqueous solution by adsorbing it on an activated carbon prepared from Ananas comosus (L) leaves was investigated by batch method. The studies were conducted by varying the pH, initial dye concentration, contact time and temperature. The sorption data was analyzed using the Langmuir, Freundlich, Tempkin isotherm and Dubinin-Radushkevich (D-R) isotherm models. The maximum monolayer adsorption capacity was found to be 227.27 mg/g. The Freundlich model is more appropriate to explain the adsorption phenomena with good fit. The data were also analyzed in terms of their kinetic behaviour and was found to obey the pseudo second order equation with an r2 value of 0.999.
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- M. Hema and S. Arivoli, Int. J. Phys. Sci., 2, 010 (2007).
- H. Zollinger, In Colour Chemistry; VCH; New York, edn. 1 (1987).
- N.I. Sax, Cancer causing Chemical, DC 9625000, VNR: New York, edn. 1 (1981).
- I.A. Alaton, B.H. Gutsoy and J.E. Schmidt, Dyes Pigments, 78, 117 (2008).
- S.M. Ghoreishi and R. Haghighi, Chem. Eng. J., 95, 163 (2003).
- S. Al. Asheh, F. Banat and L. Abu-Aitah, Sep. Sci. Technol., 21, 451 (2003).
- M.A. Khraisheh and M.S. Alg-Houti, Adsorption, 11, 547 (2005).
- A.R. Cestai, E.F.S. Viera and J.A. Mota, J. Hazard. Mater., 160, 337 (2008).
- D. Mohan, K.P. Singh, G. Singh and K. Kumar, Ind. Eng. Chem. Res., 41, 3644 (2002).
- G. McKay and S.J. Allen, J. Sep. Proc. Technol., 4, 1 (1983).
- S. Wang and H. Li, Dyes Pigments, 72, 308 (2007).
- I.A.W. Tan, B.H. Hameed and A.L. Ahmad, Chem. Eng. J., 127, 111 (2007).
- M.J. Iqbal and M.N. Ashiq, J. Hazard. Mater., 139, 57 (2007).
- S.B. Bakaullah, M.A. Rauf and S.S. Al Ali, Dyes Pigm., 24, 85 (2007).
- M. Lehocky and A. Mracek, Czech. J. Phys., 56, 1277 (2006).
- G. Cirini, Bioresour. Technol., 589, 67 (2006).
- G. Horvath and K. Kawazoe, J. Chem. Eng. (Japan), 16, 470 (1983).
- E.P. Barrett, L.G. Jaoyner and P.P. Halenda, J. Am. Chem. Soc., 73, 373 (1953).
- C.T. Hsieh and H. Teng, J. Colloid Interf. Sci., 230, 171 (2000).
- P.K. Malik, Dyes Pigments, 56, 239 (2003).
- A. Ozcan and A.S. Ozcan, J. Hazard. Mater., B125, 252 (2007).
- Y.S. Ho and G. McKay, Process Safety Environ. Protect., 76, 183 (1998).
- K. Ravikumar, B. Deebika and K. Balu, J. Hazard. Mater., 122, 75 (2005).
- B. Noroozi, G.A. Sorial, H. Bahrami and M. Arami, J. Hazard. Mater., B139, 167 (2007).
- W.J. Weber Jr., J.C. Morriss and J. Sanit, Eng. Div. Am. Soc. Civil Eng., 89, 31 (1963).
- Q. Sun and L. Yang, Water Res., 37, 1535 (2003).
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1981).
- Y. Bulut and H. Aydin, Desalination, 194, 259 (2006).
- M.K. Purkait, D.S. Gusain, S. Das Gupta and S. De, Sep. Sci. Technol., 39, 2419 (2004).
- M.J. Tempkin and V. Pyzhev, Acta Physiol. Chem. U.S.S.R., 12, 217 (1941).
- C. Aharoni and D.L. Sparks, In eds.: D.L. Sparks and D.L. Suarez, Kinetics of Soil Chemical Reactions-A Theoretical Treatment, Rate of soil Chemical Processes, Soil Science Society of America, Madison, Wt, pp. 1-18 (1991).
- M.M. Dubinin, Chem. Rev., 60, 235 (1960).
- M.M. Dubinin, Zh. Fizich. Khim., 39, 1305 (1965).
- L.V. Radushkevich, Zh. Fizich. Khim., 23, 1410 (1949).
- S. Kundu and A.K. Gupta, Colliods Surf. A, 273, 121 (2006).
- A. Ramesh, D.J. Lec and J.W.C. Wang, J. Colliod Interf. Sci., 291, 588 (2005).
- S.D. Khattri and M.K. Singh, Water, Air Soil Pollut., 120, 283 (2000).
- M.J. Iqbal and M.N. Ashiq, J. Chem. Soc. Pak., 32, 419 (2010).
References
M. Hema and S. Arivoli, Int. J. Phys. Sci., 2, 010 (2007).
H. Zollinger, In Colour Chemistry; VCH; New York, edn. 1 (1987).
N.I. Sax, Cancer causing Chemical, DC 9625000, VNR: New York, edn. 1 (1981).
I.A. Alaton, B.H. Gutsoy and J.E. Schmidt, Dyes Pigments, 78, 117 (2008).
S.M. Ghoreishi and R. Haghighi, Chem. Eng. J., 95, 163 (2003).
S. Al. Asheh, F. Banat and L. Abu-Aitah, Sep. Sci. Technol., 21, 451 (2003).
M.A. Khraisheh and M.S. Alg-Houti, Adsorption, 11, 547 (2005).
A.R. Cestai, E.F.S. Viera and J.A. Mota, J. Hazard. Mater., 160, 337 (2008).
D. Mohan, K.P. Singh, G. Singh and K. Kumar, Ind. Eng. Chem. Res., 41, 3644 (2002).
G. McKay and S.J. Allen, J. Sep. Proc. Technol., 4, 1 (1983).
S. Wang and H. Li, Dyes Pigments, 72, 308 (2007).
I.A.W. Tan, B.H. Hameed and A.L. Ahmad, Chem. Eng. J., 127, 111 (2007).
M.J. Iqbal and M.N. Ashiq, J. Hazard. Mater., 139, 57 (2007).
S.B. Bakaullah, M.A. Rauf and S.S. Al Ali, Dyes Pigm., 24, 85 (2007).
M. Lehocky and A. Mracek, Czech. J. Phys., 56, 1277 (2006).
G. Cirini, Bioresour. Technol., 589, 67 (2006).
G. Horvath and K. Kawazoe, J. Chem. Eng. (Japan), 16, 470 (1983).
E.P. Barrett, L.G. Jaoyner and P.P. Halenda, J. Am. Chem. Soc., 73, 373 (1953).
C.T. Hsieh and H. Teng, J. Colloid Interf. Sci., 230, 171 (2000).
P.K. Malik, Dyes Pigments, 56, 239 (2003).
A. Ozcan and A.S. Ozcan, J. Hazard. Mater., B125, 252 (2007).
Y.S. Ho and G. McKay, Process Safety Environ. Protect., 76, 183 (1998).
K. Ravikumar, B. Deebika and K. Balu, J. Hazard. Mater., 122, 75 (2005).
B. Noroozi, G.A. Sorial, H. Bahrami and M. Arami, J. Hazard. Mater., B139, 167 (2007).
W.J. Weber Jr., J.C. Morriss and J. Sanit, Eng. Div. Am. Soc. Civil Eng., 89, 31 (1963).
Q. Sun and L. Yang, Water Res., 37, 1535 (2003).
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1981).
Y. Bulut and H. Aydin, Desalination, 194, 259 (2006).
M.K. Purkait, D.S. Gusain, S. Das Gupta and S. De, Sep. Sci. Technol., 39, 2419 (2004).
M.J. Tempkin and V. Pyzhev, Acta Physiol. Chem. U.S.S.R., 12, 217 (1941).
C. Aharoni and D.L. Sparks, In eds.: D.L. Sparks and D.L. Suarez, Kinetics of Soil Chemical Reactions-A Theoretical Treatment, Rate of soil Chemical Processes, Soil Science Society of America, Madison, Wt, pp. 1-18 (1991).
M.M. Dubinin, Chem. Rev., 60, 235 (1960).
M.M. Dubinin, Zh. Fizich. Khim., 39, 1305 (1965).
L.V. Radushkevich, Zh. Fizich. Khim., 23, 1410 (1949).
S. Kundu and A.K. Gupta, Colliods Surf. A, 273, 121 (2006).
A. Ramesh, D.J. Lec and J.W.C. Wang, J. Colliod Interf. Sci., 291, 588 (2005).
S.D. Khattri and M.K. Singh, Water, Air Soil Pollut., 120, 283 (2000).
M.J. Iqbal and M.N. Ashiq, J. Chem. Soc. Pak., 32, 419 (2010).