Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Flame Retardant Synergism of Bentonite and Magnesium Hydroxide in Polypropylene
Corresponding Author(s) : Jingwei Yang
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
The flammability characterization and synergistic effect of bentonite with magnesium hydroxide in polypropylene have been studied in this work. A synergistic effect on flame retardancy was found when bentonite was incorporated into magnesium hydroxide/polypropylene composites. The mass ratio of magnesium hydroxide and bentonite should be 37:3 and the loading of magnesium hydroxide and bentonite should be 45-50 % to get better flame-retardant effect and mechanical properties according to the experimental results. The flame retardant synergism of bentonite and magnesium hydroxide in polypropylene is further illustrated by the horizontal burning rates. Thermogravimetric analysis revealed that the addition of magnesium hydroxide or bentonite/magnesium hydroxide improves the thermal stability of the composites. The fire performance of polypropylene and polypropylene composites was compared by cone calorimeter test, which indicated that the addition of bentonite/magnesium hydroxide in polypropylene system greatly reduced the heat release rate and mass loss rate.
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References
M.M. Hirschler and T.R. Thevaranjan, Eur. Polym. J., 21, 371 (1985).
L. Delfosse, C. Baillet, A. Brault and D. Brault, Polym. Degrad. Stab., 23, 337 (1989).
P.R. Hornsby and C.L. Watson, Polym. Degrad. Stab., 30, 73 (1990).
R.N. Rothon and P.R. Hornsby, Polym. Degrad. Stab., 54, 383 (1996).
H. Gui, X. Zhang, Y. Liu, W. Dong, Q. Wang, J. Gao, Z. Song, J. Lai and J. Qiao, Compos. Sci. Technol., 67, 974 (2007).
H. Cao, H. Zheng, J. Yin, Y. Lu, S. Wu, X. Wu and B. Li, J. Phys. Chem. C, 114, 17362 (2010).
J. Formosa, J.M. Chimenos, A.M. Lacasta and L. Haurie, Thermochim. Acta, 515, 43 (2011).
A.A. Sener and E. Demirhan, Mater. Design, 29, 1376 (2008).
F. Laoutid, L. Bonnaud, M. Alexandre, J.M. Lopez-Cuesta and P. Dubois, Mater. Sci. Eng. Reports, 63, 100 (2009).
J. Liang and Y. Zhang, Polym. Int., 59, 539 (2010).
T. Xu, X. Huang and Y. Zhao, Fire Safety J., 46, 330 (2011).
L. Ye, Q. Wu and B. Qu, Polym. Degrad. Stab., 94, 751 (2009).
G. Zhang, P. Ding, M. Zhang and B. Qu, Polym. Degrad. Stab., 92, 1715 (2007).
G. Fei, Y. Liu and Q. Wang, Polym. Degrad. Stab., 93, 1351 (2008).
M. Fu and B. Qu, Polym. Degrad. Stab., 85, 633 (2004).
Z. Li and B. Qu, Polym. Degrad. Stab., 81, 401 (2003).
G. Song, S. Ma, G. Tang, Z. Yin and X. Wang, Energy, 35, 2179 (2010).
H. Gui, X. Zhang, W. Dong, Q. Wang, J. Gao, Z. Song, J. Lai, Y. Liu, F. Huang and J. Qiao, Polymer, 48, 2537 (2007).
S. Bourbigot, S. Duquesne, Z. Sébih, S. Ségura and R. Delobel, Fire and Polymers IV, American Chemical Society, p. 200 (2005).
X. Chen, H. Wu, Z. Luo, B. Yang, S. Guo and J. Yu, Polym. Eng. Sci., 47, 1756 (2007).
Z. Wang, B. Qu, W. Fan and P. Huang, J. Appl. Polym. Sci., 81, 206 (2001).
F. Carpentier, S. Bourbigot, M. Le Bras, R. Delobel and M. Foulon, Polym. Degrad. Stab., 69, 83 (2000).
H. Dvir, M. Gottlieb, S. Daren and E. Tartakovsky, Compos. Sci. Technol., 63, 1865 (2003).
M. Sain, S.H. Park, F. Suhara and S. Law, Polym. Degrad. Stab., 83, 363 (2004).
A.B. Shehata, Polym. Degrad. Stab., 85, 577 (2004).
X. Chen, J. Yu and S. Guo, J. Appl. Polym. Sci., 102, 4943 (2006).
B.B. Marosfoi, S. Garas, B. Bodzay, F. Zubonyai and G. Marosi, Polym. Adv. Technol., 19, 693 (2008).
J. Yang, J.Z. Liang and C.Y. Tang, Polym. Test., 28, 907 (2009).
N. Suppakarn and K. Jarukumjorn, Compos. Part. B-Eng., 40, 613 (2009).
J.-Z. Liang, J. Yang and C.-Y. Tang, Polym. Test., 29, 624 (2010).
R. Gul, A. Islam, T. Yasin and S. Mir, J. Appl. Polym. Sci., 121, 2772 (2011).
J.B. Dahiya, M. Muller-Hagedorn, H. Bockhorn and B.K. Kandola, Polym. Degrad. Stabil., 93, 2038 (2008).
B. Du, Z. Guo, P. Song, H. Liu, Z. Fang and Y. Wu, Appl. Clay. Sci., 45, 178 (2009).
L. Tang, M. Su, J. Yang and K. Yu, Asian. J. Chem., 23, 4093 (2011).