Kinetics of Oxidation of 2,6-Diphenyltetrahydrothiopyran- 4-ones by Pyridinium Chlorochromate
Corresponding Author(s) : M. Krishna Pillay
Asian Journal of Chemistry,
Vol. 3 No. 3 (1991): Vol 3 Issue 3
Abstract
Oxidation of cis- and trans-isomers of 2,6-diphenyltetrahydrothiopyran-4-one by pyridinium chlorochromate are found to be first order in each with respect to [subs] and [oxd]. Rate has been found to increase with increase in acid concentration and the rate dependence on [H+] is not unity. Based on the kinetic results suitable mechanism has been proposed.
Keywords
Kinetics
Oxidation
2,6-Diphenyltetrahydrothiopyran- 4-ones
Pyridinium Chlorochromate
Krishna Pillay, M., & Shanthi, R. (2010). Kinetics of Oxidation of 2,6-Diphenyltetrahydrothiopyran- 4-ones by Pyridinium Chlorochromate . Asian Journal of Chemistry, 3(3), 272–274. Retrieved from https://asianpubs.org/index.php/ajchem/article/view/25241
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX