Synthesis and Crystal Structure of Phosphorus Vanadium Heteropoly Acid Potassium Compound: (K12P4V72O172)&middot;24Cl&middot;24(OH)&middot;14.4H2O

Hai-Xing Liu; Qing Liu; Lin-Tong Wang; Huan-Mei Guo; Kai-Qi Ye; Guang Zeng; Xi-Shi Tai

doi:10.14233/ajchem.2013.14607

Issue

Vol. 25 No. 14 (2013): Vol 25 Issue 14

Issue Published : 8 August 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of Phosphorus Vanadium Heteropoly Acid Potassium Compound: (K12P4V72O172)·24Cl·24(OH)·14.4H2O

https://doi.org/10.14233/ajchem.2013.14607

Hai-Xing Liu

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Qing Liu

College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P.R. China

Lin-Tong Wang

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Huan-Mei Guo

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Kai-Qi Ye

College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P.R. China

Guang Zeng

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R. China

Xi-Shi Tai

Chemistry and Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R. China

Corresponding Author(s) : Hai-Xing Liu

haixingliu@tom.com

Asian Journal of Chemistry, Vol. 25 No. 14 (2013): Vol 25 Issue 14
Article Published : 13 August 2013

Abstract

Phosphorus vanadium heteropoly acid potassium: (K₁₂P₄V₇₂O₁₇₂)·24Cl·24(OH)·14.4(H₂O), is prepared by the hydrothermal method. Cubic, Fm-3m. a = b = c = 21.866(2) Å a = b = g = 90º. V = 10454.6(17) Å³. Z = 2. R₁ = 0.0479, wR₂ = 0.1191. T = 291(2) K. The V atoms are linked with O atom bridge. It is striking that the structure of the phosphorus vanadium heteropoly acid potassium exhibits extensive hydrogen-bonding interactions.

Keywords

Heteropoly acid Structure analysis

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Liu, H.-X.; Liu, Q.; Wang, L.-T.; Guo, H.-M.; Ye, K.-Q.; Zeng, G.; Tai, X.-S. Synthesis and Crystal Structure of Phosphorus Vanadium Heteropoly Acid Potassium Compound: (K12P4V72O172)·24Cl·24(OH)&Middot;14.4H2O. ajc 2013, 25, 8217-8218.