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Vol. 25 No. 3 (2013): Vol 25 Issue 3

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Preparation of Polyhedral Oligosilsesquioxane-Based Organic-Inorganic Hybrid Porous Nanocomposite by Freeze-Drying Conditions

https://doi.org/10.14233/ajchem.2013.12609
Yuancheng Qin
School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P.R. China
Qiang Peng
School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P.R. China
Jinsheng Song
School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, P.R. China

Corresponding Author(s) : Qiang Peng

qiangpengjohnny@yahoo.com

Asian Journal of Chemistry, Vol. 25 No. 3 (2013): Vol 25 Issue 3

Abstract

Novel organic-inorganic hybrid porous nanocomposites have been obtained by the reaction of octa(aminophenyl)silsesquioxane with formaldehyde under mild conditions by freeze-drying conditions. The structures of the products were characterized by FTIR spectroscopy, N2 adsorption isotherm and FESEM. The material showed a specific surface area of 340 m2/g and a pore volume of 0.83 cm3/g. The material has pore size 3.6-60 nm. The results of FTIR, solid-state 13C and 29Si NMR spectra clearly show that the cage structure of the polyhedral oligosilsesquioxane is retained during the synthesis and the polyhedral oligosilsesquioxane building blocks were successfully woven into the porous structure.

Keywords

Nanocomposites Organic-inorganic Freeze-drying polyhedral oligosilsequioxane
Qin, Y., Peng, Q., & Song, J. (2012). Preparation of Polyhedral Oligosilsesquioxane-Based Organic-Inorganic Hybrid Porous Nanocomposite by Freeze-Drying Conditions. Asian Journal of Chemistry, 25(3), 1229–1232. https://doi.org/10.14233/ajchem.2013.12609
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