Prediction of Transport Properties of R142b Using A New Intermolecular Potential

Xiao-Po Wang; Bo Song; Fu-Xin Yang; Zhi-Gang Liu

doi:10.14233/ajchem.2013.12927

Issue

Vol. 25 No. 2 (2013): Vol 25 Issue 2

Issue Published : September 6, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

Prediction of Transport Properties of R142b Using A New Intermolecular Potential

https://doi.org/10.14233/ajchem.2013.12927

Xiao-Po Wang

Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P.R. China

Bo Song

Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P.R. China

Fu-Xin Yang

Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P.R. China

Zhi-Gang Liu

Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P.R. China

Corresponding Author(s) : Xiao-Po Wang

wangxp@mail.xjtu.edu.cn

Asian Journal of Chemistry, Vol. 25 No. 2 (2013): Vol 25 Issue 2
Article Published : September 8, 2012

Abstract

An iterative inversion scheme was used to determine the pair interaction potential of refrigerant R142b from a new correlation of collision integrals. According to the Chapman-Enskog theory and the Wang Chang-Uhlenbeck-de Boer scheme, transport properties of pure R142b were predicted by the new potential from 273.15 to 973.15 K at low-density, including viscosity, thermal conductivity, self-diffusion coefficient and thermal diffusion factor. The accuracy of the calculated values is estimated to be 1.5 % for viscosity, 5.0 % for thermal conductivity and 7.5 % for self-diffusion coefficient.

Keywords

Inversion method Potential energy surface Transport property Refrigerant R142b

Wang, X.-P., Song, B., Yang, F.-X., & Liu, Z.-G. (2012). Prediction of Transport Properties of R142b Using A New Intermolecular Potential. Asian Journal of Chemistry, 25(2), 827–830. https://doi.org/10.14233/ajchem.2013.12927

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References

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References

J.O. Hirschfelder, C.F. Curtiss and R.B. Bird, Molecular Theory of Gases and Liquids, New York: John Wiley (1954).

G.C. Maitland, M. Rigby, E.B. Smith and W.A. Wakeham, Intermolecular Forces: Their Origins and Determination, Oxford: Clarendon Press (1984).

P. Clancy, D.W. Gough, G.P. Matthews, E.B. Smith and G.C. Maitland, Mol. Phys., 30, 1397 (1975).

J. Kestin, K. Knierim, E.A. Mason, B. Najafi, S.T. Ro and M. Waldman, J. Phys. Chem. Ref. Data, 13, 229 (1984).

A. Boushehri, J. Bzowski, J. Kestin and E.A. Mason, J. Phys. Chem. Ref. Data, 16, 445 (1987).

J. Bzowski, J. Kestin, E.A. Mason and F.J. Uribe, J. Phys. Chem. Ref. Data, 19, 1179 (1990).

A. Boushehri and A. Maghari, J. Phys. Soc. (Japan), 59, 4302 (1990).

H. Behnejad, A. Maghari and M. Najafi, J. Comp. Chem., 16, 441 (1995).

B. Haghighi, M. Fathabadi and M.M. Papari, Fluid Phase Equilib., 203, 205 (2002).

M.M. Papari, D. Mohammad-Aghaiee, B. Haghighi and A. Boushehri, Fluid Phase Equilib., 232, 122 (2005).

T. Hosseinnejad, H. Behnejad and V.H. Shahmir, Fluid Phase Equilib., 258, 155 (2007).

B. Haghighi, A. Maghari and M. Najafi, J. Phys. Soc. (Japan), 67, 3086 (1998).

E.K. Goharshadi and M. Abbaspour, Fluid Phase Equilib., 212, 53 (2003).

J. Moghadasi, D. Mohammad-Aghaie and M.M. Papari, Ind. Eng. Chem. Res., 45, 9211 (2006).

J. Moghadasi, M.M. Papari, D. Mohammad-Aghaie and A. Campo, Bull. Chem. Soc. (Japan), 81, 220 (2008).

B. Haghighi, F. Heidari and M.M. Papari, Indian J. Chem., 47A, 867 (2008).

B. Haghighi, F. Heidari and M.M. Papari, Indian J. Chem., 49A, 180 (2010).

X.P. Wang, B. Song, J.T. Wu and Z.G. Liu, Acta Phys. Sin., 59, 7158 (2010).

L.A. Viehland, A.R. Janzen and R.A. Aziz, J. Chem. Phys., 102, 5444 (1995).

M.L. Huber, A. Laesecke and R.A. Perkins, Ind. Eng. Chem. Res., 42, 3163 (2003).

B. Najafi, Y. Ghayeb and G.A. Parsafar, Int. J. Thermophys., 21, 1011 (2000).

H. Nabizadeh and F. Mayinger, High Temp.-High Press., 24, 221 (1992).

M. Takahashi, C. Yokoyama and S. Takahashi, J. Chem. Eng. Data, 32, 98 (1987).

R. Afshar and S.C. Saxena, Int. J. Thermophys., 1, 51 (1980).

B.R. Fellows, R.G. Richard and I.R. Shankland, Thermal Conductivity Data for Some Environmentally Acceptable Fluorocarbons, Proceedings of the Twenty-First International Thermal Conductivity Conference, Lexington, USA (1989).

U. Hammerschmidt, Int. J. Thermophys., 16, 1203 (1995).

A.T. Sousa, P.S. Fialho, C.A. Nieto de Castro, R. Tufeu and B. Leneindre, Int. J. Thermophys., 13, 383 (1992).

Y. Tanaka, M. Nakata and T. Makita, Int. J. Thermophys., 12, 949 (1991).

E.W. Lemmon, M.L. Huber and M.O. McLinden, NIST Standard Reference Database 23, Reference Fluid Thermodynamic and Transport Properties Database (REFPROP), Version 8.0, Gaithersburg: National Institute of Standards and Technology (2007).

Issue

Vol. 25 No. 2 (2013): Vol 25 Issue 2

Prediction of Transport Properties of R142b Using A New Intermolecular Potential

Corresponding Author(s) : Xiao-Po Wang

Abstract

Keywords

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