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Microwave Assisted Synthesis of meso-Tetraphenylporphyrin and Its Application for Trace Metal Spectrophotometric Determination
Corresponding Author(s) : M.H. Givianrad
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
The synthesis of meso-tetraphenylporphyrin with quantitative yield in presence of p-toluene sulfonic acid as new catalyst under microwave irradiation was accomplished. The meso-tetraphenylporphyrin was characterized by means of elemental analysis, UV-visible spectra, 1H NMR spectra, infrared spectra and was used as chelating agent for direct determination of zinc ions by UV-visible spectroscopy.
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- K.M. Smith, Porphyrins and Metalloporphyrins, Ed. Elsevier, Amsterdam (1975).
- L.R. Milgrom, The Colours of Life, Oxford Press, New York (1997).
- H. Fischer and A. Stern, Die Chemie Des Pyrroles, 2, 48 (1940).
- D.F. Marsh and L.M. Mink, J. Chem. Ed., 73, 1181 (1996).
- R. Lemberg and J.W. Legge, Haematin Compoundsand Bile Pigments, Interscience, New York (1949).
- J.E. Falk, Porphyrins and Metalloporphyrins, Elsevier, New York (1975).
- M. Biesaga, K. Pyrzynska and M. Trojanowicz, Talanta, 51, 209 (2000).
- R.F. Beeston, S.E. Stitzel and M.A. Rhea, J. Chem. Educ., 74, 1468 (1997).
- A. Loupy, A. Petit, J. Hamelin, F. Texier-Boullet, P. Jacquault and P. Mathe, Synthesis, 1213 (1998).
- I. Elghamry and L.F. Tietze, Tetrahedron Lett., 49, 3972 (2008).
- M.O. Liu, Ch.H. Tai, W.Y. Wang, J.R. Chen, A.T. Hu and T.H. Wei, J. Organomet. Chem., 689, 1078 (2004).
- M. Chandrasekharam, Ch.S. Rao, S.P. Singh, M.L. Kantam, M.R. Reddy, P.Y. Reddy and T. Toru, Tetrahedron Lett., 48, 2627 (2007).
- Y. Nagao, T. Naito, Y. Abe and T. Misono, Dyes Pigments, 32, 71 (1996).
- R. Bonnett, S. Loannou,A.G. James, C.W. Pitt and M.M. Soe, J. Mater. Chem., 3, 793 (1993).
- E.C. Franklin, J. Am. Chem. Soc., 46, 2137 (1924).
References
K.M. Smith, Porphyrins and Metalloporphyrins, Ed. Elsevier, Amsterdam (1975).
L.R. Milgrom, The Colours of Life, Oxford Press, New York (1997).
H. Fischer and A. Stern, Die Chemie Des Pyrroles, 2, 48 (1940).
D.F. Marsh and L.M. Mink, J. Chem. Ed., 73, 1181 (1996).
R. Lemberg and J.W. Legge, Haematin Compoundsand Bile Pigments, Interscience, New York (1949).
J.E. Falk, Porphyrins and Metalloporphyrins, Elsevier, New York (1975).
M. Biesaga, K. Pyrzynska and M. Trojanowicz, Talanta, 51, 209 (2000).
R.F. Beeston, S.E. Stitzel and M.A. Rhea, J. Chem. Educ., 74, 1468 (1997).
A. Loupy, A. Petit, J. Hamelin, F. Texier-Boullet, P. Jacquault and P. Mathe, Synthesis, 1213 (1998).
I. Elghamry and L.F. Tietze, Tetrahedron Lett., 49, 3972 (2008).
M.O. Liu, Ch.H. Tai, W.Y. Wang, J.R. Chen, A.T. Hu and T.H. Wei, J. Organomet. Chem., 689, 1078 (2004).
M. Chandrasekharam, Ch.S. Rao, S.P. Singh, M.L. Kantam, M.R. Reddy, P.Y. Reddy and T. Toru, Tetrahedron Lett., 48, 2627 (2007).
Y. Nagao, T. Naito, Y. Abe and T. Misono, Dyes Pigments, 32, 71 (1996).
R. Bonnett, S. Loannou,A.G. James, C.W. Pitt and M.M. Soe, J. Mater. Chem., 3, 793 (1993).
E.C. Franklin, J. Am. Chem. Soc., 46, 2137 (1924).