Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Investigation of Photocatalytic Activity of TiO2/SiO2Nanocomposite in Presence of Carboxy Methyl Cellulose, Poly(vinyl pyrrolidone) and Hydroxyl Propyl Cellulose
Corresponding Author(s) : B. Khodadadi
Asian Journal of Chemistry,
Vol. 25 No. 2 (2013): Vol 25 Issue 2
Abstract
TiO2/SiO2 nanocomposites powder are the most important materials due to their extensive application in the field of photocatalysis, were prepared by the sol-gel method with and without poly(vinyl pyrrolidone), carboxy methyl cellulose and hydroxyl propyl cellulose as additives. In this work, the influence of these additives on the properties, structure and photocatalytic activity under UV-irradiation for removal of organic pollutant were investigated by IR spectra, scanning electron microscopy, energy dispersive analytical X-ray and X-ray diffraction methods. The results suggest that these additives play an important role in decreasing of particles size and TiO2/SiO2 with hydroxy propyl cellulose was the best sample.
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- J. Winkler, In ed.: ed.: V. Verlag, Titanium Oxide, Hannover (2003).
- A. Fujishima, T.N. Rao and D.A. Tryk, J. Photochem. Photobiol. C: Photochem., 1, 1 (2000).
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- H. Imai and H. Hirashima, J. Am. Ceram. Soc., 82, 2301 (1999).
- S. Liu, N. Jaffrezic and C. Guillard, J. Appl. Surf. Sci., 255, 2704 (2008).
- C. Euvananont, C. Junin, K. Inpor, P. Limthongkul and C. Thanachayanont, J. Ceram. In., 34, 1067 (2008).
- K. Guan, J. Surf. Coat. Technol., 191, 155 (2005).
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- M.M. Mohamed, T.M. Salama and T. Yamaguchi, J. Colloids Surf., 207, 25 (2002).
- C.U.I. Odenbrand, S.L.T. Anderson, L.A.H. Anderson, J.G.M. Brandin and G. Busca, J. Catal., 125, 541 (1990).
- X. Gao and I.E. Wachs, J. Catal. Today, 51, 233 (1999).
- G. Schmid, Nanoparticles, Wiley-Interscience, New York (2004).
- G. Colon, M.C. Hidalgo and J.A. Navio, J. Appl. Catal. A: Gen., 231, 185 (2002).
- M. Itoh, H. Hattori and K. Tanabe, J. Catal., 35, 225 (1974).
- J.R. Sohn and H.J. Jang, J. Catal., 132, 563 (1991).
- T. Kataoka and J.A. Dumesic, J. Catal., 112, 66 (1988).
- Z. Liu, J. Tabora and R.J. Davis, J. Catal., 149, 117 (1994).
- M. Houmard, D. Riassetto, F. Roussel, A. Bourgeois, G. Berthome, J.C. Joud and M. Langlet, J. Appl. Surf. Sci., 254, 1405 (2007).
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- Y. Tanaka and M. Suganuma, J. Sol-Gel Sci. Technol., 22, 83 (2001).
- T.A. Egerton and I.R. Tooley, J. Phys. Chem. B, 108, 5066 (2004).
- X. Deng, Y. Yue and Z. Gao, J. Appl. Catal. B, 39, 135 (2002).
- Y. Nosaka, N. Ohta and H. Miyama, J. Phys. Chem., 94, 3752 (1990).
- N. Xu, Z. Shi, Y. Fan, J. Shi and M.Z.C. Hu, J. Ind. Eng. Chem. Res., 38, 373 (1999).
- J.M. Nedeljkovic, M.T. Nenadovic, O.I. Micic and A.J. Nozik, J. Phys. Chem., 90, 12 (1986).
- M. Toyoda, Y. Nanbu, Y. Nakazawa, M. Hirano and M. Inagaki, J. Appl. Catal. B, 49, 227 (2004).
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- K. Tanaka, M.F.V. Capule and T. Hisanaga, J. Chem. Phys. Lett., 187, 73 (1991).
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- A.C. Pierre, Introduction to Sol-Gel Processing, Kluwer Academic Publishers, Boston (1998).
- K.M. Parida and N. Sahu, J. Mol. Catal. Chem. A, 287, 151 (2008).
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- H. Thoms, M. Epple, M. Froba, J. Wong and A. Reller, J. Mater. Chem., 8, 1447 (1998).
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References
J. Winkler, In ed.: ed.: V. Verlag, Titanium Oxide, Hannover (2003).
A. Fujishima, T.N. Rao and D.A. Tryk, J. Photochem. Photobiol. C: Photochem., 1, 1 (2000).
A. Mills and S. Le Hunte, J. Photochem. Photobiol. A: Chem., 108, 1 (1997).
J. Ovenstone and K. Yanagisawa, J. Mater. Sci., 11, 2770 (1999).
H. Imai and H. Hirashima, J. Am. Ceram. Soc., 82, 2301 (1999).
S. Liu, N. Jaffrezic and C. Guillard, J. Appl. Surf. Sci., 255, 2704 (2008).
C. Euvananont, C. Junin, K. Inpor, P. Limthongkul and C. Thanachayanont, J. Ceram. In., 34, 1067 (2008).
K. Guan, J. Surf. Coat. Technol., 191, 155 (2005).
X. Fu, L.A. Clark, Q. Yang and M.A. Anderson, J. Environ. Sci. Technol., 30, 647 (1996).
M.M. Mohamed, T.M. Salama and T. Yamaguchi, J. Colloids Surf., 207, 25 (2002).
C.U.I. Odenbrand, S.L.T. Anderson, L.A.H. Anderson, J.G.M. Brandin and G. Busca, J. Catal., 125, 541 (1990).
X. Gao and I.E. Wachs, J. Catal. Today, 51, 233 (1999).
G. Schmid, Nanoparticles, Wiley-Interscience, New York (2004).
G. Colon, M.C. Hidalgo and J.A. Navio, J. Appl. Catal. A: Gen., 231, 185 (2002).
M. Itoh, H. Hattori and K. Tanabe, J. Catal., 35, 225 (1974).
J.R. Sohn and H.J. Jang, J. Catal., 132, 563 (1991).
T. Kataoka and J.A. Dumesic, J. Catal., 112, 66 (1988).
Z. Liu, J. Tabora and R.J. Davis, J. Catal., 149, 117 (1994).
M. Houmard, D. Riassetto, F. Roussel, A. Bourgeois, G. Berthome, J.C. Joud and M. Langlet, J. Appl. Surf. Sci., 254, 1405 (2007).
K.L. Yeung, A.J. Maira, J. Stolz, E. Hung, N.K.C. Ho, A.C. Wei, J. Soria, K.J. Chao and P.L. Yue, J. Phys. Chem. B, 106, 4608 (2002).
D. Farin, J. Kiwi and D. Avnir, J. Phys. Chem., 93, 5851 (1989).
Y. Tanaka and M. Suganuma, J. Sol-Gel Sci. Technol., 22, 83 (2001).
T.A. Egerton and I.R. Tooley, J. Phys. Chem. B, 108, 5066 (2004).
X. Deng, Y. Yue and Z. Gao, J. Appl. Catal. B, 39, 135 (2002).
Y. Nosaka, N. Ohta and H. Miyama, J. Phys. Chem., 94, 3752 (1990).
N. Xu, Z. Shi, Y. Fan, J. Shi and M.Z.C. Hu, J. Ind. Eng. Chem. Res., 38, 373 (1999).
J.M. Nedeljkovic, M.T. Nenadovic, O.I. Micic and A.J. Nozik, J. Phys. Chem., 90, 12 (1986).
M. Toyoda, Y. Nanbu, Y. Nakazawa, M. Hirano and M. Inagaki, J. Appl. Catal. B, 49, 227 (2004).
Y. Li, N.H. Lee, D.S. Lee, D.S. Hwang, J.S. Song, E.G. Lee and S.J. Kim, J. Langmuir, 20, 10838 (2004).
G.P. Lepore, C.H. Langford, J. Vichova and A. Vlcek Jr., J. Photochem. Photobiol. A: Chem., 75, 67 (1993).
K. Tanaka, M.F.V. Capule and T. Hisanaga, J. Chem. Phys. Lett., 187, 73 (1991).
H. Hayashi and K. Torii, J. Mater. Chem., 12, 3671 (2002).
J. Ovenstone, J. Mater. Sci., 36, 1325 (2001).
A.C. Pierre, Introduction to Sol-Gel Processing, Kluwer Academic Publishers, Boston (1998).
K.M. Parida and N. Sahu, J. Mol. Catal. Chem. A, 287, 151 (2008).
G. Zhao, Q. Tian, Q. Liu and G. Han, J. Surf. Coat. Technol., 198, 55 (2005).
H. Thoms, M. Epple, M. Froba, J. Wong and A. Reller, J. Mater. Chem., 8, 1447 (1998).
M.P. Zheng, M. Gu, Y. Jin and G. Jin, J. Mater. Sci. Eng. B, 77, 55 (2000).
M.P. Zheng, M.Y. Gu, Y.P. Jin, H.H. Wang, P.F. Zu, P. Tao and J.B. He, J. Mater. Sci. Eng. B, 87, 197 (2001).
P. Aberoomand Azar, S. Moradi, S. Samadi, S. Kamyar and M. Saber Tehrani, Asian J. Chem., 22, 1619 (2010)