A Kinetic Study of Oxidation of Aliphatic Ketone with N-Bromobenzamide in Acidic Medium
Corresponding Author(s) : S. K. Solanki
Asian Journal of Chemistry,
Vol. 1 No. 3 (1989): Vol 1 Issue 3
Abstract
The kinetics of oxidation of ethyl methyl ketone by N-bromobenzamide (NBB) in aquoacetic acid media has been done. The reaction has a zero order dependency on [NBB] and a first order dependency with respect to substrate [ethyl methyl ketone]. The reaction is catalysing by H+. The effect of ionic strength, mercuric acetate and product [benzamide] variations has been studied. Various thermodynamic parameters have been computed and a probable reaction mechanism consistent with the kinetic results has been suggested.
Keywords
Kinetic Study
Oxidation
Aliphatic Ketone
N-Bromobenzamide
Acidic Medium
P. Dubey, R., Kumari, G., & K. Solanki, S. (2010). A Kinetic Study of Oxidation of Aliphatic Ketone with N-Bromobenzamide in Acidic Medium. Asian Journal of Chemistry, 1(3), 249–253. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/25406
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