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Vol. 25 No. 16 (2013): Vol 25 Issue 16

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Action of Metal and Organometallic Halides and Pseudohalides Towards Stannoxanes

https://doi.org/10.14233/ajchem.2013.14969
Kiran Singhal
Department of Chemistry, Lucknow University, Lucknow-226 007, India
Subhas Kumar Chaudhary
Department of Chemistry, Lucknow University, Lucknow-226 007, India
Om Prakash
Department of Chemistry, Lucknow University, Lucknow-226 007, India

Corresponding Author(s) : Kiran Singhal

kiran.singhal@gmail.com

Asian Journal of Chemistry, Vol. 25 No. 16 (2013): Vol 25 Issue 16

Abstract

Interactions of HgX2 (X = Cl, Br, I, SCN, CN, NCO), SbCl3, TeCl4 and PhTeCl3 with (p-FC6H4)3Sn-O-Sn(p-FC6H4)3 at room temperature have been found to proceed with the simultaneous cleavage of Sn-O and Sn-C bonds, invariably yielding (p-FC6H4)2SnO, (p-FC6H4)3SnX and the corresponding organo-mercury, -antimony and -tellurium derivatives. The course of the reactions suggests the instability of the Sn-O-M (M = Hg, Sb, Te) system.

Keywords

Stannoxane Interactions metallic Organometallic-halides and pseudohalides
Singhal, K., Kumar Chaudhary, S., & Prakash, O. (2013). Action of Metal and Organometallic Halides and Pseudohalides Towards Stannoxanes. Asian Journal of Chemistry, 25(16), 9020–9022. https://doi.org/10.14233/ajchem.2013.14969
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