Synthesis and Spectroscopic Studies of Ru(II) Complexes of 1,2,4-Triazoles, 1,2,4-Triazines and Pyrimidine Derivatives

Abdullah M. Asiri; A.O. Baghlaf; R.M. Abdel-Rahman; Salman A. Khan; M. Ishaq

doi:10.14233/ajchem.2013.14604

Issue

Vol. 25 No. 14 (2013): Vol 25 Issue 14

Issue Published : 8 August 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Spectroscopic Studies of Ru(II) Complexes of 1,2,4-Triazoles, 1,2,4-Triazines and Pyrimidine Derivatives

https://doi.org/10.14233/ajchem.2013.14604

Abdullah M. Asiri

Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah-21589, Saudi Arabia

A.O. Baghlaf

Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah-21589, Saudi Arabia

R.M. Abdel-Rahman

Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah-21589, Saudi Arabia

Salman A. Khan

Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah-21589, Saudi Arabia

M. Ishaq

Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah-21589, Saudi Arabia

Corresponding Author(s) : Salman A. Khan

sahmad_phd@yahoo.co.in

Asian Journal of Chemistry, Vol. 25 No. 14 (2013): Vol 25 Issue 14
Article Published : 12 August 2013

Abstract

Treatment of the dichlorodicarbonyl ruthenium(II) [Ru(CO)₂Cl₂]_n with bidentate 1,2,4-triazoles, 1,2,4-triazines and pyrimidine derivatives in refluxing ethanol or in THF yielded stable, octahedral yellow or pale-yellow solids. All the complexes have been characterized by IR, ¹H NMR spectroscopy and elemental analyses.

Keywords

Ruthenium(II) Triazoles Triazines Pyrimidine

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M. Asiri, A.; Baghlaf, A.; Abdel-Rahman, R.; A. Khan, S.; Ishaq, M. Synthesis and Spectroscopic Studies of Ru(II) Complexes of 1,2,4-Triazoles, 1,2,4-Triazines and Pyrimidine Derivatives. ajc 2013, 25, 7779-7782.