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Swertia chirata Extract Synthesized Iron Oxide Nanoparticles as Corrosion Inhibitor for SS-316L in Hank’s Solution
Corresponding Author(s) : Vineet Kumar
Asian Journal of Chemistry,
Vol. 33 No. 8 (2021): Vol 33 Issue 8, 2021
Abstract
Metallic implants are the artificial biomedical devices used to replace, repair or improve the functioning of damaged body organ or tissue. Corrosion of metallic component in the human body leads to the failure or improper functioning of the implant. This study focuses on the application of Swertia chirata extract synthesized iron oxide nanoparticles as corrosion inhibitor for stainless steel (SS) 316L in Hank’s solution. Gravimetric method and electrochemical studied were used to analyze the corrosion inhibition property. SEM and AFM analyses confirmed the corrosion preventive effect of iron oxide nanoparticles on SS-316L surface. Further concentration dependent increase in inhibition efficiency was observed with maximum 80.3% corrosion inhibition at 100 ppm nanoparticles concentration from gravimetric analysis, which is well correlated with the electrochemical measurements. Therefore, iron oxide nanoparticles can be utilized as potent anticorrosive agent, which can protect the metal surface from further deterioration in harsh body environments.
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- N. Eliaz, Materials, 12, 407 (2019); https://doi.org/10.3390/ma12030407
- M.A. Hussein, A.S. Mohammed and N. Al-Aqeeli, Materials, 8, 2749 (2015); https://doi.org/10.3390/ma8052749
- K. Prasad, O. Bazaka, M. Chua, M. Rochford, L. Fedrick, J. Spoor, R. Symes, M. Tieppo, C. Collins, A. Cao, D. Markwell, K.K. Ostrikov and K. Bazaka, Materials, 10, 884 (2017); https://doi.org/10.3390/ma10080884
- N.S. Manam, W.S.W. Harun, D.N.A. Shri, S.A.C. Ghani, T. Kurniawan, M.H. Ismail and M.H.I. Ibrahim, J. Alloys Compd., 701, 698 (2017); https://doi.org/10.1016/j.jallcom.2017.01.196
- G. Manivasagam, D. Dhinasekaran and A. Rajamanickam, Recent Pat. Corros. Sci., 2, 40 (2010); https://doi.org/10.2174/1877610801002010040
- N. Bhardwaj, P. Sharma and V. Kumar, Corros. Rev., 39, 27 (2021); https://doi.org/10.1515/corrrev-2020-0046.
- J. Tkacz, K. Slouková, J. Minda, J. Drábiková, S. Fintová, P. Dolezal and J. Wasserbauer, Metals, 7, 465 (2017); https://doi.org/10.3390/met7110465
- S.B. Arya, A. Bhattacharjee and M. Roy, Mater. Corros., 69, 1025 (2018); https://doi.org/10.1002/maco.201709894
- X. Niu, H. Shen, J. Fu, J. Yan and Y. Wang, Corros. Sci., 157, 284 (2019); https://doi.org/10.1016/j.corsci.2019.05.026
- N.V. Srikanth Vallabani and S. Singh, 3 Biotech., 8, 279 (2018); https://doi.org/10.1007/s13205-018-1286-z
- S. Kanagasubbulakshmi and K. Kadirvelu, Defence Life Sci. J., 2, 422 (2017); https://doi.org/10.14429/dlsj.2.12277
- B. Sivakumar, L.C. Pathak and R. Singh, Appl. Surf. Sci., 401, 385 (2017); https://doi.org/10.1016/j.apsusc.2017.01.033
- V. Kumar and J. Van Staden, Front. Pharmacol., 6, 308 (2016); https://doi.org/10.3389/fphar.2015.00308
- V. Kumar and S.K. Yadav, J. Chem. Technol. Biotechnol., 84, 151 (2009); https://doi.org/10.1002/jctb.2023
- V. Kumar, S.C. Yadav and S.K. Yadav, J. Chem. Technol. Biotechnol., 85, 1301 (2010); https://doi.org/10.1002/jctb.2427
- V. Kumar, K. Singh, S. Panwar and S.K. Mehta, Int. Nano Lett., 7, 123 (2017); https://doi.org/10.1007/s40089-017-0205-3
- A.C. Richard, Laboratory Corrosion Testing of Medical Implants, ASM International, Newyark, Delaware, USA (2003).
- ASTM F2129-17b, Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements o Determine the Corrosion Susceptibility of Small Implant Devices, ASTM International, West Conshohocken, PA (2017).
- L. Zhang, X. Tong, J. Lin, Y. Li and C. Wen, Corros. Sci., 169, 108602 (2020); https://doi.org/10.1016/j.corsci.2020.108602
- D. Mei, C. Wang, S.V. Lamaka and M.L. Zheludkevich, J. Magnesium Alloys, 9, 805 (2021); https://doi.org/10.1016/j.jma.2020.07.002
- J. Tkacz, K. Slouková, J. Minda, J. Drábiková, S. Fintová, P. Dolezal and J. Wasserbauer, Metals, 7, 465 (2017); https://doi.org/10.3390/met7110465
- J. Tkacz, K. Slouková, J. Minda, J. Drábiková, S. Fintová, P. Dolezal and J. Wasserbauer, Koroze a Ochrana Mater., 60, 101 (2016); https://doi.org/10.1515/kom-2016-0016
- E. Tamam and I. Turkyilmaz, J. Oral Implantol., 40, 153 (2014); https://doi.org/10.1563/AAID-JOI-D-11-00083
- R. Ambat, N.N. Aung and W. Zhou, J. Appl. Electrochem., 30, 865 (2000); https://doi.org/10.1023/A:1004011916609
- H. Altun and S. Sen, Mater. Des., 25, 637 (2004); https://doi.org/10.1016/j.matdes.2004.02.002
- L.Y. Wu, Y.L. Kuo, K.H. Chang, T.H. Chen, C.Y. Cheng, Y.S. Liu and C. Huang, Surf. Interface Anal., 51, 993 (2019); https://doi.org/10.1002/sia.6684
- M.C. Merino, A. Pardo, R. Arrabal, S. Merino, P. Casajus and M. Mohedano, Corros. Sci., 52, 1696 (2010); https://doi.org/10.1016/j.corsci.2010.01.020
- A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, Constr. Build. Mater., 245, 118464 (2020);
- https://doi.org/10.1016/j.conbuildmat.2020.118464
- S. Shetty, J. Nayak and N. Shetty, J. Magnes. Alloys, 3, 258 (2015); https://doi.org/10.1016/j.jma.2015.07.004
- G.F. Vander Voort, Metallography, Principles and Practice, ASM International: Materials Park, OH, USA, Ed. 1, pp. 1-752 (1999).
- J. Tkacz, J. Minda, S. Fintová and J. Wasserbauer, Materials, 9, 925 (2016); https://doi.org/10.3390/ma9110925
- S.E. Harandi, P.C. Banerjee, C.D. Easton and R.K. Singh Raman, Mater. Sci. Eng. C, 80, 335 (2017); https://doi.org/10.1016/j.msec.2017.06.002
- O. Igwe and F. Nwamezie, Chem. Int., 4, 60 (2018).
- T. Mengistie, A. Alemu and A. Mekonnen, Chem. Int., 4, 130 (2018).
- N. Eliaz and E. Gileadi, Physical Electrochemistry: Fundamentals, Techniques and Applications. John Wiley & Sons (2019).
- Y. Zhu, G. Wu, Y.H. Zhang and Q. Zhao, Appl. Surf. Sci., 257, 6129 (2011); https://doi.org/10.1016/j.apsusc.2011.02.017
- Y. Song, D. Shan, R. Chen, F. Zhang and E.-H. Han, Mater. Sci. Eng. C, 29, 1039 (2009); https://doi.org/10.1016/j.msec.2008.08.026
- D.H. Abdeen, M.A. Atieh and B. Merzougui, Materials, 14, 119 (2020); https://doi.org/10.3390/ma14010119
- A. Pardo, M.C. Merino, A.E. Coy, R. Arrabal, F. Viejo and E. Matykina, Corros. Sci., 50, 823 (2008); https://doi.org/10.1016/j.corsci.2007.11.005
- I. Milosan, M. Florescu, D. Cristea, I. Voiculescu, M.A. Pop, I. Cañadas, J. Rodriguez, C.A. Bogatu and T. Bedo, Materials, 13, 581 (2020); https://doi.org/10.3390/ma13030581
- M. Alahiane, R. Oukhrib, Y.A. Albrimi, H.A. Oualid, H. Bourzi, R.A. Akbour, A. Assabbane, A. Nahlé and M. Hamdani, RSC Adv., 10, 41137 (2020); https://doi.org/10.1039/D0RA06742C
- E. Ituen, L. Yuanhua, A. Singh and R. Li, J. King Saud Univ. Eng. Sci., (2020); https://doi.org/10.1016/j.jksues.2020.05.005
- S. Feliu Jr. and I. Llorente, Appl. Surf. Sci., 347, 736 (2015); https://doi.org/10.1016/j.apsusc.2015.04.189.
- R. Walter and M.B. Kannan, Mater. Des., 32, 2350 (2011); https://doi.org/10.1016/j.matdes.2010.12.016
References
N. Eliaz, Materials, 12, 407 (2019); https://doi.org/10.3390/ma12030407
M.A. Hussein, A.S. Mohammed and N. Al-Aqeeli, Materials, 8, 2749 (2015); https://doi.org/10.3390/ma8052749
K. Prasad, O. Bazaka, M. Chua, M. Rochford, L. Fedrick, J. Spoor, R. Symes, M. Tieppo, C. Collins, A. Cao, D. Markwell, K.K. Ostrikov and K. Bazaka, Materials, 10, 884 (2017); https://doi.org/10.3390/ma10080884
N.S. Manam, W.S.W. Harun, D.N.A. Shri, S.A.C. Ghani, T. Kurniawan, M.H. Ismail and M.H.I. Ibrahim, J. Alloys Compd., 701, 698 (2017); https://doi.org/10.1016/j.jallcom.2017.01.196
G. Manivasagam, D. Dhinasekaran and A. Rajamanickam, Recent Pat. Corros. Sci., 2, 40 (2010); https://doi.org/10.2174/1877610801002010040
N. Bhardwaj, P. Sharma and V. Kumar, Corros. Rev., 39, 27 (2021); https://doi.org/10.1515/corrrev-2020-0046.
J. Tkacz, K. Slouková, J. Minda, J. Drábiková, S. Fintová, P. Dolezal and J. Wasserbauer, Metals, 7, 465 (2017); https://doi.org/10.3390/met7110465
S.B. Arya, A. Bhattacharjee and M. Roy, Mater. Corros., 69, 1025 (2018); https://doi.org/10.1002/maco.201709894
X. Niu, H. Shen, J. Fu, J. Yan and Y. Wang, Corros. Sci., 157, 284 (2019); https://doi.org/10.1016/j.corsci.2019.05.026
N.V. Srikanth Vallabani and S. Singh, 3 Biotech., 8, 279 (2018); https://doi.org/10.1007/s13205-018-1286-z
S. Kanagasubbulakshmi and K. Kadirvelu, Defence Life Sci. J., 2, 422 (2017); https://doi.org/10.14429/dlsj.2.12277
B. Sivakumar, L.C. Pathak and R. Singh, Appl. Surf. Sci., 401, 385 (2017); https://doi.org/10.1016/j.apsusc.2017.01.033
V. Kumar and J. Van Staden, Front. Pharmacol., 6, 308 (2016); https://doi.org/10.3389/fphar.2015.00308
V. Kumar and S.K. Yadav, J. Chem. Technol. Biotechnol., 84, 151 (2009); https://doi.org/10.1002/jctb.2023
V. Kumar, S.C. Yadav and S.K. Yadav, J. Chem. Technol. Biotechnol., 85, 1301 (2010); https://doi.org/10.1002/jctb.2427
V. Kumar, K. Singh, S. Panwar and S.K. Mehta, Int. Nano Lett., 7, 123 (2017); https://doi.org/10.1007/s40089-017-0205-3
A.C. Richard, Laboratory Corrosion Testing of Medical Implants, ASM International, Newyark, Delaware, USA (2003).
ASTM F2129-17b, Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements o Determine the Corrosion Susceptibility of Small Implant Devices, ASTM International, West Conshohocken, PA (2017).
L. Zhang, X. Tong, J. Lin, Y. Li and C. Wen, Corros. Sci., 169, 108602 (2020); https://doi.org/10.1016/j.corsci.2020.108602
D. Mei, C. Wang, S.V. Lamaka and M.L. Zheludkevich, J. Magnesium Alloys, 9, 805 (2021); https://doi.org/10.1016/j.jma.2020.07.002
J. Tkacz, K. Slouková, J. Minda, J. Drábiková, S. Fintová, P. Dolezal and J. Wasserbauer, Metals, 7, 465 (2017); https://doi.org/10.3390/met7110465
J. Tkacz, K. Slouková, J. Minda, J. Drábiková, S. Fintová, P. Dolezal and J. Wasserbauer, Koroze a Ochrana Mater., 60, 101 (2016); https://doi.org/10.1515/kom-2016-0016
E. Tamam and I. Turkyilmaz, J. Oral Implantol., 40, 153 (2014); https://doi.org/10.1563/AAID-JOI-D-11-00083
R. Ambat, N.N. Aung and W. Zhou, J. Appl. Electrochem., 30, 865 (2000); https://doi.org/10.1023/A:1004011916609
H. Altun and S. Sen, Mater. Des., 25, 637 (2004); https://doi.org/10.1016/j.matdes.2004.02.002
L.Y. Wu, Y.L. Kuo, K.H. Chang, T.H. Chen, C.Y. Cheng, Y.S. Liu and C. Huang, Surf. Interface Anal., 51, 993 (2019); https://doi.org/10.1002/sia.6684
M.C. Merino, A. Pardo, R. Arrabal, S. Merino, P. Casajus and M. Mohedano, Corros. Sci., 52, 1696 (2010); https://doi.org/10.1016/j.corsci.2010.01.020
A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, Constr. Build. Mater., 245, 118464 (2020);
https://doi.org/10.1016/j.conbuildmat.2020.118464
S. Shetty, J. Nayak and N. Shetty, J. Magnes. Alloys, 3, 258 (2015); https://doi.org/10.1016/j.jma.2015.07.004
G.F. Vander Voort, Metallography, Principles and Practice, ASM International: Materials Park, OH, USA, Ed. 1, pp. 1-752 (1999).
J. Tkacz, J. Minda, S. Fintová and J. Wasserbauer, Materials, 9, 925 (2016); https://doi.org/10.3390/ma9110925
S.E. Harandi, P.C. Banerjee, C.D. Easton and R.K. Singh Raman, Mater. Sci. Eng. C, 80, 335 (2017); https://doi.org/10.1016/j.msec.2017.06.002
O. Igwe and F. Nwamezie, Chem. Int., 4, 60 (2018).
T. Mengistie, A. Alemu and A. Mekonnen, Chem. Int., 4, 130 (2018).
N. Eliaz and E. Gileadi, Physical Electrochemistry: Fundamentals, Techniques and Applications. John Wiley & Sons (2019).
Y. Zhu, G. Wu, Y.H. Zhang and Q. Zhao, Appl. Surf. Sci., 257, 6129 (2011); https://doi.org/10.1016/j.apsusc.2011.02.017
Y. Song, D. Shan, R. Chen, F. Zhang and E.-H. Han, Mater. Sci. Eng. C, 29, 1039 (2009); https://doi.org/10.1016/j.msec.2008.08.026
D.H. Abdeen, M.A. Atieh and B. Merzougui, Materials, 14, 119 (2020); https://doi.org/10.3390/ma14010119
A. Pardo, M.C. Merino, A.E. Coy, R. Arrabal, F. Viejo and E. Matykina, Corros. Sci., 50, 823 (2008); https://doi.org/10.1016/j.corsci.2007.11.005
I. Milosan, M. Florescu, D. Cristea, I. Voiculescu, M.A. Pop, I. Cañadas, J. Rodriguez, C.A. Bogatu and T. Bedo, Materials, 13, 581 (2020); https://doi.org/10.3390/ma13030581
M. Alahiane, R. Oukhrib, Y.A. Albrimi, H.A. Oualid, H. Bourzi, R.A. Akbour, A. Assabbane, A. Nahlé and M. Hamdani, RSC Adv., 10, 41137 (2020); https://doi.org/10.1039/D0RA06742C
E. Ituen, L. Yuanhua, A. Singh and R. Li, J. King Saud Univ. Eng. Sci., (2020); https://doi.org/10.1016/j.jksues.2020.05.005
S. Feliu Jr. and I. Llorente, Appl. Surf. Sci., 347, 736 (2015); https://doi.org/10.1016/j.apsusc.2015.04.189.
R. Walter and M.B. Kannan, Mater. Des., 32, 2350 (2011); https://doi.org/10.1016/j.matdes.2010.12.016