1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Zheng-Kun Wang2
1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Gang Li2
1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Meng-Meng Zhao2
1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Li-Sha Zhang2
1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Xin-Ying Zhang2
1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Jiao-Long Meng2
1School of Chemistry and Environmental Science, Lanzhou City University, Lanzhou 730070, P.R. China
2School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
*Corresponding author: E-mail: lisylcu@126.com
Two new complexes have been synthesized by the reaction of Mn(II) and Zn(II) salts with a Salamo-type chelating ligand 5,5',6,6'-tetrahydroxy-2,2'-[ethylene-1,2-diyldioxy)bis(nitrilomethylidyne)]diphenol (H6L) in anhydrous ethanol medium and characterized by elemental analyses, IR spectra, UV-visible spectra and molar conductances. The likely formulae of the Mn(II) and Zn(II) complexes may be suggested as [Mn3(HL)(CH3COO)]·EtOH (1) and [Zn3(HL)(CH3COO)]·EtOH (2).
Keywords
Salamo-type compoundTransition metal complexesSynthesis.
Full Article
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Li1, S.-Y., Wang2, Z.-K., Li2, G., Zhao2, M.-M., Zhang2, L.-S., Zhang2, X.-Y., & Meng2, J.-L. (2013). Synthesis and Characterization of Mn(II) and Zn(II) Complexes with Tetrahydroxyl Substituted Salamo-type Compound. Asian Journal of Chemistry, 25(18), 10434–10436. https://doi.org/10.14233/ajchem.2013.15638
