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Vol. 29 No. 2 (2017): Vol 29 Issue 2

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Photochemical Reactions of Metal Carbonyls [M(CO)6 (M = Cr, Mo, W), Mn(CO)3Cp] with 3[4-Ethyl(phenyl)imino][1H-indol-2-one] and 3[4-Butyl(phenyl)imino][1H-indol-2-one]

https://doi.org/10.14233/ajchem.2017.20004
S. Sener
Ege University, Community College of Aliaga, TR-35100, Izmir, Turkey
A. Ercag
Chemistry Department, Enginee ring Faculty, Istanbul University, 34850, Istanbul, Turkey

Corresponding Author(s) : S. Sener

sevil.sesener@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 2 (2017): Vol 29 Issue 2

Abstract

Four new complexes of M(CO)5(ISE) [M = Mo (1), Cr (2), W (3)] and Mn(CO)3(ISE) (4), where ISE is 3[4-ethyl(phenyl)imino][1H-indol-2-one] has been synthesized by the photochemical reactions of metal carbonyls M(CO)6 (M = Mo, Cr, W) and Mn(CO)3Cp with ISE (1-4). Four new complexes of M(CO)5(ISB) [M = Mo (5), Cr (6), W (7)] and Mn(CO)3 (ISB) (8), where ISB is 3[4-butyl(phenyl)imino][1H-indol-2-one] has been synthesized by photochemical reactions of metal carbonyls M(CO)6 (M = Mo, Cr, W) and Mn(CO)3 Cp with ISB (5-8). The complexes have been characterized by elemental analysis, FT-IR, 1H and 13C NMR spectroscopy. The spectroscopic studies show that, 3[4-ethyl(phenyl)imino][1H-indol-2-one] and 3[4-butyl(phenyl)imino][1H-indol-2-one] ligands, behave as a monodentate ligand and coordinate via C=N donor atom to the central metal atom in M(CO)5(ISE) (1-3) and M(CO)5(ISB) (5-7) where M = Mo, Cr, W and as a tridentate ligand coordinating via imine nitrogen donor atom (C=N), oxygen donor atom (C=O) and ring NH donor atom in Mn(CO)3(ISE) (4) and Mn(CO)3(ISB) (8).

Keywords

Isatin 1,2,4-Triazole Schiff base Metal carbonyl Photochemical reaction
Sener, S., & Ercag, A. (2016). Photochemical Reactions of Metal Carbonyls [M(CO)6 (M = Cr, Mo, W), Mn(CO)3Cp] with 3[4-Ethyl(phenyl)imino][1H-indol-2-one] and 3[4-Butyl(phenyl)imino][1H-indol-2-one]. Asian Journal of Chemistry, 29(2), 235–238. https://doi.org/10.14233/ajchem.2017.20004
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