Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation of W, N Codoped TiO2 with Enhanced Visible Light Response
Corresponding Author(s) : Xue Li
Asian Journal of Chemistry,
Vol. 25 No. 1 (2013): Vol 25 Issue 1
Abstract
The W, N co-doped TiO2 nanoparticles have been synthesized by sol-gel method. The prepared photocatalysts were characterized by X-ray diffraction, field emission scanning electron microscopy, Fourier transform infrared spectroscopy and diffuse reflectance spectra. The results showed that the codoped photocatalyst with a spherical shape exhibited a smaller size than the undoped titania. Compared to un-doped TiO2, N-TiO2 and P-25, the absoption edge of the W, N co-doped TiO2 shifted to longer wavelength and its photocatalytic activity for degradation of methyl orange under Xe-lamp (350 W) was higher.
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References
M. Addamo, V. Augugliaro, A.D. Paola, E. García-López, V. Loddo, G. Marcí, R. Molinari, L. Palmisano and M. Schiavello, J. Phys. Chem. B, 108, 3303 (2004).
J. Zhu, J. Zhang, F. Chen and M. Anpo, Mater. Lett., 59, 3378 (2005).
G. Liu, X. Li, J. Zhao, H. Hidaka and N. Serpone, Environ. Sci. Technol., 34, 3982 (2000).
M. Anpo, Pure Appl. Chem., 72, 1265 (2000).
F. Bosc, A. Ayral, P. Albouy and C. Guizard, Chem. Mater., 15, 2463 (2003).
Y.J. Xu, Y.B. Zhuang and X.Z. Fu, J. Phys. Chem. C, 114, 2669 (2010).
P. Periyat, S.C. Pillai, D.E. McCormack, J. Colreavy and S.J. Hinder, J. Phys. Chem. C, 112, 7644 (2008).
G. Liu, H.G. Yang, X.W. Wang, L.N. Cheng, J. Pan, G.Q. Lu and H.M. Cheng, J. Am. Chem. Soc., 131, 12868 (2009).
H. J. Tian, L.H. Hu, C.N. Zhang, W.Q. Liu, Y. Huang, L. Mo, L. Guo, J. Sheng and S.Y. Dai, J. Phys. Chem. C, 114, 1627 (2010).
A.M. Czoska, S. Livraghi, M. Chiesa, E. Giamello, S. Agnoli, G. Granozzi, E. Finazzi, C. Di Valentin and G. Pacchioni, J. Phys. Chem. C, 112, 8951 (2008).
C.H. Hong, H.J. Choi and M.S. Jhon, Chem. Mater., 18, 2771 (2006).
A.M. Asaduzzaman and P. Krüger, J. Phys. Chem. C, 112, 4622 (2008).
J.Y. Wang, Z.H. Liu and R.X. Cai, Environ. Sci. Technol., 42, 5759 (2008).
N. Couselo, F.S. García Einschlag, R.J. Candal and M. Jobbágy, J. Phys. Chem. C, 112, 1094 (2008).
N.R. de Tacconi, C.R. Chenthamarakshan, N.A. Basit, G. Yogeeswaran, A. Watcharenwong, R.S. de Zoysa and K. Rajeshwar, J. Phys. Chem. B, 110, 25347 (2006).
J.J. Xu, Y.H. Ao, D.G. Fu and C.W. Yuan, J. Colloid. Interface Sci., 10, 1016 (2008).
R. Asahi, T. Morikawa and T. Ohwaki, Science, 293, 269 (2001)