Study on Novel Structure of Molybdenum Tungsten Imidazole Complex: (H12MoW7O30)(C3H4N2)4(H2O)3

Hai-Xing Liu; Qing Liu; Lin-Tong Wang; Kai-Qi Ye; Jing-Zhong Xiao; Guang Zeng; Xi-Shi Tai

doi:10.14233/ajchem.2013.14661

Issue

Vol. 25 No. 14 (2013): Vol 25 Issue 14

Issue Published : 8 August 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Study on Novel Structure of Molybdenum Tungsten Imidazole Complex: (H12MoW7O30)(C3H4N2)4(H2O)3

https://doi.org/10.14233/ajchem.2013.14661

Hai-Xing Liu

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Qing Liu

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

Lin-Tong Wang

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Kai-Qi Ye

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

Jing-Zhong Xiao

CEMDRX, Department of Physics, University of Coimbra, Coimbra 3004-516, Portugal

Guang Zeng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

Xi-Shi Tai

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Corresponding Author(s) : Hai-Xing Liu

haixingliu@tom.com

Asian Journal of Chemistry, Vol. 25 No. 14 (2013): Vol 25 Issue 14
Article Published : 13 August 2013

Abstract

A novel molybdenum tungsten imidazole complex (H₁₂MoW₇O₃₀)(C₃H₄N₂)₄(H₂O)₃ with the m.f. C₁₂H₃₄MoN₈O₃₃W₇ has been synthesized from a single solution reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. The Mo atom is coordinated by seven O atoms. There are two kinds coordinations mode for W atom. The crystal is stabilized by O-H···O and N-H···O hydrogen bonds interaction.

Keywords

Molybdenum tungsten complex Imidazole Structure analysis

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Liu, H.-X.; Liu, Q.; Wang, L.-T.; Ye, K.-Q.; Xiao, J.-Z.; Zeng, G.; Tai, X.-S. Study on Novel Structure of Molybdenum Tungsten Imidazole Complex: (H12MoW7O30)(C3H4N2)4(H2O)3. ajc 2013, 25, 8227-8228.