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Study of Cure Kinetics of Vinyl-tri(phenylethynyl)silane Monomer
Corresponding Author(s) : Yanli Wang
Asian Journal of Chemistry,
Vol. 25 No. 10 (2013): Vol 25 Issue 10
Abstract
An isothermal cure kinetics of vinyl-tri(phenylethynyl)silane ((ph-C=C)3-Si-C=CH2) (VTPES) was investigated by differential scanning calorimetry in the temperature range 345-370 ºC. The results showed that the shapes of the conversion curves were all similar and all of the cure reactions could be described by an autocatalytic kinetic model.
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- L.K. Luneva, A.M. Sladkov and V.V. Korshak, Izv. Akad. Nauk. SSSR, 1, 160 (1968).
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- M. Itoh, K. Inoue and N. Hirayama, J. Mater. Sci., 37, 3795 (2002).
- W.Y. Wong, C.K. Wong and G.L. Lu, Macromolecules, 36, 983 (2003).
- J.C. Sanchez and W.C.T. Trogler, Macromol. Chem. Phys., 209, 1527 (2008).
- C.I. Simionescu, V. Persec and S. Dumestrescu, J. Polym. Sci. Polym. Chem. Ed., 15, 2497 (1977).
- S.S. Swanson, W.W. Fleming and D.C. Hofer, Macromolecules, 25, 582 (1992).
- E.D. William, Eur. Polym. J., 29, 1513 (1993).
- E.T. Sabourin, J. Mol. Catal., 26, 363 (1984).
- S.B. Sastri, J.P. Armistead and T.M. Keller, Polymer, 36, 1449 (1995).
- S.B. Sastri, T.M. Keller, K.M. Jones and J.P. Armistead, Macromolecules, 26, 6171 (1993).
- Z. Luo, L. Wei, W. Li, F. Liu and T. Zhao, J. Appl. Polym. Sci., 109, 525 (2008).
- Z.L. Dai, Q. Chen, L.Z. Ni, N. Song and W.K. Zhang, J. Appl. Polym. Sci., 100, 2126 (2006).
- D. Tan, T. Shi and Z. Li, Res. Chem. Intermed., 37, 831 (2011).
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- J.Y. Lee, M.J. Shim and S.W. Kim, Mater. Chem. Phys., 48, 36 (1997).
References
L.K. Luneva, A.M. Sladkov and V.V. Korshak, Izv. Akad. Nauk. SSSR, 1, 160 (1968).
T.J. Barton, I.M. Sina and Y. Pang, Macromolecules, 24, 1257 (1991).
Y. Pang, I.M. Sina and T. Barton, J. Macromol., 26, 5671 (1993).
M. Itoh, K. Inoue and K. Iwata, Adv Mater., 9, 1187 (1997).
M. Itoh, K. Inoue and N. Hirayama, J. Mater. Sci., 37, 3795 (2002).
W.Y. Wong, C.K. Wong and G.L. Lu, Macromolecules, 36, 983 (2003).
J.C. Sanchez and W.C.T. Trogler, Macromol. Chem. Phys., 209, 1527 (2008).
C.I. Simionescu, V. Persec and S. Dumestrescu, J. Polym. Sci. Polym. Chem. Ed., 15, 2497 (1977).
S.S. Swanson, W.W. Fleming and D.C. Hofer, Macromolecules, 25, 582 (1992).
E.D. William, Eur. Polym. J., 29, 1513 (1993).
E.T. Sabourin, J. Mol. Catal., 26, 363 (1984).
S.B. Sastri, J.P. Armistead and T.M. Keller, Polymer, 36, 1449 (1995).
S.B. Sastri, T.M. Keller, K.M. Jones and J.P. Armistead, Macromolecules, 26, 6171 (1993).
Z. Luo, L. Wei, W. Li, F. Liu and T. Zhao, J. Appl. Polym. Sci., 109, 525 (2008).
Z.L. Dai, Q. Chen, L.Z. Ni, N. Song and W.K. Zhang, J. Appl. Polym. Sci., 100, 2126 (2006).
D. Tan, T. Shi and Z. Li, Res. Chem. Intermed., 37, 831 (2011).
T. Hatakeyama and F.X. Quinn, Thermal Analysis Fundamentals and Application to Polymer Science; Wiley: New York, p. 77 (1999).
J.Y. Lee, M.J. Shim and S.W. Kim, Mater. Chem. Phys., 48, 36 (1997).