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Synthesis and Structure of a Novel Thiacalix[4]arene based Triazine Derivative
Corresponding Author(s) : Xi Zeng
Asian Journal of Chemistry,
Vol. 25 No. 1 (2013): Vol 25 Issue 1
Abstract
Using thiacalix[4]arene and 1,3-bis-(dichloro-s-triazinyloxy)benzene as a starting materials, a novel thiacalix[4]arene based triazine derivative has been designed and synthesized. This nucleophilic displacement reaction occurred in mild condition. The conformation of 1,3-alternate was confirmed by NMR spectra and X-ray crystal structure analyses. Moreover, it formed a unique p-electron-deficient cavity has the potential to recognize cations and anions.
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- N. Morohashi, F. Narumi, N. Iki, T. Hattoriand and S. Miyano, Chem. Rev., 106, 5291 (2006).
- X.Y. Zheng, W.J. Zhang, L. Mu, X. Zeng, S.F. Xue, Z. Tao and T. Yamato, J. Incl. Phenom. Macrocycl. Chem., 68, 139 (2010).
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References
N. Morohashi, F. Narumi, N. Iki, T. Hattoriand and S. Miyano, Chem. Rev., 106, 5291 (2006).
X.Y. Zheng, W.J. Zhang, L. Mu, X. Zeng, S.F. Xue, Z. Tao and T. Yamato, J. Incl. Phenom. Macrocycl. Chem., 68, 139 (2010).
M.X. Wangand and H.B. Yang, J. Am. Chem. Soc., 126, 15413 (2004).
M. Kumar, A. Dhir and V. Bhalla, Eur. J. Org. Chem., 4535 (2009).