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Sorptive Elimination of Alizarin Red-S Dye from Water Using Citrullus lanatus Peels in Environmentally Benign Way Along with Equilibrium Data Modeling
Corresponding Author(s) : Rabia Rehman
Asian Journal of Chemistry,
Vol. 25 No. 10 (2013): Vol 25 Issue 10
Abstract
Textile industry effluents comprised of various toxic and non biodegradable chemicals, especially non-adsorbed dyeing materials, having synthetic origin. Alizarin Red-S dye is one such examples. In this work, sorptive removal of Alizarin Red-S from water was investigated using Citrullus lanatus peels, in batch mode on laboratory scale. It was observed that adsorption of dye on Citrullus lanatus peels increases with increasing contact time and temperature, but decreases with increasing pH. Isothermal modeling indicated that physio-sorption occurred more as compared to chemi-sorption during adsorption of Alizarin Red-S by Citrullus lanatus peels, with qm 79.60 mg g-1. Thermodynamic and kinetic investigations revealed that this process was favourable and endothermic in nature, following pseudo-second order kinetics.
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- Z. Belala, M. Jeguirim, M. Belhachemi, F. Addoun and G. Trouvé, Desalination, 271, 80 (2011).
- T. Akar, I. Tosun, Z. Kaynak, E. Ozkara, O. Yeni, E.N. Sahin and S.T. Akar, J. Hazard. Mater., 166, 1217 (2009).
- R. Rehman, T. Mahmud, J. Anwar, M. Salman, U. Shafique, W. Zaman and F. Ali, J. Chem. Soc. Pak., 33, 228 (2011).
- J. Huang and K. Zhang, Desalination, 282, 19 (2011).
- M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim and A. Idris, Desalination, 280, 1 (2011).
- M.S. Tanyildizi, Chem. Eng. J., 168, 1234 (2011).
- G. Moussavi and R. Khosravi, Chem. Eng. Res. Des., 89, 2182 (2011).
- N.M. Mahmoodi and B. Hayati, M. Arami and C. Lan, Desalination, 268, 117 (2011).
- R. Baccar, P. Blánquez, J. Bouzid, M. Feki and M. Sarrà, Chem. Eng. J., 165, 457 (2010).
- R. Rehman, A. Abbas, A. Ayub, Qurat-ul-Ain, M. Salman, T. Mahmud, U. Shafique and W. Zaman, EJEAFChe, 10, 2531 (2011).
- M.A. Ahmad and N.K. Rahman, Chem. Eng. J., 170, 154 (2011).
- S.P. Sangal, Microchem. J., 9, 26 (1965).
- M.J. Iqbal and M.N. Ashiq, J. Hazard. Mater., 139, 57 (2007).
- A.M. Rimando and P. Perkins-Veazie, J. Chromatogr. A, 1078, 196 (2005).
- M.O. Oluwamukomi, Afr. J. Food Sci., 3, 117 (2009).
- M. Tarek, A.M. Magda, A.M. Saleh, S.M. Afaf and Fahmy, Bioresour. Technol., 68, 215 (1999).
- M.B. Ibrahim and W.L.O. Jimoh, Indian J. Sci. Technol., 4, 487 (2011).
- A. Addo and A. Bart-Plange, ARPN J. Agric. Biol. Sci., 4, 14 (2009).
- S.T. Akar, S. Arslan, T. Alp, D. Arslan and T. Akar, Chem. Eng. J., 185-186, 82 (2012).
- N.A. Aviara and O.O. Ajibola, J. Food Eng., 55, 107 (2002).
- C. Djilani, R. Zaghdoudi, A. Modarressi, M. Rogalski, F. Djazi and A. Lallam, Chem. Eng. J., 189-190, 203 (2012).
- R. Rehman, J. Anwar and T. Mahmud, J. Chem. Soc. Pak., 34, 460 (2012).
- R. Sowmeyan, J. Santhosh and R. Latha,Int. Res. J. Biochem. Bioinform., 1, 297 (2011).
- Y.S. Ho and G. McKay, Process Biochem., 76, 451 (1999).
References
Z. Belala, M. Jeguirim, M. Belhachemi, F. Addoun and G. Trouvé, Desalination, 271, 80 (2011).
T. Akar, I. Tosun, Z. Kaynak, E. Ozkara, O. Yeni, E.N. Sahin and S.T. Akar, J. Hazard. Mater., 166, 1217 (2009).
R. Rehman, T. Mahmud, J. Anwar, M. Salman, U. Shafique, W. Zaman and F. Ali, J. Chem. Soc. Pak., 33, 228 (2011).
J. Huang and K. Zhang, Desalination, 282, 19 (2011).
M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim and A. Idris, Desalination, 280, 1 (2011).
M.S. Tanyildizi, Chem. Eng. J., 168, 1234 (2011).
G. Moussavi and R. Khosravi, Chem. Eng. Res. Des., 89, 2182 (2011).
N.M. Mahmoodi and B. Hayati, M. Arami and C. Lan, Desalination, 268, 117 (2011).
R. Baccar, P. Blánquez, J. Bouzid, M. Feki and M. Sarrà, Chem. Eng. J., 165, 457 (2010).
R. Rehman, A. Abbas, A. Ayub, Qurat-ul-Ain, M. Salman, T. Mahmud, U. Shafique and W. Zaman, EJEAFChe, 10, 2531 (2011).
M.A. Ahmad and N.K. Rahman, Chem. Eng. J., 170, 154 (2011).
S.P. Sangal, Microchem. J., 9, 26 (1965).
M.J. Iqbal and M.N. Ashiq, J. Hazard. Mater., 139, 57 (2007).
A.M. Rimando and P. Perkins-Veazie, J. Chromatogr. A, 1078, 196 (2005).
M.O. Oluwamukomi, Afr. J. Food Sci., 3, 117 (2009).
M. Tarek, A.M. Magda, A.M. Saleh, S.M. Afaf and Fahmy, Bioresour. Technol., 68, 215 (1999).
M.B. Ibrahim and W.L.O. Jimoh, Indian J. Sci. Technol., 4, 487 (2011).
A. Addo and A. Bart-Plange, ARPN J. Agric. Biol. Sci., 4, 14 (2009).
S.T. Akar, S. Arslan, T. Alp, D. Arslan and T. Akar, Chem. Eng. J., 185-186, 82 (2012).
N.A. Aviara and O.O. Ajibola, J. Food Eng., 55, 107 (2002).
C. Djilani, R. Zaghdoudi, A. Modarressi, M. Rogalski, F. Djazi and A. Lallam, Chem. Eng. J., 189-190, 203 (2012).
R. Rehman, J. Anwar and T. Mahmud, J. Chem. Soc. Pak., 34, 460 (2012).
R. Sowmeyan, J. Santhosh and R. Latha,Int. Res. J. Biochem. Bioinform., 1, 297 (2011).
Y.S. Ho and G. McKay, Process Biochem., 76, 451 (1999).