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Vol. 32 No. 3 (2020): Vol 32 Issue 3

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Template Synthesis and Characterization of Transition Metal Complexes of 13, 15 and 17-Membered Tetraamide Macrocyclic Disubstituted Dimethyl Tetrasubstituted Tetraazacycloalka Tetrasubstituted Tetraene Disubstiuted Diol

https://doi.org/10.14233/ajchem.2020.22362
B. Vimala
Department of Chemistry, Mother Teresa Women′s University, Kodaikanal-624102, India
S.R. Jayapradha
Department of Chemistry, Government Arts College for Women, Nilakottai-624208, India
A. Selvan
Department of Chemistry, Government Arts College for Women, Nilakottai-624208, India

Corresponding Author(s) : A. Selvan

selvamithu6970@gmail.com

Asian Journal of Chemistry, Vol. 32 No. 3 (2020): Vol 32 Issue 3

Abstract

A series of new transition metal complexes [ML(Ln)Cl2] where Ln = L13, L15 and L17 (L(13) = 11,13-dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-diol, L(15) = 9,11-dimethyl-1,4,8,12-tetraazacyclopentadeca-1,3,8,11-tetraene-2,3-diol and L(17) = 10,12-dimethyl-1,4,9,13-tetraazacycloheptadeca-1,3,9,12-tetraene-2,3-diol) and M = Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) have been synthesized by template method. All the synthesized complexes were characterized by IR, UV, ESR, X-ray microanalysis, elemental analysis, thermal studies and magnetic susceptibilities and the geometry of the complexes found to be octahedral.

Keywords

Coordination complexes Macrocyclic ligand Schiff base Polyazamacrocycles
Vimala, B., Jayapradha, S., & Selvan, A. (2020). Template Synthesis and Characterization of Transition Metal Complexes of 13, 15 and 17-Membered Tetraamide Macrocyclic Disubstituted Dimethyl Tetrasubstituted Tetraazacycloalka Tetrasubstituted Tetraene Disubstiuted Diol. Asian Journal of Chemistry, 32(3), 488–494. https://doi.org/10.14233/ajchem.2020.22362
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