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Study of Surface Modification of Ultra-Fine CaCO3 With Different Coupling Agent
Corresponding Author(s) : Guojun Cheng
Asian Journal of Chemistry,
Vol. 25 No. 10 (2013): Vol 25 Issue 10
Abstract
To compare the superficial capacity of ultra-fine calcium carbonate powder, the coupling agents of g-aminopropyl triethoxyl silane (KH550), g-methacryloxypropyl trimethoxy silane (KH-570), vinyltrimethoxy silane (SG-Si 171) and di(dioctylpyrophosphato)ethylene titanate (NDZ-311) were used as modifiers to modify its surface activity. The structural changes and properties of the unmodified and modified ultra-fine CaCO3 powder were characterized by Fourier transform infrared spectroscopy, contact angle measuring instrument (CAMI) and sedimentation stability experiment. The results showed that the coupling agent bonds covalently onto the surface of CaCO3 particles and forms an organic coating layer. Contact angle measuring instrument indicated that the coupling agent molecules were absorbed or anchored on the surface of CaCO3 particles, which facilitates to hinder the aggregation of CaCO3 particles.
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- X. Gao, Y. Guo, Y. Tian, S. Li, S. Zhou and Z. Wang, Colloids Surf. A, 384, 2 (2011).
- H. Ishida, S. Campbell and J. Blackwell, J. Chem. Mater., 12, 1260 (2000).
- C.L. Wu, M.Q. Zhang, M.Z. Rong and K. Friedrich, Comp. Sci. Technol., 65, 635 (2005).
- H.V. Tran and L.D. Tran, Colloids Surf. A, 366, 95 (2010).
- H. Ding, S.C. Lu and Y.X. Deng, Trans. Nonferrous Met. Soc. China, 17, 1100 (2007).
- F. Touaiti, P. Alam and M. Toivakka, Mater. Sci. Eng. A, 527, 2363 (2010).
- H.W. He, K.X. Li and J. Wang, Mater. Design, 32, 4521 (2011).
- Z.S. Hu and Y.L. Deng, Ind. Eng. Chem. Res., 49, 5625 (2010).
- X.Y. Gao, B. Zhou and Y.P. Guo, Colloids Surf. A, 371, 1 (2010).
- W. Gao, X.Y. Ma and Z.C. Wang, Colloids Surf. A, 389, 30 (2011).
- Y. Li, Z.F. Zhao and Y.T.R. Lau, Y. Lin and C.-M. Chan, J. Colloid Interf. Sci., 345, 168 (2010).
- Y.L. Tai, J.S. Qian, J.B. Miao and Y.C. Zhang, Mater. Design, 5, 1 (2011).
- Z.W. Li and Y.F. Zhu, Appl. Surf. Sci., 211, 315 (2003).
- F.S. Yang, J.L. Qu and Z.Y. Yang, J. China Univ. Mining Technol., 1, 25 (2007).
- C. Ocando, A. Tercjak and I. Mondragon, Eur. Polym. J., 47, 1240 (2011).
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- Y.L. Tai, J.S. Qian and Y.C. Zhang, Chem. Eng. J., 141, 354 (2008)
References
X. Gao, Y. Guo, Y. Tian, S. Li, S. Zhou and Z. Wang, Colloids Surf. A, 384, 2 (2011).
H. Ishida, S. Campbell and J. Blackwell, J. Chem. Mater., 12, 1260 (2000).
C.L. Wu, M.Q. Zhang, M.Z. Rong and K. Friedrich, Comp. Sci. Technol., 65, 635 (2005).
H.V. Tran and L.D. Tran, Colloids Surf. A, 366, 95 (2010).
H. Ding, S.C. Lu and Y.X. Deng, Trans. Nonferrous Met. Soc. China, 17, 1100 (2007).
F. Touaiti, P. Alam and M. Toivakka, Mater. Sci. Eng. A, 527, 2363 (2010).
H.W. He, K.X. Li and J. Wang, Mater. Design, 32, 4521 (2011).
Z.S. Hu and Y.L. Deng, Ind. Eng. Chem. Res., 49, 5625 (2010).
X.Y. Gao, B. Zhou and Y.P. Guo, Colloids Surf. A, 371, 1 (2010).
W. Gao, X.Y. Ma and Z.C. Wang, Colloids Surf. A, 389, 30 (2011).
Y. Li, Z.F. Zhao and Y.T.R. Lau, Y. Lin and C.-M. Chan, J. Colloid Interf. Sci., 345, 168 (2010).
Y.L. Tai, J.S. Qian, J.B. Miao and Y.C. Zhang, Mater. Design, 5, 1 (2011).
Z.W. Li and Y.F. Zhu, Appl. Surf. Sci., 211, 315 (2003).
F.S. Yang, J.L. Qu and Z.Y. Yang, J. China Univ. Mining Technol., 1, 25 (2007).
C. Ocando, A. Tercjak and I. Mondragon, Eur. Polym. J., 47, 1240 (2011).
C. Li, J.H. Wan and H.H. Sun, J. Hazard. Mater., 179, 515 (2010).
Y.L. Tai, J.S. Qian and Y.C. Zhang, Chem. Eng. J., 141, 354 (2008)