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Vol. 25 No. 1 (2013): Vol 25 Issue 1

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Green Synthetic Approach to 5-Substituted-1H-Tetrazoles via Recycle and Reuse of Tributyltin Chloride

https://doi.org/10.14233/ajchem.2013.13106
A. Sampath
Research and Development, Integrated Product Development, Innovation Plaza, Dr Reddy's Laboratories Ltd., Survey Nos. 42, 45, 46 and 54, Bachupally, Qutubullapur, Ranga Reddy District-500 123, India
V. Prabhakar Reddy
Department of Chemistry, P.G. College of Science, Osmania University, Saifabad, Hyderabad500 004, India
A. Kalyan Chakravarthy
Research and Development, Integrated Product Development, Innovation Plaza, Dr Reddy's Laboratories Ltd., Survey Nos. 42, 45, 46 and 54, Bachupally, Qutubullapur, Ranga Reddy District-500 123, India
P. Pratap Reddy
Research and Development, Macleods Pharmaceuticals Limited, G-2, Mahakali Caves Road, Andheri (E), Mumbai-400 093, India

Corresponding Author(s) : A. Sampath

sampathreddyaalla@yahoo.com

Asian Journal of Chemistry, Vol. 25 No. 1 (2013): Vol 25 Issue 1

Abstract

A simple, safe and efficient process for the recycle of tributyltin chloride from tributyltin hydroxide is developed and its reuse in the synthesis of 5-substituted-1H-tetrazoles is successfully demonstrated, which paved a way to reduce the toxic tin waste significantly. Recycling of tributyltin chloride is possible over six cycles without loss of its activity.

Keywords

Nitrile Recycle Tributyltin chloride 5-Substituted-1H-tetrazole [3 2] Cycloaddition Tributyltin hydroxide
Sampath, A., Prabhakar Reddy, V., Kalyan Chakravarthy, A., & Pratap Reddy, P. (2012). Green Synthetic Approach to 5-Substituted-1H-Tetrazoles via Recycle and Reuse of Tributyltin Chloride. Asian Journal of Chemistry, 25(1), 393–396. https://doi.org/10.14233/ajchem.2013.13106
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