Microscopic Studies of Polyaniline-poly-N-isopropylacrylamide-co-acrylic acid/ Flyash Composites Containing Dodecylbenzene Sulfonic Acid

Shashidhar; Ramprasad; C. Basavaraja; T.K. Vishnuvardhan

doi:10.14233/ajchem.2013.12972

Issue

Vol. 25 No. 1 (2013): Vol 25 Issue 1

Issue Published : August 6, 2012

This work is licensed under a Creative Commons Attribution 4.0 International License.

Microscopic Studies of Polyaniline-poly-N-isopropylacrylamide-co-acrylic acid/ Flyash Composites Containing Dodecylbenzene Sulfonic Acid

https://doi.org/10.14233/ajchem.2013.12972

Shashidhar

Department of Chemistry, SDM College of Engineering and Technology, Dharwad-580 002, India

Ramprasad

Department of Chemistry, SDM College of Engineering and Technology, Dharwad-580 002, India

C. Basavaraja

Department of Chemistry, Inje University, Kimhae 621 749, South Korea

T.K. Vishnuvardhan

Department of Chemistry, Acharya Institute of Technology, Bangalore-560 090, India

Corresponding Author(s) : Shashidhar

nshashidharreddy@gmail.com

Asian Journal of Chemistry, Vol. 25 No. 1 (2013): Vol 25 Issue 1
Article Published : August 16, 2012

Abstract

Polymer composites containing polyaniline-poly-N-isopropylacrylamide-co-acrylic acid (PAA)/ flyash (FA) were synthesized by chemical polymerization of aniline in an aqueous solution containing dispersed poly-N-isopropylacrylamide-co-acrylic acid (PNA)/flyash (FA) in the presence of dodecylbenzene sulfonic acid using different wt % of flyash (5, 10, 20 and 30 %). The structure and morphology of the polymer matrix affected by the added were studied by atomic force microscope. The direct current electrical conductivity was studied as a function of flyash content in the temperature range of 293-483 K. The results show an increase in conductivity values as the temperature increases at a particular concentration of flyash. However, further increase in flyash causes a decrease in the conductivity.

Keywords

Dodecylbenzene sulfonic acid Polyaniline-poly-N-isopropylacrylamide-co-acrylic acid/Flyash Polymerization

Shashidhar, ., Ramprasad, ., Basavaraja, C., & Vishnuvardhan, T. (2012). Microscopic Studies of Polyaniline-poly-N-isopropylacrylamide-co-acrylic acid/ Flyash Composites Containing Dodecylbenzene Sulfonic Acid. Asian Journal of Chemistry, 25(1), 271–276. https://doi.org/10.14233/ajchem.2013.12972

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References

C.Y. Lee, H.G. Song, K.S. Jang, E.J. Oh, A.J. Epstien and J. Joo, Synth. Met., 102, 1346 (1999).
H.L. Wang, A.G. MacDiarmid, Y.Z. Wang, D.D. Gebler and A.J. Epstein, Synth. Met., 78, 33 (1996).
Y.Z. Wang, D.D. Gebler, L.B. Lin, J.W. Blatchford, S.W. Jessen, H.L. Wang and A. Epstein, J. Appl. Phys. Lett., 68, 894 (1996).
A. Gok, M. Omastova and J. Prokes, Eur. Polym. J., 43, 2471 (2007).
K.G. Neoh, T.T. Young, N.T. Looi, E.T. Kang and K.L. Tan,Chem. Mater., 9, 2906 (1997).
J. Wang, K.G. Neoh and E.T. Kang, J. Colloid. Interf. Sci., 239, 78 (2000).
Y. Xu, L. Dai, J. Chen, J.Y. Gal and H. Wu, Eur. Polym. J., 43, 2072 (2007).
C. Basavaraja, Y. Veeranagouda, L. Kyoung, R. Pierson, M. Revanasiddappa and D.S. Huh, Bull. Korean Chem. Soc., 29, 2423 (2008).
K.H. Wu, C.M. Chao, C.H. Liu and T.C. Chang, Corr. Sci., 49, 3001 (2007).
S.A. Chen, K.R. Chung, C.I. Chao and H.T. Lee, Synth. Met., 82, 207 (1996).
S.L. Lim, K.L. Tan and E.T. Kang, Langmuir, 14, 5305 (1998).
C.P. Wong and S.B. Raja, J. Appl. Polym. Sci., 74, 3396 (1999).
Y. Haba, E. Segal, M. Narkis, G.I. Titleman and A. Siegmann, Synth. Met., 110, 189 (2000).
T.C.K. Yang, S.H.Y. Tsai, S.F. Wang and C.C. Juan,Compos. Sci. Technol., 62, 655 (2002).
R.H. Pelton and P. Chibante, Colloids Surf., 20, 247 (1986).
R.C. Silva, L. Arizmendi, M.D. Angel and J.R. Gracia, Langmuir, 23, 8 (2007).
B.C. Kim, G.M. Spinks, C.O. Too, G.G. Wallace, Y.H. Bae and N. Ogata, React. Funct. Polym., 44, 245 (2000).
R. Sinha and U. Dayal, Geoenvironmental Design Practices for Flyash Disposal and Utilization, Allied Publishers, New Delhi (2002).
C. Basavaraja, R. Pierson and D.S. Huh, J. App. Polym. Sci., 108, 1070 (2008).
C. Basavaraja, R. Pierson, T.K. Vishnuvardhan and D.S. Huh, Eur. Polym. J., 44, 1556 (2008).
H.L. Hwang, C.Y. Sun, C.Y. Leu, C.L. Cheng and C.C. Tu, Rev. Phys. Appl., 745 (1978).
A.B. Kaiser, Adv. Mater., 13, 927 (2001).
H.M. Rosenberg, Low Temperature Solid State Physics, Oxford University Press, U.K. (2000).
N.F. Mott and E.A. Davis, Electronic Process in Non-Crystalline Materials, Glarndon Press, Oxford (1971).
Z.X. Zhou, G. Cao, S. McCall, J.E. Grow, R.P. Guertin, C.H. Mielke and D.G. Rgckel, Philios. Magaz. B, 82, 1401 (2002).
S.F. Yasin, A.M. Zihlif and A. Ragosta, J. Mater. Sci., 16, 63 (2005).
S.C. Raghavendra, S. Khasim, M. Revanasiddappa, M.V.N. Ambika Prasad and A.B. Kulkarni, Bull. Mater. Sci., 26, 733 (2003).
C. Basavaraja, R. Pierson, T.K. Vishnuvardhan and D.S. Huh, Bull. Korean Chem. Soc., 29, 1669 (2008).

References

C.Y. Lee, H.G. Song, K.S. Jang, E.J. Oh, A.J. Epstien and J. Joo, Synth. Met., 102, 1346 (1999).

H.L. Wang, A.G. MacDiarmid, Y.Z. Wang, D.D. Gebler and A.J. Epstein, Synth. Met., 78, 33 (1996).

Y.Z. Wang, D.D. Gebler, L.B. Lin, J.W. Blatchford, S.W. Jessen, H.L. Wang and A. Epstein, J. Appl. Phys. Lett., 68, 894 (1996).

A. Gok, M. Omastova and J. Prokes, Eur. Polym. J., 43, 2471 (2007).

K.G. Neoh, T.T. Young, N.T. Looi, E.T. Kang and K.L. Tan,Chem. Mater., 9, 2906 (1997).

J. Wang, K.G. Neoh and E.T. Kang, J. Colloid. Interf. Sci., 239, 78 (2000).

Y. Xu, L. Dai, J. Chen, J.Y. Gal and H. Wu, Eur. Polym. J., 43, 2072 (2007).

C. Basavaraja, Y. Veeranagouda, L. Kyoung, R. Pierson, M. Revanasiddappa and D.S. Huh, Bull. Korean Chem. Soc., 29, 2423 (2008).

K.H. Wu, C.M. Chao, C.H. Liu and T.C. Chang, Corr. Sci., 49, 3001 (2007).

S.A. Chen, K.R. Chung, C.I. Chao and H.T. Lee, Synth. Met., 82, 207 (1996).

S.L. Lim, K.L. Tan and E.T. Kang, Langmuir, 14, 5305 (1998).

C.P. Wong and S.B. Raja, J. Appl. Polym. Sci., 74, 3396 (1999).

Y. Haba, E. Segal, M. Narkis, G.I. Titleman and A. Siegmann, Synth. Met., 110, 189 (2000).

T.C.K. Yang, S.H.Y. Tsai, S.F. Wang and C.C. Juan,Compos. Sci. Technol., 62, 655 (2002).

R.H. Pelton and P. Chibante, Colloids Surf., 20, 247 (1986).

R.C. Silva, L. Arizmendi, M.D. Angel and J.R. Gracia, Langmuir, 23, 8 (2007).

B.C. Kim, G.M. Spinks, C.O. Too, G.G. Wallace, Y.H. Bae and N. Ogata, React. Funct. Polym., 44, 245 (2000).

R. Sinha and U. Dayal, Geoenvironmental Design Practices for Flyash Disposal and Utilization, Allied Publishers, New Delhi (2002).

C. Basavaraja, R. Pierson and D.S. Huh, J. App. Polym. Sci., 108, 1070 (2008).

C. Basavaraja, R. Pierson, T.K. Vishnuvardhan and D.S. Huh, Eur. Polym. J., 44, 1556 (2008).

H.L. Hwang, C.Y. Sun, C.Y. Leu, C.L. Cheng and C.C. Tu, Rev. Phys. Appl., 745 (1978).

A.B. Kaiser, Adv. Mater., 13, 927 (2001).

H.M. Rosenberg, Low Temperature Solid State Physics, Oxford University Press, U.K. (2000).

N.F. Mott and E.A. Davis, Electronic Process in Non-Crystalline Materials, Glarndon Press, Oxford (1971).

Z.X. Zhou, G. Cao, S. McCall, J.E. Grow, R.P. Guertin, C.H. Mielke and D.G. Rgckel, Philios. Magaz. B, 82, 1401 (2002).

S.F. Yasin, A.M. Zihlif and A. Ragosta, J. Mater. Sci., 16, 63 (2005).

S.C. Raghavendra, S. Khasim, M. Revanasiddappa, M.V.N. Ambika Prasad and A.B. Kulkarni, Bull. Mater. Sci., 26, 733 (2003).

C. Basavaraja, R. Pierson, T.K. Vishnuvardhan and D.S. Huh, Bull. Korean Chem. Soc., 29, 1669 (2008).

Issue

Vol. 25 No. 1 (2013): Vol 25 Issue 1

Microscopic Studies of Polyaniline-poly-N-isopropylacrylamide-co-acrylic acid/ Flyash Composites Containing Dodecylbenzene Sulfonic Acid

Corresponding Author(s) : Shashidhar

Abstract

Keywords

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