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Vol. 25 No. 11 (2013): Vol 25 Issue 11

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A Novel and Green Method for the Synthesis of Benzo-15-crown-5 Containing Sulphonylthiourea-Based Receptors

https://doi.org/10.14233/ajchem.2013.14334
Cong-Wen Ding
Institute of Fine Chemical Industry, Department of Chemistry and Chemical Industry, College of Life Sciences, Tarim University, Alaer 843300, Xinjiang Province, P.R. China
Yue-Feng Zhang
Institute of Fine Chemical Industry, Department of Chemistry and Chemical Industry, College of Life Sciences, Tarim University, Alaer 843300, Xinjiang Province, P.R. China
Hai-Feng Yu
Institute of Fine Chemical Industry, Department of Chemistry and Chemical Industry, College of Life Sciences, Tarim University, Alaer 843300, Xinjiang Province, P.R. China

Corresponding Author(s) : Cong-Wen Ding

dingcw19731008@163.com

Asian Journal of Chemistry, Vol. 25 No. 11 (2013): Vol 25 Issue 11

Abstract

The nucleophilic reaction of 4'-aminobenzo-15-crown-5 and carbon disulphide in aqueous KOH afforded corresponding dithiocarbamate salt. Subsequent nucleophilic substitution reactions with sulfonamides aqueous NaOH provided benzo-15-crown-5-containing sulphonylthioureas. This novel, green method has the advantages of simple operation, high yields, easy product-isolation and environmental friendliness.

Keywords

Aqueous media Benzo-15-crown-5-dithiocarbamate salt Sulfonamides Sulphonylthioureas
Ding, C.-W., Zhang, Y.-F., & Yu, H.-F. (2013). A Novel and Green Method for the Synthesis of Benzo-15-crown-5 Containing Sulphonylthiourea-Based Receptors. Asian Journal of Chemistry, 25(11), 6237–6239. https://doi.org/10.14233/ajchem.2013.14334
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