Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, P.R. China
Xingjun Wang
Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, P.R. China
Shupeng Zhan
Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, P.R. China
Guangsuo Yu
Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai Engineering Research Center of Coal Gasification, East China University of Science and Technology, Shanghai 200237, P.R. China
Asian Journal of Chemistry,
Vol. 25 No. 13 (2013): Vol 25 Issue 13
Steam gasification of Hohhot coal char, demineralized Hohhot coal char and several catalysts loaded samples including alkali, slaked lime and transition metal based compounds was performed under 700 ºC and atmospheric pressure. A three-step steam gasification mechanism based on carbon-oxygen intermediate C(O) is proposed for the understanding of experimental data regarding both the kinetic behavior and reaction selectivity. The characteristics of reaction rate and the selectivity of CO, CO2 and C(O) under the effect of different catalysts were discussed. It was found that the catalyst is more effective for the H2O involved reaction steps which is probably due to the oxygen transfer function of catalyst from H2O to carbon surface.
Hong, B., Wang, X., Zhan, S., & Yu, G. (2013). Analysis of Non-Catalytic and Catalytic Steam Gasification of Hohhot Coal Char. Asian Journal of Chemistry, 25(13), 7467–7470. https://doi.org/10.14233/ajchem.2013.14852
