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This work is licensed under a Creative Commons Attribution 4.0 International License.
Removal of Uranium(VI) from Aqueous Solution by Iron Nanoparticles Synthesized from Testa Extract of Annacardium occidentale: A Fluorimetric Study
Corresponding Author(s) : Fahmida Khan
Asian Journal of Chemistry,
Vol. 32 No. 2 (2020): Vol 32 Issue 2
Abstract
Uranium(VI) is one of the most harmful and carcinogenic ion if present in water above its permissible limit. The main objective of this study is removal of uranium(VI) from water sample using nano zerovalent iron prepared by green synthesis approach with the help of Annacardium occidentale testa extract in which the whole process is completely environmental friendly and cost effective and does not involve any hazardous chemicals. Size of AO-Fe nanoparticle is characterized through UV-visible spectroscopy and FTIR analysis. Morphology of nanoparticle is studied using SEM-EDS and XRD analysis. The adsorption capacity of AO-Fe nanoparticle is studied using batch experiments. Effect of different parameters are then analyzed such as pH, adsorbent dosage, contact time and U(VI) ion concentration. Adsorption isotherm is also studied using Langmuir and Freundlich adsorption isotherm where correlation constant R2 is about 0.99.
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- J.J. Lenhart and B.D. Honeyman, Geochim. Cosmochim. Acta, 63, 2891 (1999); https://doi.org/10.1016/S0016-7037(99)00269-0.
- T.B. Scott, Ph.D. Thesis, Sorption of Uranium onto Iron Bearing Minerals, Interface Analysis Centre, University of Bristol, Bristol, U.K. (2005).
- T.B. Scott, O. Riba and G.C. Allen, Geochim. Cosmochim. Acta, 71, 5044 (2007); https://doi.org/10.1016/j.gca.2007.08.017.
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- C. Chandra, F. Khan and D.K. Verma, Int. J. Eng. Technol. Sci. Res., 4, 671 (2017).
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- A.G. Mathew, H.A.B. Parpia, J. Food Sci., 35, 140 (1970); https://doi.org/10.1111/j.1365-2621.1970.tb12123.x.
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References
G. Crini, Prog. Polym. Sci., 30, 38 (2005); https://doi.org/10.1016/j.progpolymsci.2004.11.002.
G. Gangadhar, U. Maheshwari and S. Gupta, Nanosci. Nanotechnol.-Asia, 2, 140 (2012); https://doi.org/10.2174/2210681211202020140.
Environmental Protection Agency, Nanotechnology White Paper, USEPA 100/B-07/001 (2007).
K.N. Thakkar, S.S. Mhatre and R.Y. Parikh, Nanomedicine, 6, 257 (2010); https://doi.org/10.1016/j.nano.2009.07.002.
S. Panigrahi, S. Kundu, S. K. Ghosh, S. Nath and T. Pal, J. Nanopart. Res., 6, 411 (2004); https://doi.org/10.1007/s11051-004-6575-2.
The Energy and Resources Institute, Nanotechnology Development in India: Building Capability and Governing the Technology, Briefing Paper, TERI, New Delhi, India (2010).
Patanjali, Pooja, R. Singh, A. Kumar and P. Chaudhary, eds.: A.K. Shukla and S. Iravani, Nanotechnology for Water Treatment: A Green Approach, In: Green Synthesis, Characterization and Applications of Nanoparticles, Elsevier Inc. (2019).
C.D. Hsi and D. Langmuir, Geochim. Cosmochim. Acta, 49, 1931 (1985); https://doi.org/10.1016/0016-7037(85)90088-2.
J.J. Lenhart and B.D. Honeyman, Geochim. Cosmochim. Acta, 63, 2891 (1999); https://doi.org/10.1016/S0016-7037(99)00269-0.
T.B. Scott, Ph.D. Thesis, Sorption of Uranium onto Iron Bearing Minerals, Interface Analysis Centre, University of Bristol, Bristol, U.K. (2005).
T.B. Scott, O. Riba and G.C. Allen, Geochim. Cosmochim. Acta, 71, 5044 (2007); https://doi.org/10.1016/j.gca.2007.08.017.
J.N. Fiedor, W.D. Bostick, R.J. Jarabek and J. Farrell, Environ. Sci. Technol., 32, 1466 (1998); https://doi.org/10.1021/es970385u.
J. Farrell, W.D. Bostick, R.J. Jarabek and J.N. Fiedor, Ground Water, 37, 618 (1999); https://doi.org/10.1111/j.1745-6584.1999.tb01150.x.
T.B. Scott, G.C. Allen, P.J. Heard and M.G. Randell, Geochim. Cosmochim. Acta, 69, 5639 (2005); https://doi.org/10.1016/j.gca.2005.07.003.
T.B. Scott, G.C. Allen, P.J. Heard, A.C. Lewis and D.F. Lee, Proc. R. Soc. A, 461, 1247 (2005); https://doi.org/10.1098/rspa.2004.1441.
K.J. Cantrell, D.I. Kaplan and T.W. Wietsman, J. Hazard. Mater., 42, 201 (1995); https://doi.org/10.1016/0304-3894(95)00016-N.
L. Charlet, E. Liger and P. Gerasimo, J. Environ. Eng., 124, 25 (1998); https://doi.org/10.1061/(ASCE)0733-9372(1998)124:1(25).
B. Gu, L. Liang, M.J. Dickey, X. Yin and S. Dai, Environ. Sci., 21, 3366 (1998); https://doi.org/10.1021/es980010o.
E. Liger, L. Charlet and P. van Cappellen, Geochim. Cosmochim. Acta, 63, 2939 (1999); https://doi.org/10.1016/S0016-7037(99)00265-3.
S.J. Morrison, D.R. Metzler and C.E. Carpenter, Environ. Sci. Technol., 35, 385 (1998); https://doi.org/10.1021/es001204i.
C. Chandra, F. Khan and D.K. Verma, Int. J. Eng. Technol. Sci. Res., 4, 671 (2017).
N. Chandrasekara and F. Shahidi, J. Agric. Food Chem., 59, 5006 (2011); https://doi.org/10.1021/jf2000772.
N. Chandrasekara and F. Shahidi, Food Chem., 129, 1388 (2011); https://doi.org/10.1016/j.foodchem.2011.05.075.
A.G. Mathew, H.A.B. Parpia, J. Food Sci., 35, 140 (1970); https://doi.org/10.1111/j.1365-2621.1970.tb12123.x.
J. Trox, V. Vadivel, W. Vetter, W. Stuetz, D.R. Kammerer, R. Carle, V. Scherbaum, U. Gola, D. Nohr and H.K. Biesalski, Food Chem., 128, 1094 (2011); https://doi.org/10.1016/j.foodchem.2011.04.018.
J. Yang, X. Wang, M. Zhu, H. Liu and J. Ma, J. Hazard. Mater., 264, 269 (2014); https://doi.org/10.1016/j.jhazmat.2013.11.037.