Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis and Crystal Structure of 4,4'-Dimethyl-1,1'-[butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene
Asian Journal of Chemistry,
Vol. 25 No. 11 (2013): Vol 25 Issue 11
Abstract
A new bisoxime compound, 4,4'-dimethyl-1,1'-[butane-1,4-diyldioxy)bis(nitrilomethylidyne)]dibenzene, has been synthesized and characterized structurally. There is a crystallographic twofold rotation axis passing through the middle point of the -CH2-CH2-CH2-CH2- linkage. The molecule adopts a trans-conguration with respect to the methylidene unit. There are no intramolecular and intermolecular hydrogen bonds. The two phenyl rings in each molecule are parallel to each other with a perpendicular interplanar spacing of ca. 1.266(3) Å.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- J.P. Costes, F. Dahan and A. Dupuis, Inorg. Chem., 39, 165 (2000).
- W.K. Dong, X.N. He, Y.X. Sun, L. Xu and Y.H. Guan, Acta Cryst., E64, o1917 (2008).
- P. Pfeiffer, E. Breith, E. Lubbe and T.L. Tsumaki, Ann. Chem., 503, 84 (1933).
- S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002).
- N.C. Hoshino, Chem. Rev., 174, 77 (1998).
- S.D. Bella and I. Fragalà, Synth. Met., 115, 191 (2000).
- W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010).
- W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009).
- W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transition Met. Chem., 37, 271 (2012)
References
J.P. Costes, F. Dahan and A. Dupuis, Inorg. Chem., 39, 165 (2000).
W.K. Dong, X.N. He, Y.X. Sun, L. Xu and Y.H. Guan, Acta Cryst., E64, o1917 (2008).
P. Pfeiffer, E. Breith, E. Lubbe and T.L. Tsumaki, Ann. Chem., 503, 84 (1933).
S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002).
N.C. Hoshino, Chem. Rev., 174, 77 (1998).
S.D. Bella and I. Fragalà, Synth. Met., 115, 191 (2000).
W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010).
W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009).
W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transition Met. Chem., 37, 271 (2012)