Zirconium(IV) Phosphoborate-Based Ion Selective Membrane Electrode for Potentiometric Determination of Ba(II) Ions

Sandeep Kaushal; Susheel K. Mittal; Anirudh Pratap Singh; Pritpal Singh

doi:10.14233/ajchem.2017.20208

Issue

Vol. 29 No. 2 (2017): Vol 29 Issue 2

Issue Published : November 30, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Zirconium(IV) Phosphoborate-Based Ion Selective Membrane Electrode for Potentiometric Determination of Ba(II) Ions

https://doi.org/10.14233/ajchem.2017.20208

Sandeep Kaushal

Department of Chemistry, Sri Guru Granth Sahib World University, Fatehgarh Sahib-140 407, India; Department of Chemistry, I.K. Gujral Punjab Technical University, Jalandhar-144 603, India

Susheel K. Mittal

School of Chemistry & Biochemistry, Thapar University, Patiala-147 004, India

Anirudh Pratap Singh

Department of Chemistry, I.K. Gujral Punjab Technical University, Jalandhar-144 603, India

Pritpal Singh

Department of Chemistry, Sri Guru Granth Sahib World University, Fatehgarh Sahib-140 407, India

Corresponding Author(s) : Pritpal Singh

dhillonps2003@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 2 (2017): Vol 29 Issue 2
Article Published : November 30, 2016

Abstract

Zirconium phosphoborate based heterogeneous membrane electrode has been used as a chemical sensor in aqueous medium. The membrane demonstrates sub-Nernstian response in the concentration range of 10^-5 to 10^-1 mol L^-1 Ba(II) ions, with a slope of 20.7 mV decade^-1. The designed sensor has a fast response time of 15 s and has a detection limit of 6.31 × 10^-7 mol L^-1 for Ba(II) ions. Effect of internal solution concentration on the slope of calibration curve was studied. The electrode was successfully used in partially non-aqueous medium. The proposed sensor shows good selectivity for Ba(II) ions with respect to rare earth metal and alkaline earth metal ions. The electrode does not show any change in response within pH range 3.5 to 9. The system was used successfully as an indicator electrode in potentiometric titration of Ba(II) ions with EDTA.

Keywords

Zirconium phosphoborate Indicator electrode Barium selective electrode Potentiometric titration

Kaushal, S., Mittal, S. K., Singh, A. P., & Singh, P. (2016). Zirconium(IV) Phosphoborate-Based Ion Selective Membrane Electrode for Potentiometric Determination of Ba(II) Ions. Asian Journal of Chemistry, 29(2), 375–380. https://doi.org/10.14233/ajchem.2017.20208

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References

O.R. Kirk and F.D. Othmer, Encyclopaedia of Chemical Technology, Wiley, New York, vol. 3 (1982).
I.A. Jacobs, J. Taddeo, K. Kelly and C. Valenziano, Am. J. Ind. Med., 41, 285 (2002).
C.H. Johnson and V.J. Van Tassell, Ann. Emerg. Med., 20, 1138 (1991).
Y. Mauras and P. Allain, Anal. Chim. Acta, 110, 271 (1979).
P. Heitland and H.D. Koster, J. Trace Elem. Med. Biol., 20, 253 (2006).
F. Dehairs, M. De Bondt, W. Baeyens, P. Van Den Winkel and M. Hoenig, Anal. Chim. Acta, 196, 33 (1987).
S.L. Hui, M.Q. Jun and W.X. Yan, Metallurgical Analysis, 02 (2004).
D.L. Tsalev, Progress in Analytical Methodology, CRC Press, Boca Raton, Florida, Vol. III, Chap. 4, pp. 33 (1995).
F. Faridbod, M.R. Ganjali, R. Dinarvand, P. Norouzi and S. Riahi, Sensors, 8, 1645 (2008).
M.R. Ganjali, P. Norouzi, F. Faridbod, M. Rezapour and M.R. Pourjavid, J. Iran. Chem. Soc., 4, 1 (2007).
F. Faridbod, P. Norouzi, R. Dinarvand and M.R. Ganjali, Sensors (Basel), 8, 2331 (2008).
M.A. Arnold and R.L. Solsky, Anal. Chem., 58, 84 (1986).
R.P. Buck and E. Lindner, Pure Appl. Chem., 66, 2527 (1994).
K.A. Kraus and H.O. Phillips, J. Am. Chem. Soc., 78, 694 (1956).
K.A. Kraus, H.O. Phillips, T.A. Carlson and J.S. Johnson, Proc. 2nd UN Conf. Peaceful Uses Atomic Energy, Geneva, vol. 28 (1958).
C.B. Amphlett, Proc. 2nd UN Conf. Peaceful Uses Atomic Energy, Geneva, vol. 28, p. 17 (1958).
C.B. Amphlett Inorganic Ion Exchangers, Elsevier, Amsterdam, pp. 97 (1964).
H.A. Zamani, M. Masrournia, M. Rostame-Faroge, M.R. Ganjali and H. Behmadi, Sensor Lett., 6, 759 (2008).
M. Mazloum-Ardakani, J. Safari, P. Pourhakkak and M.A. Sheikh-Mohseni, Int. J. Environ. Anal. Chem., 92, 1638 (2012).
M. Hosseini, M. Rahimi, H.B. Sadeghi, S. Taghvaei-Ganjali, S.D. Abkenar and M.R. Ganjali, Int. J. Environ. Anal. Chem., 89, 407 (2009).
M. Shamsipur, A. Shirmardi Dezaki, M. Akhond, H. Sharghi and R. Khalife, Int. J. Environ. Anal. Chem., 91, 33 (2011).
S.H. Bagheri, H. Sid Kalal, H. Hoveidi, Z. Molavi and N. Adeli-Asl, Int. J. Environ. Res., 5, 561 (2011).
A.K. Singh, A.K. Jain, A. Upadhyay, K.R.J. Thomas and P. Singh, Int. J. Environ. Anal. Chem., 93, 813 (2013).
S. Kaushal, P.P. Singh and S.K. Mittal, J. New Mater. Electrochem. Syst., 17, 8 (2014).
M.K. Rofouei, M. Mohammadi, M. Khodadadian, A.R. Jalalvand and A. Beiza, Int. J. Environ. Anal. Chem., 92, 665 (2012).
S.K. Mittal, R. Kumar, P. Dogra and H.K. Sharma, J. Anal. Chem., 65, 1045 (2010).
S.K. Mittal, P. Kumar, S.K.A. Kumar and L.F. Lindoy, Int. J. Electrochem. Sci., 5, 1984 (2010).

References

O.R. Kirk and F.D. Othmer, Encyclopaedia of Chemical Technology, Wiley, New York, vol. 3 (1982).

I.A. Jacobs, J. Taddeo, K. Kelly and C. Valenziano, Am. J. Ind. Med., 41, 285 (2002).

C.H. Johnson and V.J. Van Tassell, Ann. Emerg. Med., 20, 1138 (1991).

Y. Mauras and P. Allain, Anal. Chim. Acta, 110, 271 (1979).

P. Heitland and H.D. Koster, J. Trace Elem. Med. Biol., 20, 253 (2006).

F. Dehairs, M. De Bondt, W. Baeyens, P. Van Den Winkel and M. Hoenig, Anal. Chim. Acta, 196, 33 (1987).

S.L. Hui, M.Q. Jun and W.X. Yan, Metallurgical Analysis, 02 (2004).

D.L. Tsalev, Progress in Analytical Methodology, CRC Press, Boca Raton, Florida, Vol. III, Chap. 4, pp. 33 (1995).

F. Faridbod, M.R. Ganjali, R. Dinarvand, P. Norouzi and S. Riahi, Sensors, 8, 1645 (2008).

M.R. Ganjali, P. Norouzi, F. Faridbod, M. Rezapour and M.R. Pourjavid, J. Iran. Chem. Soc., 4, 1 (2007).

F. Faridbod, P. Norouzi, R. Dinarvand and M.R. Ganjali, Sensors (Basel), 8, 2331 (2008).

M.A. Arnold and R.L. Solsky, Anal. Chem., 58, 84 (1986).

R.P. Buck and E. Lindner, Pure Appl. Chem., 66, 2527 (1994).

K.A. Kraus and H.O. Phillips, J. Am. Chem. Soc., 78, 694 (1956).

K.A. Kraus, H.O. Phillips, T.A. Carlson and J.S. Johnson, Proc. 2nd UN Conf. Peaceful Uses Atomic Energy, Geneva, vol. 28 (1958).

C.B. Amphlett, Proc. 2nd UN Conf. Peaceful Uses Atomic Energy, Geneva, vol. 28, p. 17 (1958).

C.B. Amphlett Inorganic Ion Exchangers, Elsevier, Amsterdam, pp. 97 (1964).

H.A. Zamani, M. Masrournia, M. Rostame-Faroge, M.R. Ganjali and H. Behmadi, Sensor Lett., 6, 759 (2008).

M. Mazloum-Ardakani, J. Safari, P. Pourhakkak and M.A. Sheikh-Mohseni, Int. J. Environ. Anal. Chem., 92, 1638 (2012).

M. Hosseini, M. Rahimi, H.B. Sadeghi, S. Taghvaei-Ganjali, S.D. Abkenar and M.R. Ganjali, Int. J. Environ. Anal. Chem., 89, 407 (2009).

M. Shamsipur, A. Shirmardi Dezaki, M. Akhond, H. Sharghi and R. Khalife, Int. J. Environ. Anal. Chem., 91, 33 (2011).

S.H. Bagheri, H. Sid Kalal, H. Hoveidi, Z. Molavi and N. Adeli-Asl, Int. J. Environ. Res., 5, 561 (2011).

A.K. Singh, A.K. Jain, A. Upadhyay, K.R.J. Thomas and P. Singh, Int. J. Environ. Anal. Chem., 93, 813 (2013).

S. Kaushal, P.P. Singh and S.K. Mittal, J. New Mater. Electrochem. Syst., 17, 8 (2014).

M.K. Rofouei, M. Mohammadi, M. Khodadadian, A.R. Jalalvand and A. Beiza, Int. J. Environ. Anal. Chem., 92, 665 (2012).

S.K. Mittal, R. Kumar, P. Dogra and H.K. Sharma, J. Anal. Chem., 65, 1045 (2010).

S.K. Mittal, P. Kumar, S.K.A. Kumar and L.F. Lindoy, Int. J. Electrochem. Sci., 5, 1984 (2010).

Issue

Vol. 29 No. 2 (2017): Vol 29 Issue 2

Zirconium(IV) Phosphoborate-Based Ion Selective Membrane Electrode for Potentiometric Determination of Ba(II) Ions

Corresponding Author(s) : Pritpal Singh

Abstract

Keywords

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