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Vol. 25 No. 16 (2013): Vol 25 Issue 16

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Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate

https://doi.org/10.14233/ajchem.2013.14925
Ting-Hai Yang
School of Chemistry & Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, Jiangsu Province, P.R. China ; Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal; State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P.R. China
Yin-Feng Han
Department of Chemistry and Environment Science, Taishan University, Taian, 271021, P.R. China
Fa-Nian Shi
Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal

Corresponding Author(s) : Ting-Hai Yang

yangtinghai@jsut.edu.cn

Asian Journal of Chemistry, Vol. 25 No. 16 (2013): Vol 25 Issue 16

Abstract

A novel complex, Zn2(Hpdc)2(Ox)(H2O)4] (H2pdc = pyridine-2,5-dicarboxylic acid, Ox = oxalate), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. Crystal structure analysis reveals that the compound crystallizes in monoclinic space group P2(1)/n, features an interesting 3D-supramolecular network via hydrogen bonding and p-p stacking interactions. Cell unit parameter for the compound: a = 10.2152(3) Å, b = 9.6535(3) Å, c = 10.3594(2) Å, b = 105.664º, V = 983.63(5) Å3, Z = 2, Mr = 623.05, Dc = 2.104 g/cm3, μ = 2.536 mm-1, F(000) = 628, T = 150(2) K, R = 0.0356, wR = 0.0612 for 2510 reflections with I > 2s(I).

Keywords

Crystal structure Zinc Hydrogen bond Pyridine-2,5-dicarboxylic acid
Yang, T.-H., Han, Y.-F., & Shi, F.-N. (2013). Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate. Asian Journal of Chemistry, 25(16), 8946–8948. https://doi.org/10.14233/ajchem.2013.14925
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