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Synthesis, Structural, Optical, Thermal and LDT Characterization of Novel Semi-Organic Non-Linear Optical Material: Calcium Borolactate
Corresponding Author(s) : Vidyavathy Balraj
Asian Journal of Chemistry,
Vol. 29 No. 2 (2017): Vol 29 Issue 2
Abstract
A new non-linear optical semi organic crystal calcium borolactate was developed by solution growth cum slow evaporation method. Single crystal XRD studies exposed that the calcium borolactate crystal accord to orthorhombic with the space group P212121. The unit cell parameters are a = 8.49560(1) Å b = 10.0527(2) Å c = 21.3733(3) Å v = 1825.36(5) z = 4, 1.3469(1) mg m-3 R = 0.03 and Mr = 1181.08. The heading compound has also been characterized by UV-visible, FTIR, TGA/DSC studies. Non-linear optical studies shown that calcium borolactate exists a SHG coincide efficiency which is 1.5 times more of KDP.
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- H.S. Nalwa and S. Miyata, Nonlinear Optics Molecules and Polymers, CRC Press: New York (1997).
- P.N. Prasad and D.J. Williams, Introduction to Nonlinear Optical Effects in organic Molecules and Polymers, John Wiley & Sons Inc.: New York, USA (1991).
- K. Hussain and P. Kumbhakar, Braz. J. Phys., 36(4a), 1281 (2006).
- N. Vijayan, N. Balamurugan, R.R. Babu, R. Gopalakrishnan, P. Ramasamy and W.T.A. Harrison, J. Cryst. Growth, 267, 218 (2004).
- T.V. Anderson, Ph.D. Thesis, Application of Nonlinear Optics and Optical Fibres, University of Aarhus, Denmark (2006).
- R.M. Kumar, D. Rajan Babu, D. Jayaraman, R. Jayavel and K. Kitamura, J. Cryst. Growth, 275, 1935 (2005).
- R.B. Ganesh, V. Kannan, K. Meera, N.P. Rajesh and P. Ramasamy, J. Cryst. Growth, 282, 429 (2005).
- P. Anikeeva, SPIE, International Society of Optics and Photonics (2015).
- K.A. Nandekar, J.R. Dontulwar and W.B. Gurnule, Rasayan J. Chem., 5, 261 (2012).
- R.A. Khatri, S.S.C. Chuang, Y. Soong and M.M. Gray, Energy Fuels, 20, 1514 (2006).
- SAINT-Bruker AXS Inc., Madison Wisconsin 53719, USA (1994-1996).
- G.M. Sheldrick, SADABS, University of Gottingen, Germany (1996).
- G.M. Sheldrick, SHELXS97 & SHELXL97, University of Gottingen, Germany (1997).
References
H.S. Nalwa and S. Miyata, Nonlinear Optics Molecules and Polymers, CRC Press: New York (1997).
P.N. Prasad and D.J. Williams, Introduction to Nonlinear Optical Effects in organic Molecules and Polymers, John Wiley & Sons Inc.: New York, USA (1991).
K. Hussain and P. Kumbhakar, Braz. J. Phys., 36(4a), 1281 (2006).
N. Vijayan, N. Balamurugan, R.R. Babu, R. Gopalakrishnan, P. Ramasamy and W.T.A. Harrison, J. Cryst. Growth, 267, 218 (2004).
T.V. Anderson, Ph.D. Thesis, Application of Nonlinear Optics and Optical Fibres, University of Aarhus, Denmark (2006).
R.M. Kumar, D. Rajan Babu, D. Jayaraman, R. Jayavel and K. Kitamura, J. Cryst. Growth, 275, 1935 (2005).
R.B. Ganesh, V. Kannan, K. Meera, N.P. Rajesh and P. Ramasamy, J. Cryst. Growth, 282, 429 (2005).
P. Anikeeva, SPIE, International Society of Optics and Photonics (2015).
K.A. Nandekar, J.R. Dontulwar and W.B. Gurnule, Rasayan J. Chem., 5, 261 (2012).
R.A. Khatri, S.S.C. Chuang, Y. Soong and M.M. Gray, Energy Fuels, 20, 1514 (2006).
SAINT-Bruker AXS Inc., Madison Wisconsin 53719, USA (1994-1996).
G.M. Sheldrick, SADABS, University of Gottingen, Germany (1996).
G.M. Sheldrick, SHELXS97 & SHELXL97, University of Gottingen, Germany (1997).