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A Novel Mn(II) Complex: Synthesis, Characterization and Magnetic Property
Corresponding Author(s) : Jing Hu
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
A new Mn(II) complex: [Mn(HBTC)(H2O)3] where HBTC = 1,3,5-benzene tricarboxylic acid has been synthesized and characterized by IR spectra and elemental analysis. The relationship between the temperature and the magnetic susceptibility of the complex over the range 5~300 K indicates the presence of a antiferromagnetic interactions in the Mn(II) ions of the complex.
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- K.L. Yao, Q.M. Liu and Z.L. Liu, J. Phys. Rev. B, 70, 224430 (2004).
- M.H. Whangbo, H.J. Koo, D. Dai and D. Jung, Inorg. Chem., 41, 5575 (2002).
- Y. Takano and Y. Kitagawa, J. Am. Chem. Soc., 124, 450 (2002).
- I.K. Maj, S. Sain, G. Mostafa, T.H. Lu, J. Ribas, M. Monfort and N.R. Chaudhuri, Inorg. Chem., 42, 709 (2003).
- S. Chattopadhyay, R.A. Geiger, G.C. Yin, D.H. Busch and T.A. Jackson, Inorg. Chem., 49, 7530 (2010).
- G. Izzet, E. Ishow, J. Delaire, C. Afonso, J.C. Tabet and A. Proust, Inorg. Chem., 48, 11865 (2009).
- K. Ghosh, N. Tyagi, P. Kumar, U.P. Singly and N. Goel, J. Inorg. Biochem., 104, 9 (2010).
- G. Bhargavi, M.V. Rajasekharan and J.P. Tuchagues, Inorg Chim. Acta, 362, 3247 (2009).
- F.A. Mautner, A. Egger, B. Sodin, M.A.S. Goher, M.A.M. Abu-Youssef, A. Massoud, A. Escuer and R. Vicente, J. Mol. Struct.,. 969, 192 (2010)
References
K.L. Yao, Q.M. Liu and Z.L. Liu, J. Phys. Rev. B, 70, 224430 (2004).
M.H. Whangbo, H.J. Koo, D. Dai and D. Jung, Inorg. Chem., 41, 5575 (2002).
Y. Takano and Y. Kitagawa, J. Am. Chem. Soc., 124, 450 (2002).
I.K. Maj, S. Sain, G. Mostafa, T.H. Lu, J. Ribas, M. Monfort and N.R. Chaudhuri, Inorg. Chem., 42, 709 (2003).
S. Chattopadhyay, R.A. Geiger, G.C. Yin, D.H. Busch and T.A. Jackson, Inorg. Chem., 49, 7530 (2010).
G. Izzet, E. Ishow, J. Delaire, C. Afonso, J.C. Tabet and A. Proust, Inorg. Chem., 48, 11865 (2009).
K. Ghosh, N. Tyagi, P. Kumar, U.P. Singly and N. Goel, J. Inorg. Biochem., 104, 9 (2010).
G. Bhargavi, M.V. Rajasekharan and J.P. Tuchagues, Inorg Chim. Acta, 362, 3247 (2009).
F.A. Mautner, A. Egger, B. Sodin, M.A.S. Goher, M.A.M. Abu-Youssef, A. Massoud, A. Escuer and R. Vicente, J. Mol. Struct.,. 969, 192 (2010)