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Vol. 32 No. 2 (2020): Vol 32 Issue 2

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Colorimetric Detection of Iron(III) Ion Based on 4-Aminothiophenol and Schiff Base Naphthalene-2-ol Modified Silver Nanoparticles

https://doi.org/10.14233/ajchem.2020.22301
Wachirawit Samerjai
Department of Chemistry, Faculty of Science, Srinakharinwirot University114 Sukhumvit 23 Rd., Wattana, Bangkok 10110, Thailand
Piyada Jittangprasert
Department of Chemistry, Faculty of Science, Srinakharinwirot University114 Sukhumvit 23 Rd., Wattana, Bangkok 10110, Thailand
Pan Tongraung
Department of Chemistry, Faculty of Science, Srinakharinwirot University114 Sukhumvit 23 Rd., Wattana, Bangkok 10110, Thailand

Corresponding Author(s) : Pan Tongraung

pan15164649@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 2 (2020): Vol 32 Issue 2

Abstract

A facile, highly selective colorimetric sensor based on 4-aminothiophenol (4-ATP) and Schiff base naphthalene-2-ol (L) modified silver nanoparticles (4-ATP-L-AgNPs) for detection of Fe(III) ion in aqueous solution. The presence of Fe(III) ion induced the aggregation of AgNPs that caused the red-shift from 430 to 440 nm, through a cooperative metal-ligand interaction from the coordination bond between Fe(III) ion and functional groups on AgNPs surface resulting in a colour change from dark brown to dark yellow with increasing absorption at 365 nm. The absorbance at 365 nm is linear with the concentration of Fe(III) ion ranging from 9.0 × 10-6 M to 9.0 × 10-3 M with a correlation coefficient of 0.9991. The detection limit of the developed method was 7.9 × 10-6 M. The practical application of 4-ATP-L-AgNPs for selective sensor for Fe(III) ion in various drinking water samples were demonstrated.

Keywords

Colorimetric detection Modified silver nanoparticles Iron(III) ion Water samples
Samerjai, W., Jittangprasert, P., & Tongraung, P. (2019). Colorimetric Detection of Iron(III) Ion Based on 4-Aminothiophenol and Schiff Base Naphthalene-2-ol Modified Silver Nanoparticles. Asian Journal of Chemistry, 32(2), 287–292. https://doi.org/10.14233/ajchem.2020.22301
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